• Keine Ergebnisse gefunden

Formation of Methylchloroaluminium Alkanethiolates, MeAl(SR)Cl, and Dichloroaluminium Alkanethiolates, Cl2

N/A
N/A
Info
Herunterladen
Protected

Academic year: 2022

Aktie "Formation of Methylchloroaluminium Alkanethiolates, MeAl(SR)Cl, and Dichloroaluminium Alkanethiolates, Cl2"

Copied!
1
0
0

Wird geladen.... (Jetzt Volltext ansehen)

Jetzt herunterladen ( 1 Seite )

Volltext

(1)

Formation of Methylchloroaluminium Alkanethiolates, MeAl(SR)Cl, and Dichloroaluminium Alkanethiolates, Cl

2

AlSR, from Methylaluminium Dichloride and Trimethylsilyl Alkanethiolates, Me

3

SiSR

Gerhard G. Hoffmann

Institut für Erdöl- und Erdgasforschung, Walther-Nernst-Str. 7, D-38678 Clausthal-Zellerfeld, Germany. E-mail: Gerhard.Hoffmann@tu-clausthal.de

Dedicated to Prof. Dr. Dr. h.c. Max Schmidt on the occasion of his 75thbirthday Z. Naturforsch.55 b,1195Ð1198(2000); received August 22, 2000

Methylchloroaluminium Alkanethiolates, Dichloroaluminium Alkanethiolates

Depending on the reaction conditions methylaluminium dichloride, MeAlCl2, and trime- thylsilyl alkanethiolates, Me3SiSR, give dichloroaluminium alkanethiolates, Cl2AlSR with R = Me and Et or methylchloroaluminium alkanethiolates, MeAl(SR)Cl with R = Me, Et, andi-Pr. The reaction pathways are described and IR and1H NMR spectroscopic data are presented.

Referenzen

Jetzt herunterladen ( PDF - 1 Seite - 21.83 KB )

ÄHNLICHE DOKUMENTE

Crystal chemistry of the mendipite-type system Pb(3)O(2)Cl(2)-Pb(3)O(2)Br(2)

Lead oxyhalides / Mendipite / Oxocentered tetrahedra / Conformation / Single crystal structure analysis / X-ray

Oxides/ ions mol% BA-0 BA-Cl BA-Cl-2 BA-Cl-3 BA-Cl-4 BA-Cl-F BA-Cl-F-2 BA-Cl-F-3 BA-F BA-F-2

Table II: Analysis of redox equilibrated halogen-free and -bearing glasses (electron microprobe).. The measurement of each glass is based on average of 10 measurements with

TEM and CL of semiconducting 1D nanostructures

The nucleation of the bulk cubic (zinc blende) crystal phase along the wurtzite arms of ZnO tetrapods grown through a vapour-solid mechanisms has been observed for the first

2 Mg 012 + H20 2 Cl—Mg—O—Mg—Cl + 2 HCI

Laßt man Kohlensäure im Über- schuß auf in Wasser suspendierte Magnesia einwirken, so erhält man eine Lösung von saurem Karbonat Diese dissoziiert sich allmählich und geht in

Si-C bond activation in the reaction of first generation Grubbs' catalyst with alkynylsilanes - formation of [Cl2{P(C6H11)3}2Ru(=CHCH=CHPh)] and disiloxanes

In the last stage of the sequence (Scheme 5) the alkylidyne complex immediately reacts with hydrochloride to form complex 3, The formation of a ruthenium alkylidene

On the Formation and

The reaction of N,N -diaryl-substituted formamides with oxalyl chloride gives rise, instead to the formation of the expected salt-like formamide chlorides, to the formation

Cl NQR Study of Phase Soliton Formation and Residual Commensurations in K2

The rotational dynamics of each tetrahedral group in the lock-in phase appears to ex- plain the residual commensuration from the Cl(1)-1, and the phase soliton formation from the

COCl + Cl — ^-»COCl, + Cl

a) Verwenden Sie Quasistationarität für die Radikale Cl und COCl um das differentielle Geschwindigkeitsgesetz für die Bildung von COCI 2 zu finden. Die Ratengleichung soll