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Multiphase polymer dispersions and nanocomposites by catalytic/free radical emulsion polymerization

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Supporting information for

Multiphase polymer dispersions and nanocomposites by catalytic / free radical emulsion polymerization

Ludmila Kolb, Ralf Thomann and Stefan Mecking*

Macromol. Rapid Commun.

0,0 0,5 1,0 1,5 2,0

0 20 40 60 80 100

conversion [%]

polymerization time [h]

Figure S1. Conversion over time in second-stage free-radical polymerizations (circles: styrene;

crosses: butyl acrylate; 80 °C reaction temperature).

Konstanzer Online-Publikations-System (KOPS) URL: http://www.ub.uni-konstanz.de/kops/volltexte/2007/4330/

URN: http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-43307

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Figure S2. AFM images of PE/PS latex at different temperatures (top height mode, bottom phase mode respectively).

RT 50 °C 70 °C

90 °C 100 °C 120 °C

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