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Crystal Structure of a Lithium Chloride Cubane Cluster Solvated by Diethyl Ether

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Crystal Structure of a Lithium Chloride Cubane Cluster Solvated by

Diethyl Ether

Norbert W. Mitzel and Christian Lustig

Anorganisch-chemisches Institut,

Technische Universität München, Lichtenbergstr. 4, DÐ85747 Garching Reprint request to Dr. N. W. Mitzel.

Fax: +49 (0) 89 28 91 31 47

Z. Naturforsch.56 b,443Ð445 (2001);

received March 2, 2001

Lithium Chloride, Aggregation, Crystal Structure The thermally highly unstable diethyl ether sol- vate of lithium chloride was crystallised and its crystal structure determined. It consists of a cubic cluster of the composition Li4Cl4with each of the four Li atoms coordinated to a molecule of di- ethyl ether.

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