• Keine Ergebnisse gefunden

31 . 01 . 2011

N/A
N/A
Protected

Academic year: 2021

Aktie "31 . 01 . 2011"

Copied!
147
0
0

Wird geladen.... (Jetzt Volltext ansehen)

Volltext

(1)

!

"#$$

(2)

31 . 01 . 2011

(3)

+3

+3

! "

ν

2

#$lu %

&&

+3 '

(

) *

(

+3

+3 # +

, , - ' .

/, 0 ( , $

/, #

.( 1 , . * #

1 02

+3 2

# 3 4 ( # .

( . 54 3

( " 6 78

ν

26

( ( ! 1 . -

# $lu 9%( , 3 4

6 (4 ( 54 :) 4 ; .

/ &&<

+3

<' , , . <

(4)

48 / ( 0

. 3 ( 0 (

5 , 3 4

3 4 1 ,

. ( 4, : ; 3 4

4 .= ( 2

> 54 ( .(

( 7

(5)

+3

&? * @

&& A

&&? !

&&& 0 ?B

&&C # ?B

&&D 0 ??

&C

+3 ?"

&D

+3 ?!

&D? + ?!

&D& &B

C? E &C

C?? $ F &"

C?& * &"

C?C = ' &A

C&

+3 &G

CC ) C?

CC? ) H C?

CC& ) * *I C&

D? F CA

D& ) D?

D&? * D&

(6)

@? + DA

@& / DG

@C 2 @&

!

"? @A

"& 2 "B

"C .' "&

"# $

A? 0 "!

A& * A&

AC . A"

% %

G? . GC

G?? 0 GD

G?& * G@

G& 0 GA

GC . G!

$ & ' $

( ) *

+ , - *

*

. ,

/

0 $

(7)

2

. &B

= ( &?

J?K

+3 I

?BB J& CK *

+3

0 2 JD @K

* 2 +

3

. % 2 +

3

I : ;

+3 $

+3

(

+3

+3

+3

'

$ F *

(8)

L<#2M

N

<#2

#

>

J"K

+

< :/ O ;

+3

+3 *

+3 < :# 2 O /

(9)

(10)
(11)

+ 3

(

+3

* 6

&@B ?B

+3

*

+3

* 2

+3

*

+3

?!?? H H

:0<# P CN?

L &?M J&K

+3

JCK

+3 +

+

+2

+3

(12)

+2 JAK / 0 # 6 ) JGK

+3

2

+

+2

+3

+ ,

L&?M

)

L

10

−9−3 −1M * ?!C? +> J!K

H H J?BK J&K .

+

+3 CBQ

+3 L

+3 2 BC 1M J?? ?& ?C ?D ?@K

%

R CB

+3

+3

. - / ?!"? J?"K

H H 9 6-

J?A ?G ?!K ?!"D 0 # + '

J&BK

(

(

*

?"@

a

0 ?!AG 6 +

J&?K

+3 DCCA1 J&&K +

+3

+2 S

BD1

?!A" 6. + 0 = <

+3 J&CK - F

?!GB

+3 J&DK

(13)

-/ <$

<$

ν

2

+3 J&@K

J&"K J&AK J&GK >

&BB? ?A G!@

G?AB

−1

L

2 &&?M J&!K F'

H6 &BBCJCBK 2

JC?K &BBG

??&BB?CDBB

−1

JC&K * $ * +

+3

$? +

*

+3 L1

A

1M

3h

*.

&&

+3 (

+3

4426

−1 * ?BBBB−1

L 2 &&?M

+

+ @

4500

−1

2 L

v

TB

J

TBMS +

CD!@@

−1

+2 L

v = 0 , J = 0

MS

(14)

+3

J

!"#

G

!"$ +3# %

&&'(

−1

)

% )

&*('−1#

1 / 2( ν

1

+ 2 ν

2

)

+,

(&−1

J

!-

)$

20 000 0 10 000 30 000

ener gy (cm

-1

)

34 955

H2(υ=0,J=0) + H+

1=0, υ2=0) (J=1, G=1)

9 930

40 000 50 000

H3+ (1A‘1) H3+ (3+u)

For an overview on experiments in this spectral region see Appendix C

sensitivity limit for traditional absorption spectroscopy chemical probing

spectroscopy see Chap. 7 & 8

H2+ (υ=0,J=0) + H

49590

Carrington predissociation spectrum see Sec. 2.4.1

barrier to linearity

(15)

20000

15000

10000

5000

0 Energy (cm-1)

θ (deg)

θ

θ

40 80 120 160 200 240 280 320

+,

+3

) .*& / 0 ) 1%

) %

! "

&C <#2

(

θ

JCCK +3 ?BBBB−1 =

:; <#2

*

<#2

+3

*

R

?BBBB

−1

(16)

H JC@K

= /

*

* *I JC"K

+3

+3

<FQJCAK

/ Q JCGK

: ;

>

+3

L

3

Σ

+uM

+3

2

+

+ +3

+2

+

L

&&M 2

/ L

BCA1U&!@?

−1

M

L( B&?1U?A&&

−1

M *

+3

+

#

+3

(17)

a x y

ν 1 ν 2

+3

# "

)

1 2

3 r

1

r

2

r

3

*

N

C

N

C

N

"

L M

+3

C

·

C

"

=

C

r

1

, r

2

r

3 &D

r

1

& C

r

2 ? C

r

3 ? & *

V

(

*

JC!K L

A

1M

0

ν

1

L &@M

JDBK

s

a

= 1

3 ( r

1

+ r

2

+ r

3

) .

L&&M

s

x

= 1

6 (2 r

3

r

1

r

2

)

L&CM

(18)

ν 2-

ν 2+

2) % %

s

y

= 1

2 ( r

1

r

2

)

L&DM

ν

2

ν

2

+3

*

ν

2

JD?K

&"

s

x

s

y S!B L

ν

2+M !B L

ν

2M

1

L

F = J + I

M L

±

M

J

I

+3

I

J

I

J

$

*

L

?GBBB−1M

%

Referenzen

ÄHNLICHE DOKUMENTE

al., Phase III trial of bevacizumab (BEV) in the primary treatment of advanced epithelial ovarian cancer (EOC), primary peritoneal cancer (PPC), or fallopian

In chapter 3, we prove our existence theorem of boosted ground states and traveling solitary waves for focusing (fNLS), as well as the existence of symmetric boosted ground

Moreover, novel rational homoclinic waves for the Schrödinger and coupled Schrödinger equation are obtained via the limit of the period in homoclinic breather wave solution

Second, we aim using the well-known direct integration on the reduced nonlinear ordinary differential equation obtained after using the travelling wave transformation on the

In this research work a time-dependent partial differential equation which has several important applications in science and engineering is investigated and a method is proposed to

The Use of Homotopy Analysis Method to Solve the Time-Dependent Nonlinear Eikonal Partial Differential Equation.. Mehdi Dehghan and

The time-dependent nonlinear Boltzmann equation, which describes the time evolution of a single- particle distribution in a dilute gas of particles interacting only through

The time-dependent nonlinear Boltzmann equation, which describes the time evolution of a single- particle distribution in a dilute gas of particles interacting only through