Theoretical Investigation of the g Factors for Copper (II) Ion in an Orthorhombic Crystal and its Application to (CuCl4

Pro- jection of the infinite 2D supramolecular network of the Cu(II) complexes onto the ab plane (hydro- gen atoms, except those forming hydrogen bonds, are omitted for

Due to the large covalency and the large spin-orbit (s. o.) coupling constant of the ligand ions, however, the classical crystal-field calcu- lations cannot agree with the

1.) The local distance ∆ Z , smaller than the host ∆ Z, can be illustrated by the modification of local struc- ture properties around the impurity Ni 3+ replacing the Ti 4+. Since

b Department of Applied Physics, University of Electronic Science and Technology of China, Chengdu 610054,

a Institute of Applied Physics and College of Electronic Engineering, Chongqing University of Posts and Telecommunications, Chongqing 400065,

Substituting these parameters into the above formu- las and diagonalizing the complete energy matrix, the anisotropic g-factors for Cu 2+ and the hyperfine struc- ture constants A

The crystal-field parameters for the tetragonally distorted tetrahedra are determined by using the superposition model and the structural data of the impurity Er 3 + on the host Ca 2

c Department of Applied Physics, University of Electronic Science and Technology of China, Chengdu 610054,