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Synthesis and Molecular Structure of [Fe2

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Synthesis and Molecular Structure of [Fe

2

Cl

2

( µ -S-tBu)

2

( η

1

- η

1

- µ -dppe)]

(dppe = Ph

2

P(CH

2

)

2

PPh

2

)

Han Vinh Huynh

a

, Roland Fröhlich

b

, and F. Ekkehardt Hahn

a

a Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Wilhelm-Klemm-Straße 8, D-48149 Münster

b Organisch-Chemisches Institut,

Westfälische Wilhelms-Universität Münster, Corrensstraße 40, D-48149 Münster Reprint requests to Prof. Dr. F. E. Hahn.

E-mail: fehahn@uni-muenster.de Z. Naturforsch.5 8 b,359Ð361 (2003);

received January 16, 2003

The red title compound was synthesized by the metathesis reaction of [FeCl2(dppe)] (dppe = Ph2PCH2)2PPh2) and NaS-tBu in THF. The X-ray structure analysis revealed a dinuclear complex with two iron(II) centers coordinated in a dis- torted tetrahedral fashion by two bridging thio- lates, one bridging dppe molecule and one termi- nal chloro ligand.

Key words:Dinuclear Complexes, Iron, Thiolates

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