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1.

WAXD fittings iPP

0 10 20 30 40 50 60

0,0 5,0x10³ 1,0x10⁴ 1,5x10⁴ 2,0x10⁴

Data4_B

Data4_A Fitting Results

MaxHeight 16963.46881 4223.92958 4673.89445 5736.75471 4531.97571 363.78273 958.59183 2684.84275

AreaFitTP 20.65461 4.20829 5.87826 8.89057 4.96671 0.71918 4.66142 50.02096 FWHM

0.55 0.5 0.6 0.7 0.55 0.7 1 8.95417

CenterGrvty 13.95935 16.79582 18.44018 21.04009 21.8 25.27077 -- 17.77883 AreaFitT

11384.86559 2319.61632 3240.11126 4900.5028 2737.66291 396.4141 2569.3864 27571.66219 55120.22157 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Peak # 1 2 3 4 5 6 7 8

0 10 20 30 40 50 60

-2,0x10³ 0,0 2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴ 1,2x10⁴ 1,4x10⁴ 1,6x10⁴ 1,8x10⁴

Data4_C

Data4_A Fitting Results

MaxHeight 14282.53834 5749.05714 4640.34195 3568.1351 3504.80123 1392.35321 1283.62703 3844.35994 867.90909 816.1734

AreaFitTP 16.14183 4.80681 5.1018 6.31576 3.41878 3.98716 3.67581 50.08964 3.92486 2.53754 FWHM

0.73 0.6 0.75 0.9 0.7 2 2 8.95417 3.2 2.2

CenterGrvty 13.95 16.71941 18.3814 21.04 21.74859 25.267 28.37497 17.77883 16.46229 21.36304 AreaFitT

12722.5125 3788.58973 4021.09214 4977.89705 2694.58151 3142.56386 2897.16719 39479.18122 3093.45843 2000.0123 78817.05594 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10

Fig. A1: iPP 1.12 K/s Fig. A2: iPP 4 K/s

10 20 30

0,0 2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴ 1,2x10⁴ 1,4x10⁴

Data4_D

Data4_A Fitting Results

MaxHeight 10672.60136 5818.33351 2959.87163 1764.56609 2178.49052 713.18249 1424.13366 3431.72753 1077.02422 1264.40343

AreaFitTP 16.13386 5.48558 3.69758 3.04375 2.95185 0.85949 2.50903 54.57582 5.94483 4.79821 FWHM

0.8 0.57 0.75 1 0.8 0.68959 1.00811 8.95417 3.2 2.2

CenterGrvty 13.84413 16.71941 18.33172 21.04 21.68112 25.267 28.41747 17.77883 16.50728 21.36304 AreaFitT

10418.25081 3542.2523 2387.6694 1965.46481 1906.12498 555.00445 1620.17955 35241.70343 3838.80249 3098.38869 64573.8409 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10

0 10 20 30 40 50 60

-2,0x10³ 0,0 2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴ 1,2x10⁴ 1,4x10⁴ 1,6x10⁴ 1,8x10⁴

Data4_E

Data4_A Fitting Results

MaxHeight 12513.5815 6960.61222 4571.4161 2766.82679 3534.63445 614.75605 545.12935 3003.99535 992.85634 1060.36009

AreaFitTP 16.3228 7.07414 6.00773 4.01659 4.40866 0.90418 1.01035 50.25756 5.76489 4.23313 FWHM

0.75 0.58 0.75 0.8 0.7 0.8 1.00811 8.95417 3.2 2.2

CenterGrvty 13.95 16.79 18.44 21.04 21.77 25.27 28.52 17.77883 14.79 21.21 AreaFitT

10019.28184 4342.2565 3687.67018 2465.4661 2706.12717 555.00504 620.17172 30849.16044 3538.60977 2598.38561 61382.13437 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10

Fig. A3: iPP 9 K/s Fig. A4: iPP 12 K/s

0 10 20 30 40 50 60 0,0

2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10

Data4_F

Data4_A Fitting Results

MaxHeight 3662.8427 2722.09416 1224.3622 859.02146 921.30805 327.8699 248.21578 3324.79448 2732.32591 1468.44678

AreaFitTP 6.22044 3.60975 1.74573 1.35297 1.42484 0.98099 0.74266 60.34978 17.21256 6.36027 FWHM

0.9 0.7 0.75 0.8 0.8 1.5 1.5 8.95417 3.2 2.2

CenterGrvty 13.95 16.79 18.44 21.04 21.77 25.27 28.52 17.77883 14.79 21.21 AreaFitT

3519.28526 2042.25403 987.66856 765.45749 806.12161 555.00576 420.17029 34143.56768 9738.20154 3598.39176 56576.12399 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10

0 10 20 30 40 50 60

0 1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³ 7x10³

Data4_G

Data4_A Fitting Results

MaxHeight 2832.71894 2171.18269 1054.5302 354.01417 498.43758 268.79437 189.14025 2611.90751 1806.4792 1672.49013

AreaFitTP 5.5111 3.96883 1.93781 0.7186 0.99348 1.03649 0.72934 61.10164 14.66663 9.33608 FWHM

0.8 0.75 0.75 0.8 0.8 1.5 1.5 8.95417 3.2 2.2

CenterGrvty 13.95 16.79 18.44 21.04 21.77 25.27 28.52 17.77883 14.79 21.21 AreaFitT

2419.28584 1742.25356 850.66848 315.45521 436.12048 455.00494 320.16948 26822.6627 6438.41882 4098.39483 43898.43433 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10

Fig. A5: iPP 30 K/s Fig. A6: iPP 40 K/s

0 10 20 30 40 50 60

0,0 2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴

Data4_H

Data4_A Fitting Results

MaxHeight 673.76484 426.51404 434.70541 241.79032 384.14827 29.5385 29.63634 3859.45971 4919.54674 2010.4658

AreaFitTP 1.12856 0.537 0.5502 0.33805 0.52737 0.07845 0.07871 62.18613 25.79163 8.7839 FWHM

1 0.75 0.75 0.8 0.8 1.5 1.5 8.95417 3 2.5

CenterGrvty 13.95 16.79 18.44 21.04 21.77 25.27 28.52 17.77883 14.79 21.21 AreaFitT

719.28673 342.25384 350.66818 215.4547 336.12017 50.00166 50.16728 39634.24642 16438.25922 5598.40372 63734.86192 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10

0 10 20 30 40 50 60

0,0 2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴

Data4_H

Data4_A Fitting Results

MaxHeight 673.76484 426.51404 434.70541 241.79032 384.14827 29.5385 29.63634 3859.45971 4919.54674 2010.4658

AreaFitTP 1.12856 0.537 0.5502 0.33805 0.52737 0.07845 0.07871 62.18613 25.79163 8.7839 FWHM

1 0.75 0.75 0.8 0.8 1.5 1.5 8.95417 3 2.5

CenterGrvty 13.95 16.79 18.44 21.04 21.77 25.27 28.52 17.77883 14.79 21.21 AreaFitT

719.28673 342.25384 350.66818 215.4547 336.12017 50.00166 50.16728 39634.24642 16438.25922 5598.40372 63734.86192 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10

Fig. A7: iPP 76 K/s Fig. A8: iPP 93 K/s

0 10 20 30 40 50 60

0 1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³ 7x10³ 8x10³ 9x10³

Data4_J

Data4_A Fitting Results

MaxHeight 4098.94463 2362.56614 3591.3519

AreaFitTP 25.50473 10.10734 64.38794 FWHM

3.2 2.2 8.95417

CenterGrvty 14.78747 21.21812 17.77883 AreaFitT

14608.92431 5789.40865 36880.94628 57279.27925 Peak Type

Pearson7 Pearson7 Asym2Sig Peak # 1 2 3

Fig. A9: iPP 986 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0,0

2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴ 1,2x10⁴

Data1_B

Data1_A Fitting Results

MaxHeight 9141.55727

AreaFitTP 100 FWHM

5.05446

CenterGrvty 19.13439 AreaFitT

58235.71136 58235.71136 Peak Type

PsVoigt2 Peak # 1

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0,0

2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴

Data1_C

Data1_A Fitting Results

MaxHeight 8469.32571

AreaFitTP 100 FWHM

4.86795

CenterGrvty 19.37474 AreaFitT

51836.55883 51836.55883 Peak Type

PsVoigt2 Peak # 1

Fig. A10: EOC 0.12 K/s Fig. A11: EOC 24 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0,0

2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴

Data1_D

Data1_A Fitting Results

MaxHeight 7809.01438

AreaFitTP 100 FWHM

4.93879

CenterGrvty 19.36818 AreaFitT

49610.36124 49610.36124 Peak Type

PsVoigt2 Peak # 1

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³ 7x10³ 8x10³ 9x10³

Data1_E

Data1_A Fitting Results

MaxHeight 7211.20908

AreaFitTP 100 FWHM

4.98108

CenterGrvty 19.42273 AreaFitT

46463.66524 46463.66524 Peak Type

PsVoigt2 Peak # 1

Fig. A12: EOC 171 K/s Fig. A13: EOC 200 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0,0

2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴

Data1_F

Data1_A Fitting Results

MaxHeight 8902.31593

AreaFitTP 100 FWHM

4.94331

CenterGrvty 19.33805 AreaFitT

56956.1426 56956.1426 Peak Type

PsVoigt2 Peak # 1

Fig. A14: EOC 600 K/s

WAXD fittings EPDM

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³

Data1_B

Data1_A Fitting Results

MaxHeight 4648.71459

AreaFitTP 100 FWHM

5.99533

CenterGrvty 18.83182 AreaFitT

33208.73414 33208.73414 Peak Type

Pearson7 Peak # 1

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³

Data1_C

Data1_A Fitting Results

MaxHeight 4748.55611

AreaFitTP 100 FWHM

6.03961

CenterGrvty 18.99875 AreaFitT

35099.22634 35099.22634 Peak Type

Pearson7 Peak # 1

Fig. A15: EPDM 4 K/s Fig. A16: EPDM 15 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³

Data1_D

Data1_A Fitting Results

MaxHeight 4616.48263

AreaFitTP 100 FWHM

6.00198

CenterGrvty 19.06086 AreaFitT

32783.79569 32783.79569 Peak Type

Pearson7 Peak # 1

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³

Data1_E

Data1_A Fitting Results

MaxHeight 4632.21574

AreaFitTP 100 FWHM

5.89915

CenterGrvty 19.11765 AreaFitT

32463.47532 32463.47532 Peak Type

Pearson7 Peak # 1

Fig. A17: EPDM 100 K/s Fig. A18: EPDM 700 K/s

WAXD fittings PP/EOC 30/70p

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0,0

2,0x10^-1 4,0x10^-1 6,0x10^-1 8,0x10^-1 1,0x10⁰ 1,2x10⁰

Data1_B

Data1_A Fitting Results

MaxHeight 0.53264 0.3824 0.16295 0.23413 0.24523 0.03472 0.01985 0.21387 0 0 0.72164

AreaFitTP 5.21056 2.80578 1.20248 2.67215 2.27136 0.39541 0.86163 29.16638 0 0 55.41426 FWHM

0.6 0.5 0.5 0.7 0.6 0.55 1.5 8.95417 3.2 2.2 4.34218

CenterGrvty 13.9 16.77269 18.3392 20.87754 21.53025 25.25798 -- 19.07883 -- -- 19.13 AreaFitT

0.38999 0.21 0.09 0.2 0.17 0.0296 0.06449 2.18298 0 0 4.14753 7.48459 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 2,0x10^-1

4,0x10^-1 6,0x10^-1 8,0x10^-1 1,0x10⁰ 1,2x10⁰ 1,4x10⁰

Data1_C

Data1_A Fitting Results

MaxHeight 0.5603 0.47801 0.21992 0.19901 0.22445 0.03018 0.0262 0.21258 0.06963 0.02894 0.73887

AreaFitTP 4.7869 4.18851 2.24577 2.03442 1.79509 0.23935 0.68585 25.94818 3.84275 1.13893 53.09425 FWHM

0.65 0.6 0.55 0.7 0.6 0.6 1.4578 8.94624 3.2 2.2 4.35629

CenterGrvty 13.9 16.77269 18.3392 20.87754 21.53025 25.25798 28.28947 19.08761 14.77103 21.21115 19.13 AreaFitT

0.4 0.35 0.18766 0.17 0.15 0.02 0.05731 2.16827 0.32111 0.09517 4.43664 8.35617 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A19: PP/EOC 30/70p 0.57 K/s Fig. A20: PP/EOC 30/70p 1.9 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 6,0x10^-1

8,0x10^-1 1,0x10⁰ 1,2x10⁰ 1,4x10⁰ 1,6x10⁰

Data1_E

Data1_A Fitting Results

MaxHeight 0.44124 0.25797 0.18753 0.1434 0.1214 0.02546 0.02977 0.21387 0.10113 0.0751 0.75521

AreaFitTP 4.22738 2.05339 1.57025 1.691 0.9663 1.13393 1.16073 26.36769 4.83149 3.57084 52.427 FWHM

0.65 0.6 0.6 0.8 0.6 2.5 1.5 8.95417 3.70976 2.96964 4.34218

CenterGrvty 13.87309 16.70817 18.20203 20.96279 21.53025 25.25798 -- 19.07883 14.42735 21.29446 19.13 AreaFitT

0.34999 0.17 0.13 0.14 0.08 0.09388 0.0961 2.18298 0.4 0.29563 4.34044 8.27901 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 6,0x10^-1

8,0x10^-1 1,0x10⁰ 1,2x10⁰ 1,4x10⁰ 1,6x10⁰ 1,8x10⁰

Data1_F

Data1_A Fitting Results

MaxHeight 0.26014 0.15979 0.06366 0.11937 0.09105 0.02546 0.0397 0.21387 0.17956 0.12383 0.75521

AreaFitTP 2.35784 1.41471 0.81233 1.73733 1.17892 1.11263 1.51453 25.7355 8.2505 4.71568 51.17002 FWHM

0.7 0.65 0.7 0.8 1 2.5 1.5 8.95417 3.5 2.9 4.34218

CenterGrvty 13.95 16.79 18.45883 21.04 21.77 22.88986 -- 19.07883 14.10891 21.45039 19.13 AreaFitT

0.2 0.12 0.0689 0.14737 0.1 0.09438 0.12847 2.18298 0.69984 0.4 4.34044 8.48238 Peak Type Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A21: PP/EOC 30/70p 8 K/s Fig. A22: PP/EOC 30/70p 17 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 1,0x10⁰

1,2x10⁰ 1,4x10⁰ 1,6x10⁰ 1,8x10⁰ 2,0x10⁰ 2,2x10⁰

Data1_G

Data1_A Fitting Results

MaxHeight 0.40818 0.33618 0.09095 0.06373 0.06366 0.01273 0.00496 0.23882 0.17956 0.13931 0.78877

AreaFitTP 2.80547 2.69326 1.10462 0.78553 0.77339 0.52955 0.18021 27.35513 7.8535 5.04986 50.86948 FWHM

0.56 0.65 0.7 1 0.7 2.5 1.5 8.95417 3.5 2.9 4.34218

CenterGrvty 13.95 16.74 18.44 20.88068 21.77 22.88986 -- 19.07883 14.1164 21.35146 19.01107 AreaFitT

0.25 0.24 0.09844 0.07 0.06892 0.04719 0.01606 2.43766 0.69984 0.45 4.53307 8.91118 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 1,2x10⁰

1,4x10⁰ 1,6x10⁰ 1,8x10⁰ 2,0x10⁰ 2,2x10⁰

Data1_H

Data1_A Fitting Results

MaxHeight 0.05603 0.13642 0.04547 0.02458 0.03642 0.00255 0.00992 0.21387 0.20521 0.18575 0.72164

AreaFitTP 0.49514 1.82623 0.60923 0.37133 0.49514 0.11682 0.39755 27.02168 9.90039 7.42703 51.33946 FWHM

0.65 0.7 0.7 1 1 2.5 1.5 8.95417 3.5 2.9 4.34218

CenterGrvty 13.95 16.74002 18.44001 20.88066 21.77 22.88986 -- 19.07883 14.11641 21.35146 19.13 AreaFitT

0.04 0.14753 0.04922 0.03 0.04 0.00944 0.03212 2.18298 0.79982 0.6 4.14753 8.07864 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A23: PP/EOC 30/70p 55 K/s Fig. A24: PP/EOC 30/70p 72 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 -1x10³

0 1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³

Data1_I

Data1_A Fitting Results

MaxHeight 378.20755 238.73241 136.41852 163.88993 136.57237 101.85916 29.7742 1069.33045 1410.81405 773.95752 4615.15607

AreaFitTP 0.6382 0.62626 0.31412 0.42546 0.31911 0.80386 0.20498 23.22059 11.69931 5.31857 56.42954 FWHM

0.65 0.8 0.7 1 1 2.5 1.5 8.95417 3.5 2.9 4.34218

CenterGrvty 13.95 16.79 18.44 21.04 21.77 22.0772 -- 19.07883 14.83151 21.35146 19.13 AreaFitT

299.988 294.37352 147.65262 199.99046 150.00059 377.85514 96.35099 10914.91463 5499.2976 2500.01248 26524.88549 47005.32153 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10

Data1_J

Data1_A Fitting Results

MaxHeight 585.32119 192.38374 63.66198 122.91745 91.04825 12.7324 4.96237 926.75306 1026.04658 928.74903 4078.11973

AreaFitTP 1.22068 0.36623 0.23869 0.36621 0.24415 0.11534 0.03925 23.09549 9.76499 7.3245 57.22447 FWHM

0.7 0.7 1 1 1 2.5 1.5 8.95417 3.5 2.9 4.34218

CenterGrvty 13.95 16.79 18.44 21.04 21.77 21.77 -- 19.07883 15.15018 21.35146 19.13 AreaFitT

499.97307 150.00092 97.7636 149.99285 100.0004 47.24336 16.07609 9459.59268 3999.60636 3000.01497 23438.35336 40958.61764 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A25: PP/EOC 30/70p 80 K/s Fig. A26: PP/EOC 30/70p 120 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 -1x10³

0 1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³

Data1_K

Data1_A Fitting Results

MaxHeight 351.19271 280.14846 129.82575 127.32395 91.04825 18.20965 4.96237 1069.33045 1256.90706 835.87413 4111.6845

AreaFitTP 0.6951 0.46342 0.34757 0.45325 0.23171 0.11586 0.03725 25.29105 11.35234 6.25623 54.75622 FWHM

0.7 0.65 1 1 1 2.5 1.5 8.95417 3.5 2.9 4.34218

CenterGrvty 13.95 16.79 18.44 21.04 21.77 25.27 -- 19.07883 14.79 21.21 19.13 AreaFitT

299.98384 200.00078 150.00163 195.61133 100.0004 50.00018 16.07609 10914.91463 4899.35283 2700.0136 23631.26162 43157.21692 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³

Data1_L

Data1_A Fitting Results

MaxHeight 0 0 0 0 0 0 0 926.75306 1385.16288 692.58144 3859.94871

AreaFitTP 0 0 0 0 0 0 0 23.80171 13.58539 6.7936 55.8193 FWHM

0.7 0.7 1 1 1 2.5 1.5 8.95417 3.5 3.5 4.34218

CenterGrvty -- -- -- -- -- -- -- 19.07883 14.79 21.21 19.13 AreaFitT

0 0 0 0 0 0 0 9459.59268 5399.28679 2700.00172 22184.44968 39743.33087 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A27: PP/EOC 30/70p 192 K/s Fig. A28: PP/EOC 30/70p 860 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0,0

2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴

Data1_B

Data1_A Fitting Results

MaxHeight 6828.74684 4916.69792 2349.2279 1755.96357 2317.5917 363.78273 148.871 1853.50612 561.11922 408.0867 1342.59086

AreaFitTP 11.57995 6.9482 4.40056 3.47407 3.24249 0.91049 0.80704 43.81789 4.63181 2.31607 17.87145 FWHM

0.6 0.5 0.7 0.7 0.55 0.7 1 8.95417 3.2 2.2 4.34218

CenterGrvty 13.95 16.79 18.44 21.04 21.77 25.27 -- 19.07883 14.79 21.21 19.13 AreaFitT

4999.8586 3000.013 1900.02143 1499.99286 1400.00544 393.12185 348.45329 18919.18536 1999.86818 1000.00608 7716.33032 43176.8564 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0,0

2,0x10³ 4,0x10³ 6,0x10³ 8,0x10³ 1,0x10⁴

Data1_C

Data1_A Fitting Results

MaxHeight 5853.21191 3729.28482 2055.57435 1529.63935 1820.96494 90.94568 207.4915 2245.59395 1402.79804 734.55606 1678.23857

AreaFitTP 9.54859 5.15655 3.6287 2.67372 2.86474 0.1877 0.75721 43.77561 9.54847 3.4377 18.42101 FWHM

0.7 0.65 0.8 0.75 0.75 0.7 1 8.95417 3.2 2.2 4.34218

CenterGrvty 13.95 16.79 18.44 21.04 21.77 25.27 28.52 19.07883 14.79 21.21 19.13 AreaFitT

4999.73066 2700.01638 1900.02137 1399.98615 1500.00592 98.28046 396.48097 22921.32073 4999.67044 1800.01095 9645.4129 52360.93693 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A29: PP/EOC 70/30p 7 K/s Fig. A30: PP/EOC 70/30p 16 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³

Data1_D

Data1_A Fitting Results

MaxHeight 2868.07374 1885.99944 961.67225 614.58723 796.67215 79.57747 133.9839 1390.12959 1122.23843 652.93872 973.37837

AreaFitTP 8.65591 4.48295 3.09171 1.85498 2.16418 0.30309 0.96958 43.86906 12.36591 4.94672 17.29591 FWHM

0.8 0.7 0.9 0.8 0.8 0.8 1 8.95417 3.2 2.2 4.34218

CenterGrvty 13.84886 16.71 18.33 21.04 21.77 25.27 -- 19.07883 14.79 21.21 19.13 AreaFitT

2799.74149 1450.00569 1000.0111 599.99054 700.00276 98.03459 313.60796 14189.38902 3999.73636 1600.00973 5594.33948 32344.86872 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³

Data1_E

Data1_A Fitting Results

MaxHeight 1024.31205 967.38761 461.60267 153.64681 227.62061 74.89644 44.6613 1782.21742 2300.58878 1509.92079 1342.59086

AreaFitTP 2.43823 2.07269 1.95077 0.36576 0.48769 0.23875 0.25491 44.35907 19.99395 9.02231 18.81586 FWHM

0.8 0.8 1.5 0.8 0.8 0.85 1 8.95417 3.2 2.2 4.34218

CenterGrvty 13.95 16.75 18.44 21.04 21.70431 25.27 -- 19.07883 14.79 21.21 19.13 AreaFitT

999.91152 850.00335 800.00543 149.99763 200.00079 97.91168 104.53599 18191.52439 8199.45953 3700.02251 7716.33032 41009.70314 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A31: PP/EOC 70/30p 50 K/s Fig. A32: PP/EOC 70/30p 80 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³ 7x10

Data1_F

Data1_A Fitting Results

MaxHeight 819.44964 761.22701 317.35183 512.15603 341.43092 74.89644 14.8871 2495.10439 3366.71529 1224.2601 1678.23857

AreaFitTP 1.50801 1.22536 1.03685 0.94257 0.56555 0.18458 0.06569 48.0119 22.62062 5.65556 18.1833 FWHM

0.8 0.8 1.5 0.8 0.8 0.85 1 8.95417 3.2 2.2 4.34218

CenterGrvty 13.95 16.79 18.44 21.04 21.77 25.27 -- 19.07883 14.79 21.21 19.13 AreaFitT

799.92922 649.99964 550.00373 499.99211 300.00118 97.91168 34.84533 25468.13414 11999.20907 3000.01825 9645.4129 53045.45726 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³

Data1_G

Data1_A Fitting Results

MaxHeight 717.01844 468.44739 173.101 204.86241 227.62061 0 14.8871 2138.66091 3366.71529 1346.68611 1846.06243

AreaFitTP 1.41191 0.80688 0.60516 0.40343 0.40344 0 0.07029 44.03502 24.20474 6.65678 21.40234 FWHM

0.8 0.8 1.5 0.8 0.8 0.85 1 8.95417 3.2 2.2 4.34218

CenterGrvty 13.95 16.79 18.44 21.04 21.77 -- -- 19.07883 14.79 21.21 19.13 AreaFitT

699.93807 399.99978 300.00203 199.99685 200.00079 0 34.84533 21829.82926 11999.20907 3300.02008 10609.95419 49573.79544 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A33: PP/EOC 70/30p 90 K/s Fig. A34: PP/EOC 70/30p 123 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³

Data1_H

Data1_A Fitting Results

MaxHeight 8.1945 11.71118 5.77003 10.24312 11.38103 7.48964 1.48871 1960.43917 3226.43549 1265.06877 1460.06756

AreaFitTP 0.01858 0.02322 0.02322 0.02322 0.02322 0.02274 0.00809 46.46868 26.70347 7.19885 19.48671 FWHM

0.8 0.8 1.5 0.8 0.8 0.85 1 8.95417 3.2 2.2 4.34218

CenterGrvty 13.95 16.79 18.44 21.04 21.77 25.27 -- 19.07883 14.79 21.21 19.13 AreaFitT

7.99929 9.99999 10.00007 9.99984 10.00004 9.79117 3.48453 20010.67682 11499.24202 3100.01886 8391.50923 43062.72187 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 PsVoigt2 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A35: PP/EOC 70/30p 931 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³

Data1_B

Data1_A Fitting Results

MaxHeight 1927.18782 1576.41389 752.37933 819.44967 1040.55141 106.10329 44.6613 623.7761 28.05596 20.40433 3531.21871

AreaFitTP 3.54909 1.67673 1.25755 1.95617 2.23565 0.27526 0.29213 17.79298 0.27944 0.13973 70.54526 FWHM

0.6 0.35 0.55 0.7 0.7 0.6 1 8.95417 3.2 2.2 6

CenterGrvty 14.1 16.9 18.55 21.04 21.77 25.6 -- 19.07883 14.79 21.21 18.83 AreaFitT

1270.00488 600.00134 450.00105 699.99667 800.00315 98.50029 104.53599 6367.03354 99.99341 50.0003 25243.88733 35783.95794 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³

Data1_C

Data1_A Fitting Results

MaxHeight 1891.03773 1062.22951 620.27856 585.32119 650.34463 63.66198 44.6613 463.37653 224.44769 204.04335 2908.06247

AreaFitTP 4.89364 2.2838 1.40291 1.63127 1.63128 0.3181 0.34105 15.43123 2.60987 1.63129 67.82555 FWHM

0.65 0.6 0.6 0.7 0.7 1 1 8.95417 3.2 2.2 6

CenterGrvty 13.95 16.9 18.55 21.04 21.77 25.6 -- 19.07883 14.79 21.21 18.83 AreaFitT

1499.94001 700.00272 430.0048 499.99762 500.00197 97.49969 104.53599 4729.79634 799.94727 500.00304 20789.08369 30650.81313 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A36: PP/EPDM 30/70p 3 K/s Fig. A37: PP/EPDM 30/70p 8 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³

Data1_D

Data1_A Fitting Results

MaxHeight 1558.32057 689.68104 545.52359 344.78727 518.86937 23.79352 33.80705 481.1987 310.46431 436.57242 3207.67902

AreaFitTP 4.13211 1.37627 1.37628 0.9175 1.22335 0.17293 0.26979 15.02179 3.36171 2.44669 69.70159 FWHM

0.7 0.6 0.7 0.71311 0.70359 1.16715 1.13263 8.95417 3.06069 1.7177 5.98024

CenterGrvty 14.1 16.89776 18.55635 21.03847 21.76999 25.55674 -- 19.07883 14.64965 21.21 18.84289 AreaFitT

1351.08442 450.00105 450.00564 299.99825 400.00142 56.54324 88.21449 4911.71158 1099.18635 799.9995 22790.49673 32697.24266 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0,0

5,0x10² 1,0x10³ 1,5x10³ 2,0x10³ 2,5x10³ 3,0x10³ 3,5x10³ 4,0x10³

Data1_E

Data1_A Fitting Results

MaxHeight 1131.08438 491.81432 350.51772 292.14424 489.05856 1.5888E-13 8.73564 427.73218 270.24575 430.69926 2669.67892

AreaFitTP 3.60567 1.14179 1.08191 0.95956 1.37578 1.6616E-14 0.08706 15.74524 3.5985 2.88508 69.5194 FWHM

0.7079 0.59441 0.71122 0.73335 0.71079 1689071186.3 1.16607 8.95417 3.12034 1.74224 6.03692

CenterGrvty 14.1 16.89766 18.56295 21.04737 21.77909 -- -- 19.07883 14.50878 21.21 18.85486 AreaFitT

999.81 316.6034 300.00197 266.07478 381.4882 4.6075E-12 24.14144 4365.96585 997.82096 799.99942 19276.89995 27728.80599 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A38: PP/EPDM 30/70p 22 K/s Fig. A39: PP/EPDM 30/70p 30 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0,0

5,0x10² 1,0x10³ 1,5x10³ 2,0x10³ 2,5x10³ 3,0x10³ 3,5x10³ 4,0x10³

Data1_F

Data1_A Fitting Results

MaxHeight 533.79576 307.78862 276.99497 290.94883 360.86052 1.5888E-13 8.73564 409.91001 405.36862 484.53667 2601.22561

AreaFitTP 1.85943 0.74394 0.92993 0.98567 1.04705 1.7139E-14 0.0898 15.5634 5.56739 3.34773 69.86566 FWHM

0.75 0.6 0.75 0.73335 0.71079 1689071186.3 1.16607 8.95417 3.12034 1.74224 6.03692

CenterGrvty 14.1 16.89766 18.56295 21.04737 21.77909 -- -- 19.07883 14.50878 21.21 18.85486 AreaFitT

499.88842 200.00034 250.00118 264.98604 281.48783 4.6075E-12 24.14144 4184.05061 1496.73145 899.99935 18782.62046 26883.90712 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³ 6x10³

Data1_G

Data1_A Fitting Results

MaxHeight 700.60693 227.62061 115.40067 290.94883 360.86052 1.5888E-13 8.73564 773.48236 981.95863 571.32138 4326.24891

AreaFitTP 1.53624 0.32928 0.21952 0.5817 0.61792 1.0114E-14 0.053 17.33143 7.68272 3.07331 68.57489 FWHM

0.8 0.6 0.75 0.73335 0.71079 1689071186.3 1.16607 8.95417 3.2 2.2 6.03692

CenterGrvty 14.1 16.89766 18.56295 21.04737 21.77909 -- -- 19.07883 14.79 21.21 18.85486 AreaFitT

699.81343 150.00058 100.00113 264.98604 281.48783 4.6075E-12 24.14144 7895.12158 3499.76931 1400.00852 31238.4635 45553.79337 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A40: PP/EPDM 30/70p 58 K/s Fig. A41: PP/EPDM 30/70p 76 K/s

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0

1x10³ 2x10³ 3x10³ 4x10³ 5x10³

Data1_I

Data1_A Fitting Results

MaxHeight 51.2156 106.22295 75.73169 164.68802 128.19805 74.2723 3.11511 427.73218 561.11922 508.7481 3422.66528

AreaFitTP 0.15015 0.21023 0.21023 0.45046 0.30032 0.20713 0.02591 13.11203 6.00608 5.10553 74.22193 FWHM

0.8 0.6 0.8 0.73335 0.71079 0.6 1.16607 8.95417 3.2 3 6.03692

CenterGrvty 14.1 16.89766 18.56295 21.04737 21.77909 25.27 -- 19.07883 14.79 21.21 18.85486 AreaFitT

49.99584 70.00027 70.00079 149.9921 100.00038 68.96846 8.62631 4365.96585 1999.86818 1700.00791 24713.97429 33297.4004 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10 11

4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 0,0

5,0x10² 1,0x10³ 1,5x10³ 2,0x10³ 2,5x10³ 3,0x10³ 3,5x10³ 4,0x10³

Data1_J

Data1_A Fitting Results

MaxHeight 96.54377 24.05773 13.8534 49.66582 100.94065 0 0 356.44348 530.62903 478.30731 2955.83778

AreaFitTP 0.34536 0.0739 0.074 0.15702 0.10559 0 0 12.87996 7.03892 4.52073 74.80451 FWHM

0.6352 0.81237 1.41475 0.80823 0.21357 1.05909 0.34988 8.95417 3.04292 2.41044 6

CenterGrvty 14.1 16.83571 18.57803 21.06174 22.01212 -- -- 19.07883 14.78829 21.21 18.83 AreaFitT

97.55531 20.87501 20.90417 44.35557 29.82705 0 0 3638.30488 1988.33994 1277.0067 21130.61863 28247.78725 Peak Type

Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Pearson7 Asym2Sig Pearson7 Pearson7 Pearson7 Peak # 1 2 3 4 5 6 7 8 9 10 11

Fig. A42: PP/EPDM 30/70p 98 K/s Fig. A43: PP/EPDM 30/70p 180 K/s

Im Dokument Characterisation of the influence of cooling rates on structure and properties of dynamic vulcanizates (Seite 107-134)