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Influence of Chromium Ions on the Dielectric Properties of the PbO-Ga

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Influence of Chromium Ions on the Dielectric Properties of the PbO-Ga

2

O

3

-P

2

O

5

Glass System

Gnanaprakasm Little Flowera, Maddireddy Srinivasa Reddya, Musugu Venkata Ramana Reddyb, and Nalluri Veeraiaha

aDepartment of Physics, Acharya Nagarjuna University - Nuzvid Campus, Nuzvid-521 201, A. P., India.

bDepartment of Physics, P. G. College of Science, Saifabad, Osmania University, Hyderabad-500 004, India

Reprint requests to N. V.; Fax: 91-8656-235200; E-mail: nvr8@rediffmail.com Z. Naturforsch.62a,315 – 323 (2007); received Dezember 3, 2006

PbO-Ga2O3-P2O5glasses containing different amounts of Cr2O3, ranging from 0 to 1.0 mol%, were prepared. The dielectric properties (viz., constantε, loss tanδ, ac conductivityσacover a wide range of frequencies and temperatures, dielectric breakdown strength) have been studied as a function of the concentration of chromium ions. An anomaly has been observed in the dielectric properties of these glasses, when the concentration of Cr2O3is about 0.4 mol%. This anomaly has been explained in the light of different oxidation states of chromium ions with the aid of data of differential thermal analysis and optical absorption spectra of these glasses.

Key words:PbO-Ga2O3-P2O5Glass; Dielectric Properties; Cr2O3.

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