Random field fluctuations Introduction
Field fluctuations …
… are random
… have zero mean
… and small amplitude
= 0
⟨ ��❑,�,�
❑
2
⟩ ≪ �0
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Random field fluctuations Introduction
Random fluctuations …
… can be slow … and fast
How to measure the rapidness of fluctuations?
correlation function
Random field fluctuations
Correlation function: Auto-correlation
Correlation function
… defined as sliding integral with itself
… is called Auto-correlation function
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Random field fluctuations
Correlation function: Cross-correlation
Correlation function
… defined as sliding integral with another function
… is called Cross-correlation function
Random field fluctuations Auto-correlation
Use sliding integral to judge rapidness of random field fluctuations
… slow fluctiations
… rapid fluctiations
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Random field fluctuations Auto-correlation
… slow fluctiations
… rapid fluctiations
Auto correlation for random field fluctuations
~ exponential decay
Only valid for isotropic tumbling
other motions have different (more complex) correlation function
random fluctuations
… are oscillatory (like an FID)
which frequencies contribute to the oscillations?
perform Fourier Analysis to obtain spectral density
Random field fluctuations
From Auto-correlation to Spectral density
FT
FT
FT
Lorentzian (= Cauchy distribution)
Intensity scaled x 10
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Transition probabilites ~ Spectral density
Random field fluctuations Spectral density
~ ~
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