C9 C10
C71 O2
O1 C7
C61
C8
C1 C11
C6 N1 C13
C12
C3 C2
C5 O3
C4
C31
Absolute Strukturparameter 0.0(13)
Größtes Maximum und Minimum 0.158 and -0.154 e.Å-3
Tabelle 3: Atomkoordinaten (x 104) und äquivalente isotrope Auslenkungsparameter (pm2x 10-1).
U(eq) wird berechnet als ein Drittel der Spur des orthogonalen Uij-Tensors.
x y z U(eq)
O(1) 1294(2) 1342(2) 6465(2) 42(1)
C(1) -70(3) 1877(2) 5073(3) 41(1)
O(2) -49(2) 1945(2) 3743(2) 56(1)
C(2) -1441(3) 2324(2) 5497(3) 43(1)
C(3) -517(3) 2382(2) 7423(3) 40(1)
C(31) -1681(3) 2116(3) 8216(3) 48(1)
C(4) 518(3) 3660(2) 8138(3) 40(1)
C(5) 2228(3) 3221(2) 9576(3) 39(1)
O(3) 3288(2) 3912(2) 10731(2) 50(1)
N(1) 2443(2) 1902(2) 9354(2) 36(1)
C(6) 951(3) 1344(2) 7918(2) 36(1)
C(61) 547(3) -65(2) 8165(3) 49(1)
C(7) 4087(3) 1155(2) 10282(3) 39(1)
C(71) 5659(3) 1947(3) 10477(3) 55(1)
C(8) 4372(3) 605(2) 11964(2) 36(1)
C(9) 5617(3) -387(2) 12729(3) 39(1)
C(10) 5980(3) -930(2) 14277(3) 43(1)
C(11) 5103(3) -483(2) 15110(3) 44(1)
C(12) 3852(3) 498(2) 14360(3) 44(1)
C(13) 3491(3) 1032(2) 12806(3) 39(1)
Tabelle 4: Bindungslängen [pm] und Bindungswinkel [°].
O(1)-C(1) 136.2(3) N(1)-C(6) 144.2(2)
O(1)-C(6) 147.6(2) N(1)-C(7) 148.0(3)
C(1)-O(2) 121.0(3) C(6)-C(61) 150.9(3)
C(1)-C(2) 149.6(3) C(7)-C(8) 151.8(3)
C(2)-C(3) 152.3(3) C(7)-C(71) 153.1(3)
C(3)-C(31) 152.6(3) C(8)-C(13) 138.7(3)
C(3)-C(4) 153.0(3) C(8)-C(9) 139.6(3)
C(3)-C(6) 155.1(3) C(9)-C(10) 138.5(3)
C(4)-C(5) 150.2(3) C(10)-C(11) 138.4(3)
C(5)-O(3) 122.6(3) C(11)-C(12) 138.9(3)
C(5)-N(1) 137.4(3) C(12)-C(13) 138.7(3)
C(1)-O(1)-C(6) 110.62(15) N(1)-C(6)-O(1) 108.18(15)
O(2)-C(1)-O(1) 120.62(19) N(1)-C(6)-C(61) 114.39(17)
O(2)-C(1)-C(2) 129.3(2) O(1)-C(6)-C(61) 106.99(16)
O(1)-C(1)-C(2) 110.08(17) N(1)-C(6)-C(3) 105.27(16)
C(1)-C(2)-C(3) 104.43(17) O(1)-C(6)-C(3) 103.97(15)
C(2)-C(3)-C(31) 114.64(19) C(61)-C(6)-C(3) 117.29(18)
C(2)-C(3)-C(4) 113.30(18) N(1)-C(7)-C(8) 113.49(16)
C(31)-C(3)-C(4) 110.31(18) N(1)-C(7)-C(71) 112.22(18)
C(2)-C(3)-C(6) 102.39(17) C(8)-C(7)-C(71) 111.71(17)
C(31)-C(3)-C(6) 113.38(18) C(13)-C(8)-C(9) 117.62(19)
C(4)-C(3)-C(6) 101.93(16) C(13)-C(8)-C(7) 124.37(18)
C(5)-C(4)-C(3) 105.00(16) C(9)-C(8)-C(7) 118.01(18)
O(3)-C(5)-N(1) 125.04(19) C(10)-C(9)-C(8) 121.8(2)
O(3)-C(5)-C(4) 126.81(19) C(11)-C(10)-C(9) 119.9(2)
N(1)-C(5)-C(4) 108.12(16) C(10)-C(11)-C(12) 118.9(2) C(5)-N(1)-C(6) 112.41(16) C(13)-C(12)-C(11) 120.8(2)
C(5)-N(1)-C(7) 125.29(17) C(12)-C(13)-C(8) 120.9(2)
C(6)-N(1)-C(7) 121.67(17)
Tabelle 5: isotrope Auslenkungsparameter (pm2x 10-1).
Der Exponent des isotropen Auslenkungsfaktors ergibt sich aus:
-2π2[ h2 a*2U11 + ... + 2 h k a* b* U12 ]
U11 U22 U33 U23 U13 U12
O(1) 40(1) 51(1) 31(1) 0(1) 15(1) 8(1)
C(1) 41(1) 45(1) 34(1) -2(1) 14(1) 0(1)
O(2) 54(1) 75(1) 37(1) 2(1) 21(1) 6(1)
C(2) 34(1) 50(1) 38(1) -1(1) 12(1) 3(1)
C(3) 34(1) 45(1) 40(1) 2(1) 17(1) 3(1)
C(31) 40(1) 59(1) 50(1) 1(1) 25(1) 2(1)
C(4) 40(1) 38(1) 41(1) 2(1) 20(1) 5(1)
C(5) 42(1) 41(1) 35(1) -3(1) 20(1) -3(1)
O(3) 54(1) 48(1) 41(1) -7(1) 17(1) -8(1)
N(1) 34(1) 37(1) 33(1) 1(1) 13(1) 4(1)
C(6) 37(1) 39(1) 32(1) -1(1) 16(1) 2(1)
C(61) 52(1) 42(1) 47(1) 1(1) 18(1) -3(1)
C(7) 34(1) 48(1) 36(1) 5(1) 16(1) 5(1)
C(71) 40(1) 70(2) 59(1) 24(1) 26(1) 8(1)
C(8) 32(1) 38(1) 34(1) -1(1) 14(1) -2(1)
C(9) 37(1) 40(1) 40(1) 1(1) 18(1) 1(1)
C(10) 37(1) 40(1) 43(1) 5(1) 13(1) 2(1)
C(11) 46(1) 44(1) 37(1) 3(1) 16(1) -5(1)
C(12) 49(1) 46(1) 42(1) -1(1) 26(1) -3(1)
C(13) 41(1) 39(1) 39(1) 2(1) 20(1) 2(1)
Tabelle 6: Wasserstoffatom Koordinaten (x 104) und isotrope Auslenkungsparameter (pm2x 10 -1).
x y z U(eq)
H(2A) -2418 1686 5069 42(3)
H(2B) -1896 3205 5003 42(3)
H(31A) -979 2129 9453 64(3)
H(31B) -2231 1246 7851 64(3)
H(31C) -2580 2801 7855 64(3)
H(4A) 691 4127 7265 42(3)
H(4B) -93 4258 8549 42(3)
H(61A) 1508 -642 8313 64(3)
H(61B) -524 -351 7171 64(3)
H(61C) 396 -117 9173 64(3)
H(7) 3987 372 9561 45(6)
H(71A) 5419 2303 9374 64(3)
H(71B) 6679 1367 10912 64(3)
H(71C) 5886 2678 11272 64(3)
H(9) 6233 -698 12173 53(3)
H(10) 6829 -1608 14766 53(3)
H(11) 5352 -841 16179 53(3)
H(12) 3236 806 14917 53(3)
H(13) 2628 1700 12312 53(3)
Tabelle 7: Torsionswinkel [°].
C(6)-O(1)-C(1)-O(2) -178.8(2) C(2)-C(3)-C(6)-N(1) 141.57(17) C(6)-O(1)-C(1)-C(2) 1.6(2) C(31)-C(3)-C(6)-N(1) -94.4(2) O(2)-C(1)-C(2)-C(3) -162.6(2) C(4)-C(3)-C(6)-N(1) 24.16(19) O(1)-C(1)-C(2)-C(3) 16.9(2) C(2)-C(3)-C(6)-O(1) 27.9(2) C(1)-C(2)-C(3)-C(31) -150.20(19) C(31)-C(3)-C(6)-O(1) 151.96(18)
C(1)-C(2)-C(3)-C(4) 82.0(2) C(4)-C(3)-C(6)-O(1) -89.50(17) C(1)-C(2)-C(3)-C(6) -27.0(2) C(2)-C(3)-C(6)-C(61) -89.9(2) C(2)-C(3)-C(4)-C(5) -135.47(18) C(31)-C(3)-C(6)-C(61) 34.1(3) C(31)-C(3)-C(4)-C(5) 94.5(2) C(4)-C(3)-C(6)-C(61) 152.65(18)
C(6)-C(3)-C(4)-C(5) -26.2(2) C(5)-N(1)-C(7)-C(8) 86.0(2) C(3)-C(4)-C(5)-O(3) -162.2(2) C(6)-N(1)-C(7)-C(8) -103.8(2) C(3)-C(4)-C(5)-N(1) 19.7(2) C(5)-N(1)-C(7)-C(71) -41.8(3) O(3)-C(5)-N(1)-C(6) 178.0(2) C(6)-N(1)-C(7)-C(71) 128.3(2) C(4)-C(5)-N(1)-C(6) -3.9(2) N(1)-C(7)-C(8)-C(13) -17.1(3) O(3)-C(5)-N(1)-C(7) -11.1(3) C(71)-C(7)-C(8)-C(13) 111.0(2) C(4)-C(5)-N(1)-C(7) 167.08(17) N(1)-C(7)-C(8)-C(9) 163.64(18) C(5)-N(1)-C(6)-O(1) 97.29(18) C(71)-C(7)-C(8)-C(9) -68.3(3) C(7)-N(1)-C(6)-O(1) -74.0(2) C(13)-C(8)-C(9)-C(10) -0.3(3) C(5)-N(1)-C(6)-C(61) -143.59(18) C(7)-C(8)-C(9)-C(10) 179.0(2) C(7)-N(1)-C(6)-C(61) 45.1(2) C(8)-C(9)-C(10)-C(11) -0.4(3)
C(5)-N(1)-C(6)-C(3) -13.4(2) C(9)-C(10)-C(11)-C(12) 0.8(3) C(7)-N(1)-C(6)-C(3) 175.31(16) C(10)-C(11)-C(12)-C(13) -0.5(3) C(1)-O(1)-C(6)-N(1) -130.56(17) C(11)-C(12)-C(13)-C(8) -0.2(3) C(1)-O(1)-C(6)-C(61) 105.7(2) C(9)-C(8)-C(13)-C(12) 0.6(3)
C(1)-O(1)-C(6)-C(3) -19.0(2) C(7)-C(8)-C(13)-C(12) -178.7(2)
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[58] BRN :471521; CAS-NR: 24014-22-0.