Solution Structure of Metal Particles Prepared in Unimolecular Reactors of Amphiphilic Hyperbranched Macromolecules

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Solution Structure of Metal Particles Prepared in Unimolecular Reactors of Amphiphilic Hyperbranched Macromolecules

V. Garamus, T. Maksimova, W. Richtering*, L. Antonietti, C. Aymonier, R. Thomann, S. Mecking*

Supporting Information

Figure S1. Density of polymer solutions at various concentrations.

-0,002 0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 -0,00004

-0,00002 0,00000 0,00002 0,00004 0,00006 0,00008 0,00010 0,00012 0,00014 0,00016

d(polymer+solvent) - d(solvent)

Polymer concentration (wt%)

r = 0.99, α= 0.01 ± 7E^-4

r = -0.64,α= -5.7E^-4± 4E^-4 PEIam5K^linC16_0.5

PEIam25K^linC16_0.5

-0,002 0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 -0,00004

-0,00002 0,00000 0,00002 0,00004 0,00006 0,00008 0,00010 0,00012 0,00014 0,00016

d(polymer+solvent) - d(solvent)

Polymer concentration (wt%)

r = 0.99, α= 0.01 ± 7E^-4

r = -0.64,α= -5.7E^-4± 4E^-4 r = 0.99, α= 0.01 ± 7E^-4

r = -0.64,α= -5.7E^-4± 4E^-4 PEIam5K^linC16_0.5

PEIam25K^linC16_0.5

-0,002 0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 -0,00004

-0,00002 0,00000 0,00002 0,00004 0,00006 0,00008 0,00010 0,00012 0,00014 0,00016

d(polymer+solvent) - d(solvent)

Polymer concentration (wt%)

r = 0.99, α= 0.01 ± 7E^-4

r = -0.64,α= -5.7E^-4± 4E^-4 r = 0.99, α= 0.01 ± 7E^-4

r = -0.64,α= -5.7E^-4± 4E^-4 PEIam5K^linC16_0.5

PEIam25K^linC16_0.5

-0,002 0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 -0,00004

-0,00002 0,00000 0,00002 0,00004 0,00006 0,00008 0,00010 0,00012 0,00014 0,00016

d(polymer+solvent) - d(solvent)

Polymer concentration (wt%)

r = 0.99, α= 0.01 ± 7E^-4

r = -0.64,α= -5.7E^-4± 4E^-4 r = 0.99, α= 0.01 ± 7E^-4

r = -0.64,α= -5.7E^-4± 4E^-4 PEIam5K^linC16_0.5

PEIam25K^linC16_0.5

r = 0.99, α= 0.01 ± 7E^-4

r = -0.64,α= -5.7E^-4± 4E^-4 r = 0.99, α= 0.01 ± 7E^-4

r = -0.64,α= -5.7E^-4± 4E^-4 PEIam5K^linC16_0.5

PEIam25K^linC16_0.5

Konstanzer Online-Publikations-System (KOPS) URL: http://www.ub.uni-konstanz.de/kops/volltexte/2008/6562/

URN: http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-65621

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Figure S2. TEM micrograph and histogramm of silver colloid PEIam5K

C16

/Ag

.

Figure S3. TEM micrograph and histogramm of silver colloid PEIam25K

C16

/Ag

.

50nm 50nm

0 1 2 3

0 10 20 30 40

Particle size (nm)

Number of particles

1.2 ± 0.3

0 1 2 3

0 10 20 30 40

Particle size (nm)

Number of particles

1.2 ± 0.3

50nm 50nm

0 1 2 3

0 10 20 30 40

Particle size (nm)

Number of particles

1.2 ± 0.3

0 1 2 3

0 10 20 30 40

Particle size (nm)

Number of particles

1.2 ± 0.3

0 1 2 3

0 10 20 30 40

Particle size (nm)

Number of particles

1.2 ± 0.3

0 1 2 3

0 10 20 30 40

Particle size (nm)

Number of particles

1.2 ± 0.3

50nm 50nm

0 1 2 3 4

0 10 20 30 40

Particle size (nm)

Number of particles

2.3 ± 0.4

0 1 2 3 4

0 10 20 30 40

Particle size (nm)

Number of particles

2.3 ± 0.4

50nm 50nm

0 1 2 3 4

0 10 20 30 40

Particle size (nm)

Number of particles

2.3 ± 0.4

0 1 2 3 4

0 10 20 30 40

Particle size (nm)

Number of particles

2.3 ± 0.4

0 1 2 3 4

0 10 20 30 40

Particle size (nm)

Number of particles

2.3 ± 0.4

0 1 2 3 4

0 10 20 30 40

Particle size (nm)

Number of particles

2.3 ± 0.4