Synthesis and Characterization of a Three-dimensional Porous Compound: [Cu(H2

The potassium cations are found to adopt two types of coordination geometry with the malonate ligand, the bidentate hydroxylamido ligand and water molecules: the first one

Sub- sequently, the two types of groups became tied to- gether through interconnecting corners, forming a new cluster [H 2 W 12 O 42 ] 10− ; (ii) structural feature of the

Each copper atom has an elongated octahedral geometry with the two nitrogen atoms and the mutu- ally cis O carboxylate atoms equatorial and the two α - hydroxyl oxygen atoms axial,

Four THF molecules and two oxygen atoms of terminal CO ligands of different anions span the coordination sphere of the sodium cations to give a one-dimensional coordination polymer

Four THF molecules and two oxygen atoms of terminal CO ligands of different anions span the coordination sphere of the sodium cations to give a one-dimensional coordination polymer

b Department of Chemistry, National Central University, Chungly, Taiwan 320, and Institute of Chemisty, Academia Sinica, Nankang, Taipei, Taiwan 115.. Reprint requests

Only brief comments on some characteristic 4,4 ⬘ -bipyridine bands shall be made. Most of these bands appeared doubled, in agreement with the fact that two different bipy ligands

The interaction between the magnetic d orbitals and the HOMOs of the acetate oxygens has been investigated in homologous -acetato-bridged dicopper(II) complexes which