Syntheses, Crystal Structures and Vibrational Spectra

We used E UTAX calculations (Madelung poten- tials and bond valence sums, Table 3) to verify the valid- ity of our structural results by comparing them to calcu- lated results of CaH

Secondly, we used EUTAX calculations (Madelung potentials and bond valence sums, Table 3) to com- pare our results to BaHBr and to the binary com- pounds BaH 2 and BaBr 2 to verify

the dehydration stage is consistent with the calculated value of 3.0%. The anhydrous complex starts to de- compose at 253 ◦ C and shows a two-step distinct de- composition

The packing of the molecules in the crystals in both complexes is consolidated by arene π − π stacking interactions between the sac rings and by intermolecular hydrogen bonds

Europium selenogermanate(IV) and Europium selenogermanate(III) were synthesized by direct reactions of the elements at 1023 K and their crystal structures determined by single

From the viewpoint of X-ray diffraction data, the coordination number of europium changes from 7 to 6(+2) during the transition (see Table 3), but this is a matter of a dynamic

The structures comprise of equilateral mercury triangles with mean distances d (Hg-Hg) = 2.659 ˚ A, which are bonded to halogen and oxygen atoms of nearly perfect PO 4 or AsO

Klap¨otke, Burkhard Krumm, Kurt Polborn, and Claudia M.. Rien¨acker Department Chemie,