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Downstream Processing for Xylitol Recovery from Fermented Sugar Cane Bagasse Hydrolysate Using Aluminium Polychloride

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Downstream Processing for Xylitol Recovery from Fermented Sugar Cane Bagasse Hydrolysate Using Aluminium Polychloride

Silvio S. Silva

a,

*, Rodrigo M. Ramos

b

, Denise C. G. A. Rodrigues

a

and Ismael M. Mancilha

b

a Department of Biotechnology, Faculty of Chemical Engineering of Lorena, P.Box 116, Lorena, Sa˜o Paulo, Brazil. E-mail: silvio@debiq.faenquil.br

b Departament of Food Science and Technology, Federal University of Vic¸osa, Vic¸osa, M.Gerais, Brazil

* Author for correspondence and reprint requests

Z. Naturforsch.55c,10Ð15 (2000); received August 25/October 4, 1999 Xylitol, Sugar Cane Bagasse, Aluminium Polychloride, Aluminium Sulfate

Xylitol, a sweetener comparable to sucrose, is anticariogenic and can be consumed by diabetics. This sugar has been employed sucessfully in many foods and pharmaceutical pro- ducts. The discoveryof microorganisms capable of converting xylose present in lignocellulosic biomass into xylitol offers the opportunity of producing this poliol in a simple way. Xylitol production bybiotechnological means using sugar cane bagasse is under studyin our laboratories, and fermentation parameters have alreadybeen established. However, the downstream processing for xylitol recoveryis still a bottleneck on which there is onlya few data available in the literature. The present studydeals with xylitol recoveryfrom fermented sugar cane bagasse hydrolysate using 5.2 g/l of aluminium polychloride associated with acti- vated charcoal. The experiments were performed at pH 9, 50∞C for 50 min. The results showed that aluminium polychloride and activated charcoal promoted a 93.5% reduction in phenolic compounds and a 9.7% loss of xylitol from the fermented medium, which became more discoloured, facilitating the xylitol separation.

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