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EPR and Optical Absorption Studies of VO

2+

Doped KH

2

PO

4

and KH

3

C

4

O

8

·2H

2

O Single Crystals

Recep Bıyık and Recep Tapramaz

Ondokuz Mayıs University, Faculty of Art and Sciences, Department of Physics, 55139-Samsun, Turkey

Reprint requests to Dr. R. B.; E-mail: rbiyik@omu.edu.tr

Z. Naturforsch. 61a, 171 – 179 (2006); received December 20, 2005

VO2+doped potassium dihydrogen phosphate (KH2PO4) and potassium tetraoxalate (KH3C4O8· 2H2O) single crystals and powders are examined by electron paramagnetic resonance and optical ab- sorption spectroscopy. Angular variations of KH2PO4and KH3C4O8·2H2O single crystals show four and two different VO2+sites, respectively. The local symmetry of VO2+complexes is nearly axial for both host crystals. The optical absorption spectra show three bands. Spin Hamiltonian parameters are measured and molecular orbital coefficients are calculated by correlating EPR and optical absorp- tion data for the central vanadyl ion.

Key words: EPR; Potassium Dihydrogen Phospate; Potassium Tetraoxalate; Absorption Spectrum;

Vanadyl Ion.

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