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Problem 15: Harmonic oscillator coupled to 2-state system 2+1 = 3 points A one-dimensional harmonic oscillator and a 2-state system are described by H

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(1)

Prof. Andreas Wipf, MSc. Marc Steinhauser November 27, 2019

Problem sheet „Advanced Quantum Mechanics“

winter term 2019/20

Sheet 7

Problem 15: Harmonic oscillator coupled to 2-state system 2+1 = 3 points A one-dimensional harmonic oscillator and a 2-state system are described by H

0

= ℏ ω

0

a

a + εσ

z

. The two systems are coupled by the interaction V (t) = g(σ

+

a + σ

a

)e

ηt

. The total Hamiltonian is given by H = H

0

+ V (t).

1. Calculate in first order perturbation theory the transition rate from the state | n ⟩ ⊗ | ↑⟩ into the state |n + 1⟩ ⊗ | ↓⟩ of the unperturbed Hamiltonian H

0

. Choose as lower integration limit t = −∞ .

2. What happens to the transition rate in the limit η 0?

Problem 16: H-atom between the plates of a capacitor 1+3=4 points A hydrogen atom in its ground state is placed between two parallel plates of a capacitor. An impulse voltage produces a spatially homogeneous electric pulse

E (t) = E

0

θ(t) e

t/τ

e

z

, τ > 0,

between the plates, and orthogonal to them (parallel to the z-axis with unit vector e

z

). Calculate in first order perturbation theory the transition probability, that the atom at t > 0 is

1. in the 2s state

2. in one of the 2p states.

What happens for τ → ∞?

Hint: You might need the explicit form of some of the following wave functions of the Hydrogen atom

r | nℓm = R

nℓ

(r)Y

ℓm

(θ, φ):

R

10

(r) = 2

a

3/2

e

r/a

, R

20

(r) = 2

(2a)

3/2

(1 r/2a)e

r/2a

, R

21

(r) = 1

3(2a)

3/2

r

a e

r/2a

,

Y

00

(θ, φ) = 1 2

√ 1

π , Y

10

(θ, φ) = 1 2

√ 3

π cos θ, Y

1±1

(θ, φ) = 1 2

√ 3

2π sin θe

±iφ

.

Problem 17: Rabi oscillations 3+2+1=6 points

Given is the Hamilton operator H(t) = H

0

+ V (t) with

H

0

= E

1

| 1 ⟩⟨ 1 | + E

2

| 2 ⟩⟨ 2 | , V (t) = ℏ ω

0

e

iωt

| 1 ⟩⟨ 2 | + ℏ ω

0

e

iωt

| 2 ⟩⟨ 1 | ,

with positive ω, ω

0

> 0 and with E

2

> E

1

. The two states |1⟩, |2⟩ form an orthonormal basis of the Hilbert space. Find the state | ψ(t) , which solves the Schrödinger equation

iℏ

∂t |ψ(t)⟩ = H|ψ(t)⟩

with initial condition | ψ(t = 0) = | 1 .

(2)

1. Find the exact solution of the problem. To find the solution you may

Study the time evolution of the state | ψ(t) in the base | n : | ψ(t) = c

1

(t)e

iE1t/

| 1 + c

2

(t)e

iE2t/

| 2 . Which initial conditions fulfill the coefficients c

1

(t) and c

2

(t)?

Insert the state vector | ψ(t) into the Schrödinger equation. You will obtain two coupled differential equations for c

1

(t) and c

2

(t).

Solve these equations.

2. Solve the problem in first order perturbation theory.

3. Compare the perturbative result with the exact solution.

Submission date: Thursday, 05.12.2019, before the lecture

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