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The D

2h

Distortion around the Cu

2+

Center in Cu

0.5

Zr

2

(PO

4

)

3

Single Crystals

Y. Huang, M. L. Du, C. Ni, and J. F. Wen

Department of Physics, Southwest University for Nationalities, Chengdu 610041, P. R. China Reprint requests to Dr. M. L. D.; E-mail: duml@mail.sc.cninfo.net

Z. Naturforsch. 60a, 193 – 195 (2005); received September 16, 2004

A formula for the calculation of the three g factors of 3d9 ions in an orthorhombic field D2h

has been derived. Using it to investigate the EPR g factors of the Cu2+ ions in single crystals of Cu0.5Zr2(PO4)3, the variation of the g factors on changing the angleαbetween the x- and y-axis has been explained. According to that, it can be confirmed that the angleαof the D2hdistortion is about 62.6. PACS: 71.70C; 76.30F

Key words: Cu0.5Zr2(PO4)3Crystal; Gyromagnetic Factor; D2hDistortion.

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