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4. VIP - A Risk Quantification Approach 57

4.2. Vulnerability used in a Risk Context

The central point of the VIP concept are the four well vulnerability criteria by Frind et al.

(2006) (step 7), set into a probabilistic context (step 8). These two steps are the essential conceptual steps of the VIP framework and need much more explanation than it has been provided in the nine-step overview of Section 4.1. Therefore, both steps are discussed in more detail in the following.

4.2.1. Step 7: Well Vulnerability Criteria (WVC)

The four intrinsic and deterministic well vulnerability criteria are (see Fig. 4.2):

1. The timetpeakbetween a spill event and arrival at the well.

2. The level of peak concentrationcpeakrelative to the spill concentrationcspill.

3. The time treact to breach a given threshold concentrationccrit (e.g., a drinking-water standard).

4. The time of exposuretexpduring which the threshold concentration is exceeded.

The first criterion tpeak represents the most common time-related capture delineation scheme. For example, German guidelines (e.g., DVGW, 2006) state, that the critical

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Figure 4.2.: Well vulnerability criteria after Frind et al. (2006), cast into a probabilistic framework.

travel time to ensure microbiological safety of drinking water isτcrit = 50d. By orig-inal definition, the capture zone is delineated according to the bulk arrival of con-centration, often denoted ast50. Advective-based or advection-dominated transport models commonly use the measure of bulk arrival time, as peak and bulk arrival times are identical for symmetric (i.e., almost Gaussian) breakthrough curves and also at the advection-dominated limit. The VIP concept uses the arrival time of peak concen-tration instead of bulk arrival in order to delineate wellhead protection zones, as the often observed tailing of breakthrough curves typically leads to earlier peak arrival tpeak than bulk arrivalt50 in heterogeneous media (see Section 3.6). Therefore,tpeak is the more conservative and relevant criterion to be considered in risk analysis. The effect of usingtpeakinstead oft50is shown and discussed further in Section 8.3.

The second criterion, peak concentrationcpeak, accounts for dilution of peak concentra-tions by pore-scale dispersion, sub-grid dispersion, heterogeneity and direct dilution within the pumping well. As discussed in Section 3.6, assessing this criterion excludes all upscaled (e.g., parameterized Fickian) macrodispersive approaches, because they fail to reflect actual levels and arrival times of peak concentrations (see discussion on bulkt50and peak arrival timetpeak, Section 8.3). The peak concentrationcpeak forms the basis for human-health risk assessment related to acute doses (see Fig. 7.2 and Tab. C.1).

The third criterion treacttells water managers the time available to react after a spill event before critical contaminant levels are being exceeded at the well. This is the most im-portant information to design early-alert sensor or monitoring systems, and to plan emergency measures, even for worst-case most early arrival of low concentrations on any desirable confidence level. Knowing the probability distribution oftreactdelivers

the information basis for operational risk assessment for setting up mitigation mea-sures.

The fourth criterion, the timetexpabove a certain critical concentration level, is equivalent to well down-time. It can serve as a measure for the damage in economic risk analysis, that a catchment manager or the water supply company has to cope with. The time out of operation can then easily be expressed monetarily, and the expected financial loss can be compared to the costs of alternative risk treatment methods within risk-informed management decisions. If a spill remains undetected, exposure timetexp is also an important impact factor for chronic health risk. Furthermore, well down-time indicates the consequences related to customer being without drinking water (e.g., Lindhe et al., 2009), due to failure within the supply system. Therefore, exposure time texp forms the basis for economic and operational risk management, and assessment of chronic health-effects (see Fig. 7.2).

Thus, well vulnerability criteria play a critical role in risk management from the economic, environmental or human safety point of view. Furthermore, they can be used as Environ-mental Performance Metricsas introduced by de Barros et al. (2012). In summary, well vulner-ability criteria deliver indispensable risk-based information on:

1. the possible detriment, such as the maximum extent of acute health effects via peak concentrations (WVC2), the possible extent of chronic health effects by long-term ex-ceedance of threshold levels (WVC4), or the magnitude of economic loss due to well down-time (via the duration of excessive concentration levels in the well, WVC4), 2. the prioritization of contaminant sources at different locations within the catchment,

e.g., due to shorter available reaction time (via the time until threshold arrival, WVC3), or due to larger potential of adverse health effects or economic loss (see item above), 3. the economic value of suggested risk mitigation measures, e.g., by cost efficiency

anal-ysis or by conducting a cost benefit analanal-ysis with the customers willingness to pay (e.g., Lindhe et al., 2011), and

4. the suggested areal outlines for wellhead protection zones that are directly linked with the transport physics to the well (WVC 1) that deliver management options as de-scribed in detail in Section 6.2.

Please note, that the third and fourth well vulnerability criterion require a pre-defined threshold concentration level,ccrit, on which the resulting well vulnerability values depend on. This concentration-based threshold level is not necessarily coinciding with the critical performance levels, introduced for the probabilistic vulnerability concept (see next). In or-der to avoid misunor-derstanding, the critical performance levels are denoted by greek letters or byW V Ccritand the concentration threshold level asccrit. The well vulnerability criteria only depend on the shape of the concentration breakthrough curve. Thus, also monitored breakthrough curves can be interpreted in the light of the well vulnerability criteria with the limitation that monitoring-based VIP cannot be used for risk prevention.

Possibilities to Combine the Four Criteria

Together, the third (time to react) and the fourth vulnerability criterion (well down-time) provide the necessary information for financial optimization of risk treatment alternatives, while criteria one and two yield the essential information for toxicity assessment in human-health risk assessment and for compliance with classical time-related delineation laws. An example for a contaminant-specific aggregation of vulnerability characteristics to augment the second and fourth well vulnerability criteria is

Z

0

(c(t)−ccrit)ψdt, (4.1)

withψbeing a dimensionless weighting factor that water managers are able to non-linearly weigh the severity of impact (response), e.g., within a non-linear dose-response relation-ship. Eq. (4.1) can also be interpreted as a linear non-carcinogenic human-health risk model (due to the threshold-based concentration) withψ = 1and, when the averaged concentra-tion over time is multiplied with some toxicologically-based parameter (e.g., the lethal dose LD50 or slope factor in cancer risk assessment) that depends on a dose-response relation-ship.

As a simplistic approach for combining all four intrinsic well vulnerability criteria, the over-all maximum extent of the delineated areas for a certain isopercentile for over-all four criteria is available. This would yield the highest reliability in providing safe and clean drinking water. This is similar to Sousa et al. (2012), who dealt with capture zone delineation uncer-tainty by taking the maximum extent from all model scenarios. More sophisticated ways to combine the four intrinsic vulnerability criteria to one simple rule of delineation could be defined on a case-to-case basis, reflecting the individual preferences of the water man-ager. Although a ”unified“ risk measure is possibly available, I do not recommend this type of aggregation, but rather propose a multi-objective optimization to find along a Pareto front the best solution, that is most suitable for the different interests of stakeholders (see Section 11.4). Risk assessment and management is based on a singular risk objective (see Section 3.2) to which the well vulnerability criteria provide quantitative risk measures. Con-sidering a unified approach blurs the actual risk picture. This is demonstrated later in this thesis (see Section 10.3), where I compare the prioritization of hazards given two different risk objectives. The discussion on stakeholder conflicts and a unit risk measure is continued in Section 7.1.

4.2.2. Step 8: Vulnerability Isopercentiles (VIP)

In order to account for epistemic uncertainty, which evolves through the lack of knowl-edge about the system to be modeled, the four deterministic well vulnerability criteria by Frind et al. (2006) are set into a probabilistic framework (see Fig. 4.2). As discussed in Sec-tion 3.6.4, it is irresponsible to perform risk analysis and management without considering epistemic uncertainty. Only by admitting and considering the effects of model and parame-ter uncertainty, the required probability distributions for contaminant peak concentrations, travel times, threshold arrival times and well down-time can be simultaneously obtained

for each location across the domain. These probability density functions enhance the infor-mation available for risk managers. They provide inforinfor-mation on expected damage and the damage related to a pre-defined confidence interval. This is in line with the US EPA (2001) guidelines, calculating human-health risk from individual contaminants and comparing the probability distributions to contaminant specific critical values.

The easiest way to set a deterministic model into a probabilistic framework is by Monte Carlo simulation, varying the input parameters for each realization to account for epistemic uncertainty. The four intrinsic well vulnerability criteria are evaluated for each Monte Carlo realizationj = 1, . . . , nr at all points xi in the domainΩ. As a result, the full probability distribution of the corresponding well vulnerability criteriakfor each locationxi is avail-able. If additional information is available in form of direct and/or indirect measurements, the model can be calibrated on the available data d0 (step 3), leading to the posterior or conditioned probability density distribution for thek-th criterion:

Pk(W V Ck ≥W V Ck,crit|x=xi,d0)≈ 1 nr

nr

X

r=1

Ik,r(xi), (4.2) whereIk,r(xi)is an indicator function that assumes a value of unity in realizationr, if thek -th criterion is larger -than -the valueW V Ck,critat locationxi within the domainΩ, and zero otherwise. When choosing a certain critical value W V Ck,crit, Eq. (4.2) yields catchment-wide probability mapsPk(x)of exceeding (or falling below) a critical levelW V Ck,crit for wellhead protection. The concept of critical values is in line with the concept of perfor-mance criteria introduced by James and Freeze (1993) to judge the risk of system failure.

When plotting these probability maps as iso-probability contours, one obtains so-called vul-nerability isopercentiles (VIPs). This follows the idea of percentile capture contours (e.g., Cole and Silliman, 2000) and probabilistic isochrones (e.g., Guadagnini and Franzetti, 1999), which express the uncertainty in capture delineation of wellhead protection zones.

Compared to the non-probabilistic well vulnerability criteria, the VIPs deliver additional probabilistic information, such as:

1. Theprobability of peak arrival from all potential spill locations to be faster than a re-quired minimum time (e.g., 50 days). The probability distribution of tpeak delivers the information necessary to assess the risk of not meeting the legal regulation about time-related delineation. This allows to rationally choose larger catchment outlines for safety reasons.

2. The probability of peak concentrations in the well to be larger than some maximum allowed level (e.g., an MCL). The statistics of cpeak form the basis for human-health risk assessment, providing information on acute doses (see Fig. 7.2 and Tab. C.1), and allows to judge the compliance with legal threshold concentrations.

3. Theprobabilityof the time window available to react (=reaction time) after a spill event until a critical concentration level is exceeded in the well (e.g., drinking water stan-dard) to be smaller than a minimum critical value (e.g., 10 days) required to take ad-equate counter measures. This is of importance to asses the reliability of monitoring systems and thus allows to judge the compliance of the operational processes.

4. The probabilitythat the well has to be shut down or is exposed to a non-compliance contamination level for more than a given critical duration. The statistics of exposure time texp form the basis for economic and operational risk management, and assess-ment of chronic health-effects (see Fig. 7.2).

The threshold levelccritfor the third and fourth vulnerability criteria and the critical values W V Ck,critfor calculating the VIPs used in Eq. (4.2) are specific to each investigated situa-tion and supply company. Often, hard data are given by regulatory agencies (e.g., drink-ing water standards), dependdrink-ing on the properties of the contaminants under investigation (bacteriological, chemical, and so forth). In all other cases, the technical situation or the risk acceptance level of the water supply company will determine the threshold values. Also, the risk measures in the second risk quantification framework (STORM, see Chapter 7) will depend on the a-priori defined critical threshold valueccrit.

Like the well vulnerability concept, the presented VIP concept is independent on the mod-eling framework. In this thesis, I will show how VIP maps are calculated for two different modeling problems in the upcoming Section 4.3.