Alfred Wegener Institute
for Polar and Marine Research Bremerhaven, Germany
Carbon cycle and the Mid Pleistocene Transition:
The Southern Ocean Decoupling Hypothesis
Peter K¨ohler
Berger Symposium on Climate Change, Louvain-la-Neuve, Belgium — May 2008
In cooperation with:
Hubertus Fischer, Climate and Environmental Physics, University of Bern, Switzerland
B¨arbel H¨onisch, Lamont Doherty Earth Observatory of Columbia University, New York, USA Richard Bintanja, KNMI (Royal Netherlands Meteorological Institute), De Bilt, Netherlands
Outline
The data The model
The EPICA Time Window
The Southern Ocean Decoupling Hypothesis Other Theories
Take-home messages
Paleo Reconstructions — Climate
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) 5
4 3
LR0418 O(o /oo)
A
MIS1357911131517192123252729313335373941434547495153555759616365100-kyr MPT
40-kyr
101 2 5 102 2 5 103 Period (kyr)
10-1
2 5
100
2 5
101
2 5
102
2
Spectralpower(-)
40-kyr world (1.2-1.8 Myr BP)
B
18O
101 2 5 102 2 5 103 Period (kyr)
10-1
2 5
100
2 5
101
2 5
102
2
Spectralpower(-)
MPT (0.6-1.2 Myr BP)
18O
101 2 5 102 2 5 103 Period (kyr)
10-1
2 5
100
2 5
101
2 5
102
2
Spectralpower(-)
100-kyr world (0-0.6 Myr BP)
C
18O
Benthic δ18O stack LR04 (Lisiecki and Raymo, 2005)
Paleo Reconstructions — Carbon Cycle
5 4 3
LR0418 O(o /oo)
A
MIS1357911131517192123252729313335373941434547495153555759616365180 200 220 240 260 280 300
CO 2(ppmv) 100-kyr
MPT 40-kyr
B
180 ppmv 280 ppmv
Vostok, EPICA Dome C
Petit et al., 1999
Siegenthaler et al., 2005 Luthi et al., 2008
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
C
Paleo Reconstructions — Carbon Cycle
5 4 3
LR0418 O(o /oo)
A
MIS1357911131517192123252729313335373941434547495153555759616365180 200 220 240 260 280 300
CO 2(ppmv) 100-kyr
MPT 40-kyr
B
180 ppmv 280 ppmv
CO2 = f(pH) = f(11B)
(Honisch & Hemming, 2005, unpublished data)
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
C
Paleo Reconstructions — Carbon Cycle
5 4 3
LR0418 O(o /oo)
A
MIS1357911131517192123252729313335373941434547495153555759616365180 200 220 240 260 280 300
CO 2(ppmv) 100-kyr
MPT 40-kyr
B
180 ppmv 280 ppmv
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
C
ODP846(3oS, 91oW); ODP677 (1oS, 83oW)(Raymo et al., 1997, 2004)
Paleo Reconstructions — Carbon Cycle
101 2 5 102 2 5 103 Period (kyr)
10-1
2 5
100
2 5
101
2 5
102
2
Spectralpower(-)
40-kyr world (1.2-1.8 Myr BP)
E
13C
101 2 5 102 2 5 103 Period (kyr)
10-1
2 5
100
2 5
101
2 5
102
2
Spectralpower(-)
MPT (0.6-1.2 Myr BP)
13C
101 2 5 102 2 5 103 Period (kyr)
10-1
2 5
100
2 5
101
2 5
102
2
Spectralpower(-)
100-kyr world (0-0.6 Myr BP)
F
13C
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
C
(Raymo et al., 1997, 2004)
100-kyr MPT
40-kyr
Variation in Glacial/Interglacial Amplitudes
5 4 3
LR0418 O(o /oo)
A
MIS1357911131517192123252729313335373941434547495153555759616365180 200 220 240 260 280 300
CO 2(ppmv) 100-kyr
MPT 40-kyr
B
180 ppmv 280 ppmv
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
C
ODP846(3oS, 91oW); ODP677 (1oS, 83oW)(Raymo et al., 1997, 2004)
Variation in Glacial/Interglacial Amplitudes
40K MPT 100K
0 -0.5 -1 -1.5
-2
G/IG(18 O)(o / oo)
LR04 climate
0.0 0.2 0.4 0.6 0.8 1.0 1.2
fratio(-)
40K MPT 100K
0 20 40 60 80 100 120
G/IG(CO 2)(ppmv)
ice core CO2
0.0 0.2 0.4 0.6 0.8 1.0 1.2
fratio(-)
40K MPT 100K
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
G/IG(13 C)(o /oo)
deep Pacific
0.0 0.2 0.4 0.6 0.8 1.0 1.2
fratio(-)
right y-axis: fratio = ∆∆40k,MPT
100k
reduced G/IG amplitude in 40k:
climate (LR04): ∼ 50% of 100k carbon (CO2): ???
carbon (δ13C): ∼ 70% of 100k
Outline
The data The model
The EPICA Time Window
The Southern Ocean Decoupling Hypothesis Other Theories
Take-home messages
THC
THC
The global
carbon cycle
60 PgC/yr 60 PgC/yr
1 PgC/yr 10 PgC/yr
ATMOSPHERE (600 PgC)
ROCK
TERR. BIOSPHERE (2200 PgC)
0.8 PgC/yr
0.2 PgC/yr
0.2 PgC/yr
DEEP OCEAN (38000 PgC)
SEDIMENT
soft tissues | hard shells marine biosphere SURFACE OCEAN (700 PgC)
preindustrial reservoir sizes and annual fluxes
000000 000000 000000 000000 000000 000000 000000 000000 000000
111111 111111 111111 111111 111111 111111 111111 111111 111111
00000 00000 00000 00000 00000 00000 00000 00000 00000
11111 11111 11111 11111 11111 11111 11111 11111 11111 0000
0000 1111 1111
00000000 00000000 00000000 11111111 11111111 11111111
Box model of the Isotopic Carbon cYCLE BICYCLE
Rock
C3
FS SS
NW W D
C4
Atmosphere
Atlantic Indo−Pacific
Sediment SO
Biosphere
mediate inter−
surface
deep
water carbon
K¨ohler et al. (2005, submitted), K¨ohler & Fischer (2006)
000000 000000 000000 000000 000000 000000 000000 000000 000000
111111 111111 111111 111111 111111 111111 111111 111111 111111
00000 00000 00000 00000 00000 00000 00000 00000 00000
11111 11111 11111 11111 11111 11111 11111 11111 11111 0000
0000 1111 1111
00000000 00000000 00000000 11111111 11111111 11111111
Box model of the Isotopic Carbon cYCLE BICYCLE
Rock
C3
FS SS
NW W D
C4
Atmosphere
Atlantic Indo−Pacific
Sediment SO
Biosphere
water carbon
Prognostic variables:
10 oceanic boxes: DIC,
7 terrestrial boxes: C, 13C, 14C 1 atmospheric box:
14C, ALK, PO4, O2 13C,
CO2,13C, 14C
DIC + ALK −> CO2, HCO3, CO3, pH
K¨ohler et al. (2005, submitted), K¨ohler & Fischer (2006)
Outline
The data The model
The EPICA Time Window
The Southern Ocean Decoupling Hypothesis Other Theories
Take-home messages
EPICA drilling sites:
Dome C (EDC): low accumulation rate; long time series (∼8 glacial cycles) Dronning Maud Land (EDML): high accumulation rate, high resolution
The EPICA Time Window
Carbon cycle model simulations based on results for Termination I
-450 -420 -390 -360
D(o /oo)
EDC D
Termination I
1 5
7 9
11 13
15 17
MIS
0 500 1000
dust(ppbv) 1500
EDC dust
700 600 500 400 300 200 100 0
Time (kyr BP)
160 200 240 280
pCO2(ppmv)
Vostok pCO
2EDC pCO
2I II
III IV
V VI
VII
EPICA, 2004; Petit et al., 1999 Siegenthaler et al., 2005
Atmospheric carbon during Termination I
Interprete the temporal evolution of atmospheric CO2, δ13C, 14C records
by carbon cycle simulations.
Smith et al., 1999; Monnin et al., 2001;
Stuiver et al., 1998; Hughen et al., 2004
-7.0 -6.8 -6.6 -6.4 -6.2
13 C[o / oo]
Interval I II III IV H1 BA YD 13
C
180 200 220 240 260 280
pCO2[ppmv]
pCO
220 18 16 14 12 10 GISP2 Age [kyr BP]
0 100
200 300 400 500
14 C[o /oo]
14
C
Overall objective and procedure for time-dependent simulations
Novelty:
• BICYCLE runs forward in time (no inverse studies)
• Transient simulations based on and forced with available paleo records
Three steps:
1. Which time-dependent processes were changing the carbon cycle on glacial/interglacial timescales?
2. How can we prescribe / force these processes in BICYCLE?
3. What are the impacts on CO2?
Time-dependent processes:
Which How (T I) What (ppmv) ?
Physics (without ocean circulation)
1 Temperature +(3–5) K +30 !
2 Sea level / salinity +125 m –15 !
3 Gas exchange / sea ice –50% –15 ?
Ocean circulation
4 NADW formation +6 Sv +15 !/? (off)
5 Southern Ocean ventilation +20 Sv +35 o
Biogeochemistry
6 Marine biota / iron fertilisation –2 PgC yr−1 +20 ? 7 Terrestrial carbon storage +500 PgC –15 !
8 CaCO3 chemistry τ=1.5 kyr +20 ?
Sum +75
Sum (without sea ice) +90
Vostok (incl. Holocene rise) +103
000000 000000 000000 000000 000000 000000 000000 000000
111111 111111 111111 111111 111111 111111 111111 111111
00000 00000 00000 00000 00000 00000 00000 00000
11111 11111 11111 11111 11111 11111 11111 11111 0000 0000 1111 1111
00000000 00000000 00000000 11111111 11111111 11111111
Box model of the Isotopic Carbon cYCLE BICYCLE
Rock
C3
FS SS
NW W D C4
Atmosphere
Atlantic Indo−Pacific
Sediment SO
Biosphere mediate
inter−
surface
deep
water carbon
-7.0 -6.8 -6.6 -6.4 -6.2
13 CO2[o /oo]
TD 13CO2 Interval I II III IV
200 220 240 260 280
pCO2[ppmv] EDC pCO2
Termination I
-450 -440 -430 -420 -410 -400 -390 -380
D[o /oo]
EDC D
0 10 20 30 40 50
2+ nss-Ca[ppb] 60
EDC nss-Ca2+
400 500 600 700
CH4[ppbv]
GISP2 EDC CH4
-42-41 -40-39 -37-38-36-35 -34
18 O[o /oo]
GISP2 18O
-120 -100 -80 -60 -40 -20 0
sealevel[m]
sea level
20 18 16 14 12 10 GISP2 Age [kyr BP]
0 5 10 15 20
Flux[106 m3 /s]
SO mixing NADW
H1 YD
-7.0 -6.8 -6.6 -6.4 -6.2
13 C[o /oo]
Interval I II III IV
13
C
180 200 220 240 260 280
pCO2[ppmv]
pCO
220 18 16 14 12 10 GISP2 Age [kyr BP]
0 100
200 300 400 500
14 C[o /oo]
20 18 16 14 12 10 GISP2 Age [kyr BP]
0 100
200 300 400 500
14 C[o /oo]
14
C
Assumptions on changes in
- Fe fertilization in SO - Ocean circulation
(NADW, SO mixing) - Climate ( T,
sealevel, sea ice) - CaCO3 chemistry - terrestrial biosphere
Forcing ⇒ Model ⇒ Results
K¨ohler et al. (2005) Global Biogeochemical Cycles
The EPICA Time Window
Working hypothesis:
Our findings for Termination I are of general nature.
Approach:
Use same assumptions and extend forcing data set back in time.
-450 -420 -390 -360
D(o /oo)
EDC D
1 5
7 9
11 13
15 17
MIS
0 500 1000
dust(ppbv) 1500
EDC dust
700 600 500 400 300 200 100 0
Time (kyr BP)
160 200 240 280
pCO2(ppmv)
Vostok pCO2 EDC pCO2
I II
III IV
V VI
VII
0 20 40 60 80 100
IRD(%) (a)
5 10 15
SST(o C)
(b)
5 4 3 2
18 O(o /oo)
(c)
0 -1 -2
18 O(o /oo)
(d)
-15 -10 -5 0
T(K)
(e)
1.0 0.5 0.0
18 O(o /oo)
(f)
-100 -50 0
sealevel(m)
(g)
-450 -420 -390 -360
D(o /oo)
(h)
1 5
7 9
11 13
15 17
500 400 300 200 100 0
Feflux(gm-2 yr-1 )
(i)
700 600 500 400 300 200 100 0
Time (kyr BP)
180 200 220 240 260 280
CO2(ppmv)
700 600 500 400 300 200 100 0
Time (kyr BP)
180 200 220 240 260 280 300
CO2(ppmv)
(j)
S6.0k S1.5k S0.0k
I II
III IV
V VI
VII VIII
a: Heinrich b: N-SST c: NADW d: EQ-SST
e: NH ∆T
f: deep sea ∆T g: sea level
h: SO SST i: Fe fert.
j: CO2
K¨ohler and Fischer, 2006, Climate of the Past
Terminations I-VIII
combined simulation vs. ice core data
∼20 ppmv per Termination are missing
VIII VII VI V IV III II I Number of Termination
0 10 20 30 40 50 60 70 80 90 100 110 120 130
CO 2rise(ppmv)
Vostok and EDC data scenario S1.5K
sum of one-at-a-time sum of all-but-one
Vostok pre-Vostok
K¨ohler and Fischer, 2006, Climate of the Past
Outline
The data The model
The EPICA Time Window
The Southern Ocean Decoupling Hypothesis Other Theories
Take-home messages
Beyond EPICA — Forcings
OLD EPICA 740kyr
K¨ohler & Fischer (2006)
5 10 15
SST(oC)
5 4 3 2
18O(o/oo)
0 -1 -2
18O(o/oo)
-15 -10 -5 0
T(K)
1.0 0.5 0.0
18O(o/oo)
-100 -50 0
sealevel(m)
-450 -420 -390 -360
D(o/oo) 1 5 7 9 11 13 15 17
700 600 500 400 300 200 100 0
Time (kyr BP) 500
400 300 200 100 0
Feflux(gm-2yr-1)
⇒
000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000
111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111
000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000
111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 0000000
0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000
1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111
0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000
1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111
⇒
CO2, δ13C740 kyr 2 Myr
NEW MPT 2 Myr
this study
LR04-based
5 10 15
SST(oC)
5 4 3 2
18O(o/oo)
0 -1 -2
18O(o/oo)
-15 -10 -5 0
T(K)
1.0 0.5 0.0
18O(o/oo)
-100 -50 0
sealevel(m)
-450 -420 -390 -360
D(o/oo) 1 5 7 9 11 13 15 17
700 600 500 400 300 200 100 0
Time (kyr BP) 500
400 300 200 100 0
Feflux(gm-2yr-1)
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) 5
4 3
LR0418O(o/oo) A MIS1357911131517192123252729313335373941434547495153555759616365
100-kyr MPT
40-kyr
⇒
5 4 3
18(o/oo) LR04 A
-100 -50 0
sealevel(m)
S_NHICE S_LR04, r2= 93%
Bintanja 1 Myr
B
-15 -10 -5 0 5
T(K) S_NHICE
S_LR04 r2= 78%
Bintanja 1 Myr
C
1.0 0.5 0.0
18O(o/oo) S_NHICE
S_LR04, r2= 90%
Bintanja 1 Myr
D
40 35 30 25 20 15
Area(1012m2) S_NHICE S_LR04
E
-5 0 5 10
Siweath(1012mol/yr) S_REGOLITH
S_LR04
F
0 -1 -2 18O(o/oo)
correl. to LR04, r2= 42%, not taken ODP677
G
-440 -400 -360
D(o/oo) S_LR04, r2= 73%
EPICA Dome C
H
2.0 1.5 1.0 0.5 0.0
Time (Myr BP) 0
200 -2-1Feflux(gmyr) 400
S_IRON S_LR04, r2= 53%
EPICA Dome C
I
EDC period pre-EDC period
⇒
000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000
111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111
000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000 000000000000
111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 111111111111 0000000
0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000
1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111
0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000 0000000
1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111 1111111
⇒
CO2, δ13C⇒ LR04-based forcing is a Null Hypothesis
Regressions between LR04 and other Records
1000 800 600 400 200 0 Time [kyr BP]
6 5 4 3
benthic18 O[o /oo] A
-120 -100 -80 -60 -40 -20 0 20 40
sea level benthic18O
3 4 5
benthic 18O [o/oo] -120
-100 -80 -60 -40 -20 0 20 40
sealevel[m]
3 4 5
-120 -100 -80 -60 -40 -20 0 20
40 B
y = 234.508 - 71.4076*x r2= 93%
1000 800 600 400 200 0 Time [kyr BP]
6 5 4 3
benthic18O[o/oo] A
-15 -10 -5 0 5 10 15
NH T benthic18O
3 4 5
benthic 18O [o/oo] -15
-10 -5 0 5 10 15
NHT[K]
3 4 5
-15 -10 -5 0 5 10 15
B
y = 22.7445 - 7.75426*x, r2= 78%
1000 800 600 400 200 0 Time [kyr BP]
3 4 5 6
benthic18 O[o /oo]
A -1 0 1
deepseatemperaturepart
deep sea T part of18O [o/oo] benthic18O
3 4 5
benthic 18O [o/oo] -1
0 1
ofbenthic18 O[o /oo]
3 4 5
-1 0 1
B
y = -1.12196 + 0.375151*x r2= 90%
800 600 400 200 0 Time [kyr BP]
6 5 4 3
benthic18 O[o /oo] A
-440 -420 -400 -380
EDC D -360
benthic18O
3 4 5
benthic 18O [o/oo] -440
-420 -400 -380 -360
EDCD[o/oo]
3 4 5
-440 -420 -400 -380
-360 B
y = -298 - 30.0981*x r2= 73%
600 400 200 0
Time [kyr BP]
2 3 4 5
benthic18O[o/oo] A
0 100 200 300 400 500 600
EDC Fe flux benthic18O
3 4 5
benthic 18O [o/oo] 0
100 200 300 400 500 600
EDCFeflux[gm-2 yr-1 ]
3 4 5
0 100 200 300 400 500 600
y = 10(-1.36087+0.737415*x) B
, r2=53%
y = -279.337+98.1174*x, r2=13%
2.0 1.5 1.0 0.5 0 Time [Myr BP]
2 3 4 5
benthic18 O[o /oo] A
-3 -2 -1 0 1 2
planktic18O ODP 667 benthic18O
3 4 5
benthic 18O [o/oo] -3
-2 -1 0 1 2
planktic18OODP667[o/oo]
3 4 5
-3 -2 -1 0 1 2
B
y = -3.84387+0.625415*x r2= 42%
3 4 5
benthic 18O [o/oo] 0
100 200 300 400 500 600
EDCFeflux[gm-2 yr-1 ]
3 4 5
0 100 200 300 400 500 600
y = 10(-1.36087+0.737415*x)
B
, r2=53%
y = -279.337+98.1174*x, r2=13%
Underlying assumption:
Climate change is similarly related to LR04 in 40k and 100k world
(1) Regression is in general good (r2 = 93,78,90, 73,53,42%).
(2) Most difficult is Fe flux to Antarctica (two approaches, see left).
Ground-truthing of LR04-based approach
5 4 3
18 O(o / oo)
A
180 200 220 240 260 280 300
pCO2(atm)
B
700 600 500 400 300 200 100 0
Time (kyr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
700 600 500 400 300 200 100 0
Time (kyr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
LR04 OLD C
(1) Simulated glacial/interglacial amplitudes of original approach are about 85% of those in the data sets.
(2) 400-kyr cycle in δ13C (eccentricity) is not covered by simulations.
Ground-truthing of LR04-based approach
160 200 240 280 pCO
2( atm)
160 200 240 280
pCO
2( atm)
pCO
2r
2= 67%
LR04
OLD
-0.4 -0.2 0.0 0.2
13
C (
o/
oo) -0.4
-0.2 0.0 0.2
13
C (
o/
oo)
deep Pacific
13C r
2= 76%
OLD LR04
LR04-based approach loses about 10%
of the glacial/interglacial amplitudes in both pCO2 and δ13C.
Null Hypothesis
5 4 3
18 O(o /oo)
A
180 200 220 240 260 280 300
pCO 2(atm) 180
200 220 240 260 280 300
B
180 ppmv280 ppmv
-1.0 -0.8 -0.6 -0.4 -0.2 0.0 0.2
2.0 1.5 1.0 0.5 0
Time (Myr BP) -1.0
-0.8 -0.6 -0.4 -0.2 0.0 0.2
13 C(o /oo)
C
100-kyr MPT
40-kyr
pCO2: within errorbars;
δ13C: amplitudes in 40-kyr world too small
⇒ Reject Null Hypothesis
Variation in Glacial/Interglacial Amplitudes
40K MPT 100K
0 20 40 60 80 100 120
G/IG(CO2)(ppmv)
CO2 - absolute
LR04 data
40K MPT 100K
CO2 - relative
0.0 0.2 0.4 0.6 0.8 1.0 1.2
f ratio(-)
LR04 data
40K MPT 100K
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
G/IG(13 C)(o / oo)
deep Pacific - absolute
LR04 data
40K MPT 100K
deep Pacific - relative
0.0 0.2 0.4 0.6 0.8 1.0 1.2
f ratio(-)
LR04 data
Improving the Null Hypothesis
LR04 regression function between LR04 and climate records Null Hypothesis
Improving the Null Hypothesis
LR04 regression function between LR04 and climate records Null Hypothesis
IRON alternative regression for Fe flux
(Southern Ocean marine export production)
Improving the Null Hypothesis
LR04 regression function between LR04 and climate records Null Hypothesis
IRON alternative regression for Fe flux
(Southern Ocean marine export production)
NHICE Sea level, ∆T in deep ocean and northern hemisphere from Bintanja & van de Wal (submitted)
Northern Hemispheric Ice Sheets Bintanja et al. (2005, submitted)
Deconvolute LR04 stacked δ18O into climate variables (∆Tdeepocean, ∆Tatmosphere, size of ice sheets, sea level)
Improving the Null Hypothesis
LR04 regression function between LR04 and climate records Null Hypothesis
IRON alternative regression for Fe flux
(Southern Ocean marine export production)
NHICE Sea level, ∆T in deep ocean and northern hemisphere from Bintanja & van de Wal (submitted)
REGOLITH as NHICE + Regolith Hypothesis (Clark et al., 2007), additionally changing silicate weathering rates between 2 and 1 Myr BP