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Science 28 January 2011: Vol. 331 no. 6016 pp. 411-412 DOI: 10.1126/science.1201509

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Science 28 January 2011:

Vol. 331 no. 6016 pp. 411-412 DOI: 10.1126/science.1201509

(2)

G. Wedler, Lehrbuch der physikalischen Chemie, 4. Auflage, Wiley-VCH, 1997

Potentialhyperflächen

H + F2  HF + F (H --- F --- F) HF

F2

Start Ende

(3)

K + Br2 → KBr + Br KBr + K → KBr + K*

K* → K + hν

Attraktive/repulsive Potentialhyperflächen

A + BC

(Eyring, Polyani, Evans) Bsp.:

AB + C

A + BC AB + C

H + Cl2 → HCl + Cl

Start Ende

Start Ende

früher ÜZ später ÜZ

RBC RBC

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