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Geochemical characterization and origin of Southeastern and Eastern European loesses (Serbia, Romania, Ukraine)

5.2 Southeastern/Eastern European loess – representative samples of the upper continental crust

As the A–CN–K plot shows, near Danube loess is derived from material with UCC-like composition. Though, due to grain size/mineral sorting no clear source composition is revealed by this diagram for Stary Kaydaky, initial UCC-like composition is evident by the Fe2O3/Al2O3 ratio, also for this site. Hence, loess deposits of the Danube Basin/Drobrudja and the Dnieper area represent average samples of the upper continental crust. This result is conform with studies from other loess regions of the world (Taylor et al., 1983; Gallet et al., 1996, 1998). For the loess material at the Dnieper River, originating from glaciofluvial sediments of the Fennoscandinavian ice-sheet, the most effective sampling process was probably glacial grinding of bedrocks with subsequent mixing of the different rock end-members. For the lower Danube Basin/Drobrudja loess, source material is proposed to be provided by river transport of the Danube River and its tributaries, draining the Eastern Alps

and the Carpathian Basin. Since already floodplain sediments of the Danube catchment mostly show a UCC-like initial composition, of the unweathered material (Fig. 1-5, Fig. 1-6), sampling and mixing occurs by fluvial processes. In both cases, loess is not the primary sample of the UCC, however, loess deposits act as archives for UCC samples provided by glaciofluvial and fluvial systems, respectively. Yet, the information about UCC composition, derived by loess geochemistry, can be biased by several effects such as mineral weathering, grain size and mineral sorting and dilution effects by minerals such as quartz (Taylor and McLennan, 1985). The A–CN–K plot indicates that the samples of the loess-paleosol-sequences, also including “pure loess“ samples, are substantially altered by weathering with respect to UCC composition. So at least one cycle of erosion/transport (activity phase) and sedimentation/weathering (stability phase) has to be proposed for the source material, before it is entrained and transported by the wind as dust and finally deposited and archived as loess.

For the lower Danube Basin loess, this previous recycling phase may either have occurred during the material is retained in the fluvial system or already during the formation of the various types of clastic sedimentary rocks in the drainage basin. Since for the material of Stary Kaydaky the intersect of the sorting trend with the weathering trend of the UCC is clearly situated towards lower CaO* + NaO contents (Fig. 1-4), also here at least one phase of recycling has to be proposed. For comparison, the composition of a probably prevailing original source itself i.e. the Baltic shield, does not reveal remarkable changes with respect to the UCC (Fig. 1-4, Fig. 1-5). This was expected, since the Precambrian shields are commonly taken as representatives of the average upper continental crust (Ronov and Yaroshevskiy, 1976; Taylor and McLennan, 1985; Condie, 1993). However, question arises about the timing of this weathering phase in the loess material of the Dnieper area. There is no simple answer for this, especially with respect to the high extent of weathering, compared to the aeolian sediments of the Danube Basin. Following the evolution history of the loess in the Dnieper area, we have to start with the uptake of the relativly unweathered bedrock of the Baltic shield

into the ice shield. During the phase of the glaciofluvial transport in sub- and proglacial streams, material gets further crushed and grinded. Generally, chemical weathering in the subglacial environment is thought to be low, according to the Arrhenius relationship between temperature and reaction rate. We are aware that significant silicate weathering in subglacial systems was observed e.g. by Tranter et al. (2002) and Anderson (2005). The latter regarded glaciers even as “flow-through reactors”. In spite of the long transport distance and residence time in the subglacial system of the Fennoscandinavian ice sheet, for us subglacial weathering does not appear likely to explain such strong initial weathering of loess. Also proglacial weathering and alteration during loessification are not expected to act sufficiently strong.

Therefore, only a combination of all three weathering phases may account for a relatively high initial weathering of the Stary Kaydaky loess. Yet, this should then be still reduced compared to loess with an alluvial source. Thus, it is to conclude that sedimentary rocks (of the Russian platform) with an inherited weathering signal, entering the glaciofluvial system, have to be the dominant source of the material and not the Baltic shield. This corresponds also to the findings of Gallet et al. (1998) that loess deposits from various parts of the world show evidences of previous sedimentary recycling. As to this, also Jahn et al. (2001) emphasized the general importance of sedimentary rocks as dust sources.

Generally, the deviations from the UCC element composition of the “pure loess” mostly reflect selective mineral enrichment and depletion, respectively, according to the weathering resistance (Schnetger, 1992). In the studied Southeastern/Eastern European loesses, low mobility elements such as Si, Ti and some trace elements (e.g. Zr, Hf) (Fig. 1-6), which are commonly associated with weathering-resistant minerals such as quartz, rutil and zircon, are enriched compared to UCC composition. Conversely, quartz accumulation leads to a dilution effect, affecting the concentrations of the other elements, as is well indicated for the Stary Kaydaky loess. The enrichment of the relatively mobile elements Ca and Mg compared to

UCC is explained by the accumulation of secondary carbonates, leached from the paleosols in the underlying loess units.

6 Conclusions

1) As already proofed for several other loess regions such as the Chinese loess plateau (Gallet et al., 1996, 1998), Western Europe (Gallet et al., 1998) and the Midwest of the USA (Taylor et al., 1983), loess of the Danube Basin/Dobrudja and the Dnieper areas represent a representative sample of the upper continental crust.

2) Compared to the upper continental crustal composition, loess shows general evidence of at least one previous recycling phase, which probably is an inherited signal from sedimentary source rocks. This is particularly obvious from the depletion of some elements, reflecting weathering resistance of their host minerals and element mobility.

Further bias of initial average UCC composition is due to mineral dilution effects especially by quartz and if not corrected for by secondary carbonates, as well as mineral and grain size sorting.

3) Loess of the Stary Kaydaky site (Dnieper loess area) is most likely derived from glaciofluvial sediments of the Fennoscandinavian ice sheet in the Ukraine and adjacent areas. Initial source rocks are proposed to be sedimentites of the Russian platform.

Prevailing cold stage paleowind direction in the Ukraine was WNW to N due to katabatic winds descending from the ice sheet.

4) .In the southern Pannonian Basin (Vojvodina, Serbia), where the course of the Danube river turns from South to East, thick loess plateaus build up by dust supply from two wind systems: N/NW winds, as they prevail in the main part of the Pannonian Basin and SE winds in the Southeastern part of the basin. This loess is confirmed by our geochemical results to originate from alluvial sediments of the Danube river. Due to the element composition, the area of the northern Alpine cover nappes and foreland

glaciations (not including the Inn area), does not seem to be the dominant initial source. Weathering products of the Carpathian mountain range, drained by the Tisza River and several smaller Danube tributaries, and of the Austroalpine base nappes, drained by the Drava River, appear to be more likely source areas with respect to element composition. Though not evaluated geochemically, the Inn River is also considered as significant sediment supplier into the Pannonian Basin (Smalley and Leach, 1978).

5) As in Serbia, the loess of the Dobrudja plateau (Romania) is predominantly derived from Danube alluvium. However, a minor but geochemically significant contribution of one or several additional source areas is evident. The prevailing paleowind direction was WNW in the Western Walachian plain and N to NE in the Dobrudja and eastern Walachian plain. Thus, the additional material input is supposed to be derived from the Ukrainian glaciofluvial deposits, probably with strongly variable contributions from local sand dune fields.

6) Further research is needed for a better differentiation between the possible source areas of the Southeastern/Eastern Eurpean loesses. Isotope studies (87Sr/86Sr,

143Nd/144Nd, 187Os/188Os, 187Re/188Os, δ18O of quartz) and element composition of different grain size fractions may be promising with this respect (Mizota and Matsuhisa, 1995; Hattori et al., 2003; Honda et al., 2004; Nakano et al., 2004).

Acknowledgements

We thank Tivadar Gaudenyi and Мladjen Јovanović for assistance during fieldwork in Serbia, J. Eidam (University of Greifswald) for XRF analyses and Dr Michael Zech for comments on the manuscript. Financial support was provided by the German Research Foundation DFG (GL 327/8-2).

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