• Keine Ergebnisse gefunden

Lithium Isotope Effect Accompanying Electrochemical Insertion of Lithium into Liquid Gallium

N/A
N/A
Info
Herunterladen
Protected

Academic year: 2022

Aktie "Lithium Isotope Effect Accompanying Electrochemical Insertion of Lithium into Liquid Gallium"

Copied!
1
0
0

Wird geladen.... (Jetzt Volltext ansehen)

Jetzt herunterladen ( 1 Seite )

Volltext

(1)

Lithium Isotope Effect Accompanying Electrochemical Insertion of Lithium into Liquid Gallium

Keita Zenzaia, Ayaka Yasuia, Satoshi Yanaseb, and Takao Oia

aFaculty of Science and Technology, Sophia University, 7-1 Kioicho, Chiyodaku, Tokyo 102-8554, Japan

bSamsung Yokohama Research Institute, 2-7Sugasawa-cho, Turumi-Ku, Yokohama 230-0027, Japan

Reprint requests to T. O.; Fax: +81-45-510-3368, E-mail: syan@ea.mbn.or.jp Z. Naturforsch.65a,461 – 467(2010); received September 7, 2009

Lithium was electrochemically inserted from a 1 : 2 (v/v) mixed solution of ethylene carbonate (EC) and methylethyl carbonate (MEC) containing 1 M LiClO4into liquid gallium to observe lithium isotope effects accompanying the insertion. It was observed that the lighter isotope6Li was prefer- entially fractionated into liquid gallium with the single-stage lithium isotope separation factorsS, ranging from 1.005 to 1.031 at 50◦C and 1.003 to 1.024 at 25◦C. The lithium isotope effects esti- mated by molecular orbital calculations at the B3LYP/6-311G(d) level of theory agreed qualitatively with those of the experiments, but the quantitative agreement of the two was not satisfactory.

Key words:Lithium Isotope Effects; Electrochemical Insertion; Gallium; Molecular Orbital Calculation; Reduced Partition Function Ratio.

Referenzen

Jetzt herunterladen ( PDF - 1 Seite - 22.49 KB )

ÄHNLICHE DOKUMENTE

Lithium Isotope Effects upon Electrochemical Release from Lithium Cobalt Oxide to Non-Lithium Electrolyte Solution

In the present study, we conducted experiments in which lithium atoms in the LiCoO 2 cathode were elec- trochemically released to a lithium-free electrolyte so- lution, a 1 : 2

Observation of Lithium Isotope Effects Accompanying Electrochemical Release from Lithium Cobalt Oxide Yuta Takami

Change in the lithium isotope composition in a lithium cobalt oxide (LiCoO 2 ) cathode for lithium ion secondary batteries accompanying the electrochemical lithium release from

A Theoretical Study of Lithium-Doped Gallium Clusters by Density Functional Theory

A square is turned out to be the most stable struc- ture of the Ga 4 cluster while the ground state of Ga 3 Li prefers a tetrahedral structure with the average bond length of 2.981 ˚

Lithium into Liquid Gallium

In the case of solid gallium, the gallium-lithium alloy is formed on the solid gallium surface and the solid-liquid mixed state does not exit, which may lead to the condition that

of Lithium into Graphite

The RPFR of this film is ex- pected to be close to that of the solvated lithium ion in the EC/MEC electrolyte solution because lithium in the film is derived from the lithium ion in

Retro 45 Lithium, V.2021 Art.-Nr EAN:

Der Rolektro Retro 45 Lithium, V.2021 ist ein hochwertig verarbeiteter Elektroroller, der maximalen Fahrspaß für 2 Personen bietet.. Die formschöne und ergonomische braune Sitzbank

Lithium

Besteht die Notwendigkeit für eine gemein- same Anwendung von Lithium und NSAR, sollten die Lithiumspiegel re- gelmäßig überprüft und wenn nötig durch eine Dosisreduktion angepasst

Hydrometallurgische Rückgewinnung von Lithium aus Lithium-Ionen-Batterien

 Abhebung von anderen Alkalimetallen durch spezifische Eigenschaften  Einsatz in Lithium- Ionen-Batterien.  Bedarf hat sich in den letzten Jahren