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Marine mineral exploration with controlled-source

1

electromagnetics at the TAG hydrothermal field, 26

N

2

Mid-Atlantic Ridge

3

R. A. S. Gehrmann1, L. A. North2, S. Graber3, F. Szitkar4, S. Petersen3, T.

4

A. Minshull1and B. J. Murton2

5

1University of Southampton, Ocean and Earth Sciences, National Oceanography Centre Southampton,

6

UK

7

2National Oceanography Centre, Natural Environment Research Council, Southampton, UK

8

3GEOMAR, Helmholtz Centre for Ocean Research Kiel, Germany

9

4Japan Agency for Marine-Earth Science Technology, JAMSTEC, Centre for Earthquakes and Tsunami,

10

Japan

11

Key Points:

12

Seafloor massive sulphide deposits can be detected/mapped on a large scale with

13

controlled source electromagnetic methods.

14

Multidisciplinary geophysical data analysis and local probing lead to a rigorous

15

interpretation of deposit dimensions and resource potential.

16

Sulphide ore content reduces with depth down to a few tens of meters into the de-

17

posit’s altered basalt and silica-dominated root.

18

Corresponding author: Romina Gehrmann,r.a.gehrmann@soton.ac.uk

This article has been accepted for publication and undergone full peer review but has not been through the copyediting, typesetting, pagination and proofreading process which may lead to differences between this version and the Version of Record. Please cite this article as doi:

10.1029/2019GL082928

(2)

Abstract

19

Seafloor massive sulphide (SMS) deposits are of increasing economic interest in order to

20

satisfy the relentless growth in worldwide metal demand. The Trans-Atlantic Geotra-

21

verse (TAG) hydrothermal field at 26N on the Mid-Atlantic Ridge hosts several such

22

deposits. This study presents new controlled source electromagnetic (CSEM), bathymet-

23

ric and magnetic results from the TAG field. Potential SMS targets were selected based

24

on their surface expressions in high-resolution bathymetric data. High-resolution reduced-

25

to-the-pole magnetic data show negative anomalies beneath and surrounding the SMS

26

deposits, revealing large areas of hydrothermal alteration. CSEM data, sensitive to the

27

electrical conductivity of SMS mineralization, further reveal a maximum thickness of up

28

to 80 m and conductivities of up to 5 S/m. SMS samples have conductivities of up to

29

a few thousand S/m, suggesting that remotely inferred conductivities represent an av-

30

erage of metal sulphide ores combined with silicified and altered host basalt that likely

31

dominates at greater depths.

32

Plain language summary

33

Seafloor massive sulphide deposits, formed by high-temperature hydrothermal activity,

34

provide a potential resource for metals including copper, zinc, lead, gold, and silver. Here,

35

we report the results of a geophysical study to estimate the distribution and size of seafloor

36

ore deposits at the Trans-Atlantic Geotraverse (TAG) hydrothermal field, located south

37

of the Azores, on the Mid-Atlantic Ridge (MAR). The TAG field hosts numerous deposits,

38

all but one of which are hydrothermally inactive. Inactive deposits are economically more

39

valuable but difficult to detect. Our solution is a combination of high-resolution seafloor

40

and sub-seafloor mapping techniques. By focusing on exploration using ship-towed elec-

41

tromagnetic sensing and autonomous underwater vehicle-based mapping and character-

42

isation of their magnetic field, we exploit unique signatures identifying these deposits from

43

their surrounding volcanic rock. These data enable us to delineate the extent of the de-

44

posits and provide a first estimate of their thickness. We integrate physical and chem-

45

ical properties of ore and host rock samples, recovered by drilling, into our interpreta-

46

tion in order to estimate the full economic potential of the deposits. Our results reveal

47

a deposit geometry consisting of a sulphide ore body that is mixed with an increasing

48

amount of silica and altered volcanic rocks at depth.

49

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1 Introduction

50

Seafloor massive sulphide (SMS) deposits are considered a potential resource for

51

economically valuable metals such as copper, zinc, lead, gold, silver as well as for trace

52

metals necessary for green or new technologies. Increasing global demand and insecure

53

supply on land lead many countries to target the deep sea for future mineral resources

54

(Hannington, Jamieson, Monecke, Petersen, & Beaulieu, 2011; Rona, 2003). While ac-

55

tive vent fields are dominantly explored using geochemical sensors that search for anoma-

56

lies in the water column, inactive fields do not exhibit such a prominent signature. In-

57

active SMS deposits, however, are estimated to contain a larger amount of metal sulphides,

58

and are characterized by the absence of high-temperature venting and the commonly as-

59

sociated low pH-values: two factors viewed as positive for possible mining operations (Han-

60

nington et al., 2011). The assessment of the quality and amount of SMS deposits suf-

61

ficient for resource calculations requires both fast and cost-effective remote exploration

62

to evaluate the distribution and size of the deposits, and localised drilling to understand

63

the resource potential of any given site.

64

The Trans-Atlantic Geotraverse (TAG) field (Figure 1), located at 2608’N, cov-

65

ering an area of about 5x5 km2 is the largest and best studied hydrothermal field on the

66

Mid-Atlantic Ridge (MAR). It hosts, in addition to the active TAG mound, several in-

67

active SMS deposits. Hydrothermal activity in the area may have started as early as 140 kyr

68

ago (Humphris et al., 1995). Radiometric data indicated that the formation of massive

69

sulphides at the active TAG mound started some 50 to 20 kyr ago with high-temperature

70

pulses every 5-6 kyr (Lalou, Reyss, Brichet, Rona, & Thompson, 1995). The inactive sul-

71

phide occurrences comprise the MIR zone, the oldest deposit, to the east of TAG mound,

72

and a number of mounds to the north of TAG mound in an area that was originally called

73

the Alvin zone (Rona et al., 1993). The Alvin zone includes the large Shinkai, South-

74

ern, Shimmering and Double Mound (White, Humphris, & Kleinrock, 1998) as well as

75

a series of smaller sulphide mounds (e.g., Rona Mound, Figure 1).

76

During summer 2016 an international and interdisciplinary survey with two back-

77

to-back cruises was conducted in the TAG hydrothermal field to study the geophysical

78

and geochemical signature of SMS deposits. The survey comprised high-resolution bathy-

79

metric mapping, and magnetic data acquisition from the autonomous underwater vehi-

80

cle (AUV) Abyss (GEOMAR), and controlled source electromagnetic (CSEM) experi-

81

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ments among others. Additionally, seafloor coring with the lander-type seafloor drilling

82

rig RD2 (British Geological Survey), and video imaging with the remotely operated ve-

83

hicle (ROV) HyBis (National Oceanography Centre) were also conducted. Physical and

84

chemical properties of the sulphide samples and sediment cores were measured shore-

85

side in the lab (Murton et al., 2019). Here, we present results from this work with em-

86

phasis on the towed CSEM study regarding SMS detection and size estimation.

87

The CSEM method is sensitive to contrasts in electrical conductivity. For exam-

88

ple, the largest component of an SMS deposits is expected to be precipitated sulphide

89

(e.g., pyrite, iron sulphide) which is a semiconductor. According to drilling results ob-

90

tained by the Ocean Drilling Program on TAG mound (Herzig, Humphris, Miller, & Zieren-

91

berg, 1998; Humphris et al., 1995) and RD2 drilling on the inactive mounds (Lehrmann,

92

Stobbs, Lusty, & Murton, 2018), the host rock underneath the deposits is likely to com-

93

prise less conductive fresh and hydrothermally altered basalts for which conductivity is

94

controlled by electrolytes (salt water) in the pore space. Due to the mound size (up to

95

a few hundreds of meters in diameter) and their potential for significant conductivity con-

96

trasts, SMS deposits may be detected with remote electromagnetic methods such as hor-

97

izontal dipole-dipole arrays (Cairns, Evans, & Edwards, 1996; Edwards & Chave, 1986;

98

Evans & Everett, 1994). Here, we present new CSEM data acquired over several kilo-

99

meters with a large footprint of up to a few hundred meters interpreted with comple-

100

mentary interdisciplinary data to solve the problem of reliable resource assessment for

101

SMS deposits.

102

2 Methods

103

2.1 Controlled Source Electromagnetics

104

The CSEM system presented here is comprised of the Deep-towed Active Source

105

Instrument (DASI, Sinha, Patel, Unsworth, Owen, & MacCormack, 1990) and two three-

106

axis electric field receivers (Vulcan, Constable, Kannberg, & Weitemeyer, 2016) towed

107

at 350 m and 505 m behind DASI. The DASI-Vulcan array was towed between 50 to 150 m

108

above the seafloor at a constant speed of 1 kn. An alternating square waveform with a

109

current amplitude of about 90 A, and a base frequency of 1 Hz was transmitted through

110

a 50-m long bipole antenna. Six multi-kilometer-long survey profiles were acquired across

111

the active TAG mound and several inactive SMS deposits (Figure 1).

112

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Data processing comprised a fast-Fourier transformation of 1-s long time windows,

113

deconvolution with the transmitter signal and stacking of 30-s long windows (Text S1,

114

Myer, Constable, & Key, 2011). Including navigational information, the amplitude of

115

the data for frequencies of 1 – 5 Hz were evaluated along each profile. There is no di-

116

rect way to interpret CSEM data for a heterogeneous seafloor conductivity model. In-

117

stead, the conductivity model below the seafloor must be inferred with inversion algo-

118

rithms. Here, we implement a two-dimensional (2D) inversion (MARE2DEM, Key, 2016):

119

a linearised scheme based on Occam’s razor, searching for the simplest model that can

120

explain the data (Text S1, Constable, Parker, & Constable, 1987). The final conductiv-

121

ity model favours gradual changes, and only includes abrupt changes between model cells

122

if the data sensitivity is high enough. Generally, data sensitivity reduces with increas-

123

ing depth but also depends on the assumed data error, which we have assessed with a

124

detailed error analysis using forward modelling that includes uncertainties caused by nav-

125

igation over rough terrain (Text S1). Also, an ambiguity arises between a thicker, less

126

conductive body and a thinner, more conductive body. In fact, the conductivity-thickness

127

product, the conductance, can often be better resolved (e.g., Edwards, 1997) than in-

128

dividual parameters alone. Despite this ambiguity, the inferred thickness does not de-

129

viate by more than a few tens of meters from the actual thickness because the model is

130

constrained by two receivers at different offsets to the source and three different frequen-

131

cies, allowing the dipole-dipole system to be sensitive to the less conductive material be-

132

low the sulphide ore body.

133

For each profile, the conductance is calculated as the integrated conductivity-thickness

134

product for 5 m intervals from the seafloor down to the the depth where conductivity

135

decreases to 1 S/m. We relate conductivities greater than 1 S/m to increasing amounts

136

of conductive metal sulphides mixed with less conductive seawater-saturated fresh and

137

altered basalts.

138

2.2 Bathymetry

139

The TAG hydrothermal field has been mapped with high-resolution (2 m, Figure 1)

140

bathymetric surveys using an AUV-based multibeam echosounder. The SMS mounds have

141

an almost circular base and a smooth to steep/rugged slope and confirm previous ob-

142

servations on lower resolution data (White et al., 1998). Examples of these mounds are

143

Shinkai, Southern and Double Mound (Figure 1) which are of conical shape. The MIR

144

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zone on the other hand has a more complex relief and a larger diameter. Inactive SMS

145

mounds can be easily mistaken with volcanic mounds which consist mainly of basalt, al-

146

though the latter have a more regular shape and have lower slope angles as is also the

147

case at Endeavour Ridge (Jamieson, Clague, & Hannington, 2014) .

148

2.3 Magnetics

149

The magnetic signature of the hydrothermal field (Szitkar & Dyment, 2015; Tivey,

150

Rona, & Kleinrock, 1996; Tivey, Rona, & Schouten, 1993) reveals a lack of magnetiza-

151

tion below the active and inactive mounds which is likely caused either by alteration of

152

the magnetic minerals of the upper crust during hydrothermal circulation and/or by the

153

volume filled with non-magnetic SMS deposits between the magnetometer and the oceanic

154

crust (Szitkar, Petersen, Caratori Tontini, & Cocchi, 2015). The magnetic data were recorded

155

with the triaxial flux-gate sensor mounted on the AUV while flown at different altitudes

156

between 20 and 100 m above the seafloor. Raw data were then adjusted for the effect

157

of the vehicle magnetic signature, low-pass filtered and interpolated on a grid. Finally,

158

magnetic anomalies were reduced-to-the-pole using the local inclination and declination

159

of the geomagnetic field to place them above their causative sources within the crust.

160

2.4 Rock Physics

161

Rock samples were collected from TAG (SMS and Jasper samples) either at out-

162

crops on the seafloor by ROV HyBis or during sub-seafloor drilling (RD2, Lehrmann

163

et al., 2018). These were supplemented by reference samples from outcrops on land (e.g.,

164

basalt from Cyprus). Samples where the electrical conductivity mechanism is dominated

165

by ionic conduction in pore space (i.e., non-SMS samples) were measured with an ionic

166

conductivity cell based on the device described by Zisser and Nover (2009). Because this

167

configuration is susceptible to measurement artefacts caused by double layer polarisa-

168

tion at any semiconductor (such as metal sulphides) to electrolyte interface (Stojek, 2010),

169

the sulphide samples were measured using direct contact and/or inductive methods (Text

170

S2).

171

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3 Results

172

Inferred conductances are elevated for all known inactive deposits in the MIR and

173

Alvin zone as well as the active TAG mound and coincide with negative reduced-to-the-

174

pole magnetic anomalies (Figure 2). The observed CSEM data are fit well by the mod-

175

els (Figure S2), but biases remain, that are likely due to systematic errors such as the

176

rough topography and the 3D characteristics of the SMS target given the large footprint

177

of the DASI-Vulcan array. A 2D inversion of data from a conical 3D structure may re-

178

sult in biases in the predicted vs. observed data and the inversion model may contain

179

artefacts below and next to the mound structure, but the elevated conductivity within

180

the mound can still be resolved adequately (Haroon et al., 2018).

181

3.1 MIR zone

182

The MIR zone is located 4 km east off the MAR axis and covers a large area (∼1 km

183

in diameter) with the only mound-like feature being<10 m high. Elevated heat-flow val-

184

ues (Rona et al., 1996) indicate a late stage of hydrothermal activity. From the inferred

185

final conductivity model for the North-South profile over the MIR zone (Figure 3b), a

186

50-m thick, elongate, conductive anomaly is present immediately beneath the seafloor.

187

The magnetic profile for the profile across the MIR zone (Figure 3a) is interpolated

188

from the reduced-to-the-pole magnetic map (Figure 2). A negative magnetic anomaly

189

encompasses the maximum of the conductance (Figure 3c) along the profile. For most

190

other SMS deposits, the highest conductances reside within the much larger areal extents

191

of the magnetic anomalies that often connect adjacent deposits.

192

Although the CSEM method is sensitive to resistivity contrasts at the base of the

193

sulphide deposit (Note: model cells with low data sensitivity are blanked out in Figure 3b),

194

a strong conductivity contrast is not typically resolved because the sulphide content likely

195

changes gradually with depth and because the inversion algorithm also favours smooth

196

transitions.

197

3.2 Alvin zone

198

The Alvin zone (Rona et al., 1993) encompasses the northern part of the hydrother-

199

mal field including Shinkai, Southern, Double, Rona and Shimmering Mound. Shinkai,

200

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target #20, Southern, Double and the newly identified Abyss Mound all exhibit distinct

201

conductivity anomalies with conductivities up to 5 S/m (Figure 4a). The root of the mounds

202

is expected to extend much deeper but the denser silica-rich wall-rock breccia and chlo-

203

ritized basalts tend to have much lower conductivities than the SMS deposits (Morgan,

204

2012). Seismic imaging of Shinkai and Southern Mound also support a deep reaching root

205

(∼220 m) consisting roughly of massive sulphide on top (∼first 100 m) and a stockwork

206

of brecciated sulphide, silica and altered basalt underneath (Murton et al., 2019). The

207

SMS deposit at Southern mound is inferred to be up to 80 m thick based on the CSEM

208

data alone (Figure 4a) with an average conductivity of 3.7 S/m. A conductance of up

209

to 300 S could also be translated in a thinner deposit of, for example, 60 m with an av-

210

erage conductivity of 5 S/m. Structures smaller than a few tens of meters are at the limit

211

of resolution, so that a thin 10 m deposit of conductive material on top of the mound

212

would appear as a thicker but less conductive cone top (Haroon et al., 2018). Southern

213

mound has also been studied with the coincident-loop system MARTEMIS, which is more

214

downward looking and has a much smaller footprint than the towed CSEM system, and

215

is more sensitive to conductive deposits with a higher vertical resolution but with a max-

216

imum penetration depth of about 50 m (Haroon et al., 2018; H¨olz & Jegen, 2016). The

217

1D inversion results of the MARTEMIS data reveal higher conductivities up to 10 S/m

218

for the upper∼50 m below the mound’s surface. Combining these observations suggests

219

that the top of the deposit has a higher percentage of metal sulphides than the deeper

220

sections.

221

The newly identified Abyss Mound SMS occurrence was verified by video obser-

222

vations (Petersen et al., 2016), and the presence of metalliferous sediments supports a

223

past history of hydrothermal activity (Dutrieux et al., 2017). Geological and geochem-

224

ical ground-truthing therefore strengthens the interpretation based on bathymetry, CSEM

225

and magnetics. The area to the north of Shimmering Mound (Figure 1) still shows some

226

low-temperature hydrothermal activity (Rona et al., 1998) but was not sampled during

227

our survey. A strong magnetic low and elevated conductivities, however, indicate hydrother-

228

mal deposition around an unnamed mound (#7 in Humphris, Tivey, & Tivey, 2015). Tar-

229

get #20 next to Shimmering Mound also shows high conductivities seemingly belong-

230

ing to the same hydrothermal system.

231

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3.3 Active TAG mound

232

The TAG Mound is the only active mound in the TAG hydrothermal field. The

233

negative magnetic anomaly extends west of TAG and coincides with other bathymetry-

234

inferred targets. TAG Mound has much lower inferred conductivities of up to 2 S/m than

235

the inactive SMS mounds (Figure 4b). The active mound is different to the inactive mounds

236

in three ways. The temperatures are distinctly higher (up to 360C) which could poten-

237

tially increase the conductivities of the sulphides and pore fluids. On the other hand,

238

it is anhydrite rich, which has a lower conductivity than sulphides, but dissolves at lower

239

temperatures and is hence not present in the inactive mounds. The third difference is

240

its smaller size (estimates of 2.7 million tonnes for TAG Mound (Hannington, Galley,

241

Herzig, & Petersen, 1998) compared to up to 6.3 million tonnes for Southern Mound (Mur-

242

ton et al., 2019)). CSEM experiments in the 1990s at the TAG active mound with smaller

243

transmitter-receiver spacings (<100 m) showed average conductivities (for homogeneous

244

seafloor) of up to 16 S/m (Cairns et al., 1996), similar to the conductivities for a sim-

245

ilar penetration depth of the MARTEMIS system at the inactive deposits (Haroon et

246

al., 2018), suggesting that the lower inferred conductivities with the DASI-Vulcan sys-

247

tem at the TAG mound are more likely caused by the target size compared to the transmitter-

248

receiver spacing. The DASI-Vulcan system averages over a larger footprint and depth,

249

and the adjacent altered basalt and increasing amount of silicate with depth likely im-

250

pacts the large-scale inferred conductivity compared to the short-offset, high-resolution

251

methods. In fact, the geometry of the DASI-Vulcan array was chosen for fast, continuously-

252

towed, data collection over several kilometers with a wide footprint to detect SMS de-

253

posits large enough to be of economic interest.

254

3.4 Rock Physics

255

Conductivity measurements in the laboratory were made on five SMS samples col-

256

lected on the seafloor by the ROV HyBis, or recovered as core drilled by RD2 (Figure 1).

257

The conductivities of SMS samples are up to five orders of magnitude higher than the

258

reference basalt samples from outcrops on Cyprus, and although they have lower porosi-

259

ties (Figure 4c), they have the electrical conduction behavior characteristic of semicon-

260

ductors/metals. By comparison, for the case of electrolytic conduction, the conductiv-

261

ity is directly related to the porosity of the sample (e.g., Archie’s Law, Archie, 1942).

262

This relationship does not hold for SMS deposits, which act as semiconductors causing

263

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the conductivities to be orders of magnitude higher and display complex behavior due

264

to their frequency-dependent chargeability (Spagnoli et al., 2016; Spagnoli, Weymer, Je-

265

gen, Spangenberg, & Petersen, 2017). Samples from the Central Indian Ridge show sim-

266

ilar behavior with a clear frequency dependence, e.g., larger conductivities at higher fre-

267

quencies (M¨uller et al., 2018). Here, the conductivities for the pure SMS samples are about

268

three orders of magnitude larger than the conductivities inferred from the remote DASI-

269

Vulcan array suggesting that the SMS deposits are locally richer and can be found at

270

shallow depth below the surface but are likely mixed with silicates and altered basalts

271

at greater depth. The results inferred from the DASI-Vulcan array average over the mound

272

and cannot resolve features and structure at scales of less than a few tens of meters.

273

4 Discussion and Conclusions

274

We have presented how remote geophysical techniques have been successfully im-

275

plemented to detect and localize SMS deposits in the TAG hydrothermal field. The deep-

276

towed controlled source electromagnetic DASI-Vulcan experiment has been used to cover

277

several-kilometer long profiles with a lateral footprint of up to a few hundred meters across

278

potential targets, some of which have been verified geologically before by localized sam-

279

pling and video observations, while others were only recognized as potential targets from

280

their shape (multi-beam mapping). The CSEM data have confirmed known deposits and

281

revealed previously uncertain ones. The inferred deposit thickness of up to 80 m is a max-

282

imum value as the inversion favours low conductivity gradients. Although the CSEM sys-

283

tem is sensitive to the conductivity contrast between the pyrite-dominated SMS cap and

284

the silicate-dominated stockwork, the product of thickness and conductivity can often

285

be better resolved than individual parameters alone. Inferred conductivities reach up to

286

5 S/m, indicating the presence of semi-conductors. The inferred values, however, are gen-

287

erally orders of magnitude lower than the conductivities of lab samples composed of pyrite

288

with interconnected chalcopyrite. These lab samples were collected at the SMS deposits

289

themselves and can reach conductivities of up to a few thousand S/m. The remotely in-

290

ferred values are therefore average conductivities for volumes larger than a few hundreds

291

of cubic meters likely with decreased connectivity. Although the inferred conductivity

292

structure is limited in resolution of a few tens of meters, the conductivity anomalies are

293

generally localised to the deposit. In comparison, negative magnetic anomalies gener-

294

ally extend over larger areas than the deposit footprint because magnetic data are sen-

295

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sitive to the nonmagnetic SMS deposit itself, and to the hydrothermally-demagnetized

296

stockwork and fault zones that surround and underlay the deposits at greater depth. High-

297

resolution magnetics is therefore an indicator for where hydrothermal circulation was ac-

298

tive on a larger scale. Sulphide deposits also have distinct surface expressions such as

299

conical mounds and rough small-scale topography which can be interpreted with high-

300

resolution bathymetry as long as the deposits are not overprinted with sedimentation

301

or lava flows (camouflaged among volcanic, hummocky, mounds). Each of the geophys-

302

ical methods alone provide a piece to the puzzle, that evaluated individually may lead

303

to ambiguous interpretations, but together lead to a robust interpretations of the SMS

304

potential.

305

In this work, we studied several inactive deposits up to∼4 km from the ridge axis

306

as well as the active TAG Mound. TAG Mound shows lower conductivities than seawa-

307

ter, but is also smaller than most of the inactive deposits. Previous studies with a seafloor

308

EM transmitter and receiver spacings of<100 m (Cairns et al., 1996) revealed higher

309

conductivities (up to∼16 S/m), similar to the conductivities for a similar penetration

310

depth of the MARTEMIS system at the inactive deposits (Haroon et al., 2018) which

311

suggests that the generally lower conductivities observed with the DASI-Vulcan system

312

at TAG are probably related to the deeper penetration depth due to the larger transmitter-

313

receiver spacing (350 and 505 m), and resulting averaging between highly conductive ma-

314

terial just beneath the seafloor and less conductive stockwork material at greater depth.

315

The smaller size of the TAG Mound compared to the inactive deposits may in this case

316

play a larger role than the possible effects of anhydrite (Lehrmann et al., 2018; Murton

317

et al., 2019) and hot fluids (∼360C) which are only present in the active system.

318

To estimate the economic value of each deposit, it is essential to quantify the sub-

319

seafloor geometry and probe the seafloor to understand the overall evolution of the de-

320

posit. Lander-type drilling shows that the content of valuable elements such as copper

321

and zinc likely decreases with depth due to element remobilizing during the waning phase

322

of hydrothermal activity (Lehrmann et al., 2018). The rich content of copper and zinc

323

in surface samples and metalliferous sediments (Dutrieux et al., 2017) therefore does not

324

represent the element concentration at depth. The elevated conductivities at greater depths

325

might be caused by a large concentration of pyrite, which has no economic value (Mur-

326

ton et al., 2019). The deposit maximum thickness from CSEM extending beneath the

327

base of the mounds on the seafloor supports the findings of Teagle and Alt (2004) that

328

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basaltic crust becomes heavily altered to secondary minerals such as silicates and chlo-

329

rites with SMS inclusions.

330

We have shown that bathymetry, magnetic and CSEM surveys are sensitive to dif-

331

ferent physical aspects of the deposits and therefore complement each other with a high

332

success rate for detection and characterization of inactive deposits.

333

Acknowledgments

334

We would like to thank the European Commission for funding the Framework 7 project

335

Blue Mining (Grant Number 604500). We thank all cruise participants and crew from

336

M127 and JC138 for their support in data acquisition especially Ian Tan, Sebastian H¨olz,

337

Eric Attias, and Geomar’s AUV Abyss team. We thank Karen Weitemeyer and Steve

338

Constable for their advice. We thank Ben Ollington, McKinley Morton and Amir Ha-

339

roon for their work with the data set. We thank Kerry Key for the inversion code MARE2DEM

340

and supporting matlab scripts as well as David Myer for processing routines and discus-

341

sions. Tim Minshull was supported by a Wolfson Research Merit award. We thank Mar-

342

ion Jegen for internally reviewing the article and two anonymous reviewers for their help-

343

ful comments to improve the manuscript. Data are available from Gehrmann (2019); Gehrmann,

344

North, Lehrmann, and Murton (2019); Petersen (2019).

345

References

346

Archie, G. E. (1942). The Electrical Resistivity Log as an Aid in Determining Some

347

Reservoir Characteristics. Trans. Am. Inst. Min. Metall. Pet. Eng.,146, 54-

348

62.

349

Cairns, G. W., Evans, R. L., & Edwards, R. N. (1996). A time domain electromag-

350

netic survey of the TAG Hydrothermal Mound. Geophysical Research Letters,

351

23(23), 3455-3458. doi: 10.1029/96GL03233

352

Constable, S. C., Kannberg, P. K., & Weitemeyer, K. (2016). Vulcan: A deep-towed

353

CSEM receiver. Geochemistry, Geophysics, Geosystems,17(3), 1042–1064. doi:

354

10.1002/2015GC006174

355

Constable, S. C., Parker, R. L., & Constable, C. G. (1987). Occam’s inversion: A

356

practical algorithm for generating smooth models from electromagnetic sound-

357

ing data. Geophysics,52, 289-300.

358

Dutrieux, A., Lichtschlag, A., Murton, B. J., Petersen, S., Barriga, F., & Martins, S.

359

(13)

(2017). Metal mobilization in hydrothermal sediments. Paper presented at 49th

360

Underwater Mining Conference, Berlin, Germany.

361

Edwards, R. N. (1997). On the resource evaluation of marine gas hydrate deposits

362

using sea-floor transient electric dipole-dipole methods. Geophysics,62(1), 63-

363

74.

364

Edwards, R. N., & Chave, A. D. (1986). A transient electric dipole-dipole method

365

for mapping the conductivity of the sea floor. Geophysics,5(4), 984-987.

366

Evans, R. L., & Everett, M. E. (1994). Discrimination of hydrothermal mound struc-

367

tures using transient electromagnetic methods. Geophysical Research Letters,

368

21(6), 501-504. doi: 10.1029/94GL00418

369

Gehrmann, R. A. S. (2019). Controlled-source electromagnetic data from the TAG

370

hydrothermal field, 26N Mid-Atlantic Ridge.[data set]. PANGAEA. Retrieved

371

fromhttps://doi.pangaea.de/10.1594/PANGAEA.899073

372

Gehrmann, R. A. S., North, L. J., Lehrmann, B., & Murton, B. J. (2019). Rock

373

physic samples from TAG, Mid-Atlantic Ridge, and various onshore samples

374

[data set]. PANGAEA. Retrieved fromhttps://doi.pangaea.de/10.1594/

375

PANGAEA.899411

376

Hannington, M. D., Galley, A. G., Herzig, P. M., & Petersen, S. (1998). 28. Com-

377

parison of the TAG mound and stockwork complex with Cyprus-type mas-

378

sive sulfide deposits. InProceedings-ocean drilling program scientific results

379

(Vol. 158, pp. 389–415).

380

Hannington, M. D., Jamieson, J., Monecke, T., Petersen, S., & Beaulieu, S. (2011).

381

The abundance of seafloor massive sulfide deposits. Geology, 39(12), 1155–

382

1158. doi: 10.1130/G32468.1

383

Haroon, A., H¨olz, S., Gehrmann, R. A., Attias, E., Jegen, M., Minshull, T. A., &

384

Murton, B. (2018). Marine Dipole-Dipole Controlled Source Electromag-

385

netic and Coincident-Loop Transient Electromagnetic Experiments to Detect

386

Seafloor Massive Sulphides: Effects of Three-Dimensional Bathymetry. Geo-

387

physical Journal International,215(3), 2156–2171. doi: 10.1093/gji/ggy398

388

Herzig, P. M., Humphris, S. E., Miller, D. J., & Zierenberg, R. A. (1998).

389

Proceedings-ocean drilling program scientific results (Vol. 158). College Sta-

390

tion, Texas, Ocean Drilling Program. doi: 10.2973/odp.proc.sr.158.1998

391

H¨olz, S., & Jegen, M. (2016). How to Find Buried and Inactive Seafloor Mas-

392

(14)

sive Sulfides Using Transient EM-A Case Study from the Palinuro Seamount.

393

Paper presented at EAGE/DGG Workshop on Deep Mineral Exploration,

394

M¨unster, Germany.

395

Humphris, S. E., Herzig, P. M., Miller, D. J., Alt, J. C., Becker, K., Brown, D., . . .

396

Zhao, X. (1995). The internal structure of an active sea-floor massive sulfide

397

deposit. Nature,377, 713–716.

398

Humphris, S. E., Tivey, M. K., & Tivey, M. A. (2015). The Trans-Atlantic Geo-

399

traverse hydrothermal field: A hydrothermal system on an active detachment

400

fault. Deep Sea Research Part II: Topical Studies in Oceanography,121, 8–16.

401

Jamieson, J., Clague, D., & Hannington, M. D. (2014). Hydrothermal sulfide accu-

402

mulation along the Endeavour Segment, Juan de Fuca Ridge. Earth and Plane-

403

tary Science Letters,395, 136–148.

404

Key, K. (2016). MARE2DEM: A 2-D inversion code for controlled-source electro-

405

magnetic and magnetotelluric data. Geophysical Journal International,207(1),

406

571–588.

407

Lalou, C., Reyss, J.-L., Brichet, E., Rona, P. A., & Thompson, G. (1995). Hy-

408

drothermal activity on a 105-year scale at a slow-spreading ridge, TAG hy-

409

drothermal field, Mid-Atlantic Ridge 26 N. Journal of Geophysical Research:

410

Solid Earth, 100(B9), 17855–17862.

411

Lehrmann, B., Stobbs, I., Lusty, P., & Murton, B. J. (2018). Insights into extinct

412

seafloor massive sulfide mounds at the tag, mid-atlantic ridge. Minerals,8(7),

413

302.

414

Morgan, L. A. (2012). Geophysical characteristics of volcanogenic massive sulfide de-

415

posits. Volcanogenic Massive Sulfide Occurrence Model. US Geological Survey,

416

Reston, VA,115, 131.

417

M¨uller, H., Schwalenberg, K., Reeck, K., Barckhausen, U., Schwarz-Schampera, U.,

418

Hilgenfeldt, C., & von Dobeneck, T. (2018). Mapping seafloor massive sul-

419

fides with the Golden Eye frequency-domain EM profiler. First Break,36(11),

420

61–67.

421

Murton, B. J., Lehrmann, B., Dutrieux, A. M., Martins, S., de la Iglesia, A. G., Sto-

422

bbs, I. J., . . . Petersen, S. (2019). Geological fate of seafloor massive sulphides

423

at the TAG hydrothermal field (Mid-Atlantic Ridge). Ore Geology Review,in

424

press.

425

(15)

Myer, D., Constable, S., & Key, K. (2011). Broad-band waveforms and robust pro-

426

cessing for marine CSEM surveys. Geophys. J. Int.,184, 689–698.

427

Petersen, S. (2019). Bathymetric data products from AUV dives during METEOR

428

cruise M127 [data set]. PANGAEA. Retrieved fromhttps://doi.pangaea

429

.de/10.1594/PANGAEA.899415

430

Petersen, S., Kr¨atschell, A., Augustin, N., Jamieson, J., Hein, J. R., & Hannington,

431

M. D. (2016). News from the seabed – Geological characteristics and resource

432

potential of deep-sea mineral resources. Marine Policy,70, 175–187.

433

Rona, P. A. (2003). Resources of the sea floor. Science,299(5607), 673–674.

434

Rona, P. A., Fujioka, K., Ishihara, T., Chiba, H., Masuda-Nakaya, H., Oomori, T.,

435

. . . Lalou, C. (1998). An active, low temperature hydrothermal mound and

436

a large inactive sulfide mound found in the TAG hydrothermal field, Mid-

437

Atlantic Ridge 26N, 45W. EOS,79, F920.

438

Rona, P. A., Hannington, M. D., Raman, C. V., Thompson, G., Tivey, M. K.,

439

Humphris, S. E., . . . Petersen, S. (1993). Active and relict sea-floor hy-

440

drothermal mineralization at the TAG hydrothermal field, Mid-Atlantic Ridge.

441

Economic Geology,88(8), 1989–2017.

442

Rona, P. A., Petersen, S., Becker, K., Von Herzen, R. P., Hannington, M. D., Herzig,

443

P. M., . . . Thompson, G. (1996). Heat flow and mineralogy of TAG Relict

444

High-Temperature Hydrothermal Zones: Mid-Atlantic Ridge 26N, 45W. Geo-

445

physical Research Letters, 23(23), 3507–3510.

446

Sinha, M., Patel, P., Unsworth, M., Owen, T., & MacCormack, M. (1990). An ac-

447

tive source electromagnetic sounding system for marine use. Marine Geophysi-

448

cal Researches,12(1-2), 59–68.

449

Spagnoli, G., Hannington, M. D., Bairlein, K., H¨ordt, A., Jegen, M., Petersen, S.,

450

& Laurila, T. (2016). Electrical properties of seafloor massive sulfides. Geo-

451

Marine Letters,36(3), 235–245.

452

Spagnoli, G., Weymer, B. A., Jegen, M., Spangenberg, E., & Petersen, S. (2017). P-

453

wave velocity measurements for preliminary assessments of the mineralization

454

in seafloor massive sulfide mini-cores during drilling operations. Engineering

455

Geology,226, 316–325.

456

Stojek, Z. (2010). The electrical double layer and its structure. InElectroanalytical

457

methods (pp. 3–9). Springer.

458

(16)

Szitkar, F., & Dyment, J. (2015). Near-seafloor magnetics reveal tectonic rotation

459

and deep structure at the TAG (Trans-Atlantic Geotraverse) hydrothermal site

460

(Mid-Atlantic Ridge, 26 N). Geology,43(1), 87–90.

461

Szitkar, F., Petersen, S., Caratori Tontini, F., & Cocchi, L. (2015). High-resolution

462

magnetics reveal the deep structure of a volcanic-arc-related basalt-hosted

463

hydrothermal site (Palinuro, Tyrrhenian Sea). Geochemistry, Geophysics,

464

Geosystems,16(6), 1950–1961.

465

Teagle, D. A., & Alt, J. C. (2004). Hydrothermal alteration of basalts beneath

466

the Bent Hill massive sulfide deposit, Middle Valley, Juan de Fuca Ridge. Eco-

467

nomic Geology,99(3), 561–584.

468

Tivey, M. A., Rona, P. A., & Kleinrock, M. C. (1996). Reduced crustal mag-

469

netization beneath relict hydrothermal mounds: TAG hydrothermal field,

470

Mid-Atlantic Ridge, 26 N. Geophysical Research Letters,23, 3511–3514.

471

Tivey, M. A., Rona, P. A., & Schouten, H. (1993). Reduced crustal magnetization

472

beneath the active sulfide mound, TAG hydrothermal field, Mid-Atlantic Ridge

473

at 26 N. Earth and Planetary Science Letters,115(1-4), 101–115.

474

White, S. N., Humphris, S. E., & Kleinrock, M. C. (1998). New Observations on

475

the Distribution of Past and Present Hydrothermal Activity in the TAG Area

476

of the Mid-Atlantic Ridge (26°08’ N). Marine Geophysical Researches,20(1),

477

41–56. doi: 10.1023/A:1004376229719

478

Zisser, N., & Nover, G. (2009). Anisotropy of permeability and complex resistivity

479

of tight sandstones subjected to hydrostatic pressure. Journal of Applied Geo-

480

physics,68(3), 356–370.

481

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Figure 1. High-resolution (2 m) bathymetry map of the TAG hydrothermal field at the MAR (white star in overview map): Bathymetry from the AUV Abyss survey (Petersen et al., 2016) overlain by its hill shading (lit from the NNW). White liner mark SMS targets identified from the bathymetry. The red stars are the location of samples for which physical properties were mea- sured. The neovolcanic zone is about 2 km to the NW of the map. The black lines are the CSEM survey lines.

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Figure 2. Reduced-to-the-pole magnetic anomaly map overlain by bathymetry hill shading, conductance for six profiles, and highlighted SMS deposits identified from the bathymetry and verified with video footage or sampling.

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Figure 3. Reduced-to-the-pole magnetic anomaly interpolated from map shown in Figure 2;

b: The 2D inversion results for CSEM profile across the MIR zone, overlain by data sensitivity, and positions of transmitter (circles) and receivers (triangles) in the water column; c: Conduc- tance estimated from b for conductivities above 1 S/m (yellow contour).

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Shinkai Southern

#20

Abyss Double

TAG a

b c

Figure 4. a: Conductivity models across mounds Shinkai, Southern, Abyss, Double and #20;

b: Conductivity models across TAG mound; c: Porosity vs. conductivity of selected samples from TAG (stars) and other sources (rectangles) for basalt, sulphide and jasper (a thin,<1 m, silicate-based layer above the sulphides, Lehrmann et al., 2018) samples; the Hashin Shtrik- man upper bound (solid line) separates the main conduction mode via electrolytes (left) and metals/semiconductors (right), and the dashed line represents Archie’s law approximation for electrolytic conduction in hard rock (Evans & Everett, 1994; M¨uller et al., 2018) with a = 1 and m = 1.8.

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Shinkai Southern Double Abyss

TAG

b c

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Shinkai Southern Double Abyss

TAG

b c

Abbildung

Figure 1. High-resolution (2 m) bathymetry map of the TAG hydrothermal field at the MAR (white star in overview map): Bathymetry from the AUV Abyss survey (Petersen et al., 2016) overlain by its hill shading (lit from the NNW)
Figure 2. Reduced-to-the-pole magnetic anomaly map overlain by bathymetry hill shading, conductance for six profiles, and highlighted SMS deposits identified from the bathymetry and verified with video footage or sampling.
Figure 3. Reduced-to-the-pole magnetic anomaly interpolated from map shown in Figure 2;
Figure 4. a: Conductivity models across mounds Shinkai, Southern, Abyss, Double and #20;

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