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Paleohydrography of the Great Belt, Denmark, during the Littorina Transgression:

the isotope signal

KYAW WINN, HELMUT ERLENKEUSER, KJELL NORDBERG, MlKAEL GUSTAFSSON

WINN, KYAW; ERlENKEUSER, HEUvlUT; NORDBERG, KJELL; GUSTAFSSON, MiKAEl, 1998:

Paleohydrography of the Great Belt, Denmark, during the Littorlna Transgres- sion: the Isotope signal. (Palaohydroqraphie des GroBen Belts wanrend der Uttorina-Transgression: das rsotoptsche Signal). - Meyniana, 50, 237-251, 6 Fig., KIel.

The marine transgression Into the Baltic Sea through the Great Belt took place around 9,370 calibrated 14C_years B,P. The sedimentary sequence from the early brackish phase and the change to marine conditions has been investi- gated in detail through 14C-datings, and oxygen and carbon isotope measure- ments, and is interpreted by comparison with modern analogs.

The oldest brackish sediments are the strongly laminated clays and silts rich in organic carbon followed by non-laminated heavily bioturbated silts. The bed- ding and textural characteristics and stable isotope analyses on Ammonia beccarii (dextral) and A.beeearii (sinistral) show that the deposltlonal condi- tions respond to a change at about 9,100 cal, a S.P. from an unstratified brackish water environment in the initial stage of the Littorina Transgression to a thermohaline layered milieu in the upper unit. The oxygen isotope results indicate that the bottom waters of this latter period had salinities and tempera- tures comparable to the present day Kiel Bay waters. The isotopic composition of the total organic carbon and the

e

13e -values ofA. beccarii reveal a gradual change from an initially lacustrine!terrestrial provenance toward a brackish!

marine dominated depositional environment. A stagnation of the sea level at around 9,100 to 9,400 a. S.P. is Indicated.

DR. K.WINN, Institut fUr Geowissenschaften der Christian-Albrechts-Universitat zu Klel, 0-24098 Klel, kw@gpl.unl-klel.de

DR. H. ERLENKEUSER, Leibniz-Labor fur Altersbestimmung und lsotopenforschung der Chrlstian-Albreehts-Unlversltat zu KIel, 0-24098 Klel.

DR. K. NORDBERG & M. GUSTAFSSON, M.Se, Dept. of Oceanography, Earth Sciences Centre, Gbteborg University, p.a. Box 460, S-405 30 Gbteborg, Sweden.

Kurzfassung

Die marine Transgression in die Ostsee durcn den GroBen Belt fand ca. 9,370 Jahre S.P.

(kalibrierte 14C-Jahre) statl. Die Sediment-Sequenz van den fruhen Meerwasser-Ingressionen bis zu den endgultigen marinen Bedingungen wurde detaillierl mit Hllte van 14C-Datierungen

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und der Messung stabiler Isotope an benthischen Foraminiferen untersucht, wobei die Interpre- tation durch Messungen an rezenten Analoqverhaltnissen gestUlzt wurde.

Die altesten brackischen Sedimenle sind laminiert8 Toneund Silte rrut hohen CC,g-Gehalten.

Sowohl die Charakteristik der Schichtung wie die Korngr6Beneigenschaften und die anAmmo- nia becceni (sinistral) undA.beccarii (dextral) durchgefOhrten Analysen stabiler Isotope weisen darauf hln, daB diese Serie zunachst in einem Milieu mit ungeschichtelem Wasserk6rper entstand, in dem sich dann im Zuge der Transgression eine ausqepraqte Sprungschicht entwickelt hat. Die "C-Altersbestimmungen ergaben 9.100 cal. a S.P. Die Ergebnisse der Sauersloffisolopenanalysen deuten darauf hin, daB Salzgehalte und Temperaturen des Boden- wassers unter der thermohalinen Sprungschlcht denen der heutigen Kieler Bucht vergleichbar waren. Das kaltere, sauerstoffreiche Bodenwasser fOhrte zu verstarkten biologischen Aktivita- ten, wie sich an der vollstandiqen Zerstbrung der Feinschichtung bzw. Durchmischung des Sedlmentes zeiqt. Die !sotopenzusammensetzung der orqanischen Gesamt-Kohlenstoff-Frakti- on sowie die

o

i 3C-Werte van A.beccarfizeigen einen Wechsel van einem terrestrisch/lakustrin zu einem brackisch/marin gepragten Ablagerungsraum.

Introduction

The Holocene marine invasion of the Baltic, commonly termed the Littori- na Transgression after the Gastropod Littorina littorea LINNE, is recorded in the sedimentary succession through a sequence ranging from lake marls to pears. clay gyttjas and brackish to marine clays. The transgression first had an impact on the then existing freshwater lakes and made brackish environ- ments develop before marine conditions were reached with foraminifera species as found today in the Skagerrak and North seas (WINN 1974). The transgression commenced around 9,370 dendrochronologically calibrated years B.P. (8,340 a B.P. conventional 14C-age, ERlENI\EUSER et al. 1975;

calibration after STUIVER&REIMEI1 1993), when the sea reached the level of the thresholds in the Great Belt Channel at about 27 m below rn.s.l. The marine incursions were first held back from the main Baltic Sea by the Darss threshold and remained confined to the Kiel and Mecklenburg Bays (SAURA- MO 1958; KOlP 1965). Studies on the Late Weichselian to Recent hydrogra- phic development of the Kattegat and Skagerrak indicated a stratified struc- ture of the water column possibly related to inflow of saline water around 10,000 cal. a B.P. (CHRISTENSEN etal. 1993) and showed full attainment of the modern circulation patterns about 8,400 cal. a B.P. (CONRADSEN & HEIER- NIELsEN 1995). WINN et al. (1988) found a low salinity event in the Kiel Bay at around 6,800 cal. a B.P. NORDBERG (1991) gave evidence of a hydrographic shift in the Kattegat at around 4,450 cal, a B.P. and two minor shifts at 1,960 cal. a B.P. and 490 cal. a B.P.

At present, a strong thermocline between 15-20 m separates the inflow- ing saline waters at depth from the outflowing brackish waters at the surface.

This situation is particularly pronounced in the late spring and early summer, due to the seasonality of the meteorological cycle. The volume of outflow

Cl (~

(E

w

(E L

a~

st d in gl cl

m m (6 SE pi tic cl

bE

cl 1~

fa (V

K. W,NN et al.

238

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Paleohydrography 01 Ihe Great Belt, Denmark... 239

---~ .---~~_._-~- ---_._._._----_._--~.._ - - - (62%) far exceeds that of inflow (DIETRlcH 1950), a feature typical of an inland sea in a humid climate (SEIBOLO 1971),

In the sediment succession, the basal brackish clays of the transgression phase are laminated (Unit 0; see, e.g., Fig. 3) showing varve-like alterna- tions on the radiographs. These deposits are followed by non-laminated clays (Unit E) with a significantly higher microfaunal diversity. The boundary between these two lithostratigraphic units is also marked by a noticeable change in the relative abundance of the sinistral to dextraiA. beccetii (WINN 1974), The coiling ratio of these species varieties was applied successfully for paieohydrographic reconstructions in the Great Beit and the Kiei Bay (WINN 1974; WINN et al. 1988).

The objective of the present study is to investigate the history of hydro- graphy in the eariy phase of the Littorina Trangression, to determine the change of the environmentai factors related to the changes in the faunal assemblage and in the bedding characteristics. We have determined the stable isotope signature of the benthic foraminiferA. beccetii (sinistral and dextral) in order to analyse the temperature and salinity conditions and gain information as to the structure of the water column during this episode.

Cores 12519-2 (55'24,TN, 100 5 8 . 4 ' E ;

water depth 25.5 m), 12522-2 (55°22.6'N, 100 5 6 . 8 ' E ;

27.2 m) and 12523-1 (55'24.2'N, 100 5 9 . 5 ' E ;

24 m) were raised north of the thresholds in the Great Belt, while core 12594-2 (55°5.0'N, 11°1.0'E; 39.6 m) was retrieved from the channel northeast of langeland Island (Fig, 1). The specimens of the modern A. beccarii were collected from surface sediments of the Havstens Fjord, eastern Skagerrak (Sweden) between August 1993 and December 1994,

The authors are grateful to Messrs. MiCHAEI. ROSLER and HANS H. CORDT for carrying out the mass spectrometer measurements, and to OR. FRIEDRICH WERNER forhelpful comments onthe manuscript.

Methods

A. beccarl!occurred abundantly in the laminated clays of Unit 0 and non- laminated clays of Unit E in the Great Belt Channel. From the available samples, carbonate shells were concentrated through flotation in CCl. (WINN 1974). Sinistral and dextral forms ofA. beccariiwere picked and sorted into 250-400pm, 400-500 pm and >500 pm size fractions under the micro- scope. In most cases, about 50 to 200 specimens were available. This large a number greatly smoothed out any natural isotopic variability among the specimens and ensured a high statistical significance of the results. The specimens were cleaned under methanol in a sonic bath for about 10 seconds. A longer sonification would have resulted in an intolerable heavy fragmentation as the shells were very thin and fragile. Most of the stable isotope measurements were made on a VG Micromass 6020 mass spectro-

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meter. Non-automated CO2 gas preparation was applied on individual sam- ples reacting (>200 f.lg) with 100% orthophosphoric acid at about 50°C under vacuum. l.ater on, for sediments with limited occurrenceofA. beccarii and for the modern series, a Finnigan MAT 251 mass spectrometer with the automated Kiel-1 carbonate preparation device was used, which allows analyses down to 10 f.lg of weight (6 f.lg in a modern set-up). Again, individual reaction with phosphoric acid is applied (in vacuo, 73°C). Isotopic stability was controlled on a daily basis by replicates of an internal standard (Solnhofen limestone). Calibration to the international POB-scale was achiev- ed via the NBS 20 international isotope standard. For both analytical proce- dures, the external reproducibility is better than ±0.1O%0 for

0

' 8

0

and :.!:0.05%0 for

0

' 3C . .

The radiocarbon data were calibrated by means of the Bidecadal Data Set (STUIVER & REIMER 1993). A correction for a marine reservoir effect has not been applied, as the close atmospheric contact of the Baltic Sea waters will largely cancel any reservoir effect of the different source waters. Moreover, most samples show a significant contribution of terrigenic organic carbon as evidenced by the stable carbon isotopes.

In order to gain a modern environment of some relevance to the paleois- otopic aspect for reference, a series of living and dead specimens of A.

beccarii, collected monthly from the Havstens Fjord, Sweden, was used for

240 K.WINI~et al.

°

5'

f

12594

E

Fig. 1: Location of cores

11° 5' isol

riee stai call TON wit! stal sali

rad site unit 197 bet vari yOL cor Iy.: on laci aut, ty t ab! cor see yee pro

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14C

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(5)

16 - Meymana

isotope analysis. Regular salinity and temperature measurements were car- ried out along with the sediment sampling at the 12 m, 20 m, 30 m and 40 m stations. From these data, a hypothetical isotopic equilibrium composition of calcite was calculated applying the palaeotemperature equation of SHACKLE- TON (1974). The regression of the oxygen isotope composition of the water with salinity was taken into account as -0.25 %o/psu (W,NN et el. 1988), starting with an Atlantic Norwegian Sea water of 35.2 psu (psu = practical salinity units) and

Ow

= 0.04%0 (ERLENKEUSER 1985),

Results

Core 12522 (Fig. 2) penetrated the oldest sediments of this study. The radiocarbon dates show that the freshwater peat and lake marls were depo- sited between 9,870 and 9,370 cal. a B,P, (ERLENI\EUSERetet. 1975), The clay unit contained more dextral coiling A beccarii than sinistral specimens (W,NN 1974), The oxygen isotope levels in Unit D remained fairly stable and ranged between -5.4%0 and --6,5%0, The carbon isotope ratios also reveal little variability but show a tendency towards the lighter ratios upwards, The youngest

0

180 and

0

13C levels, however, from the topmost centimeter of the core (Unit G)are significantly increased, at -1 ,95%0 and -1,32%0 respective- ly, The

0

13C values of the total sedimentary organic carbon measured earlier on this core (ERLENKEUSER et et. 1975), indicate a predominantly terrestrial to lacustrine source for the organic carbon of Unit D, but with an increasing autochonous input in the upper part of the sequence,

Cores 12519 and 12523 (Figs, 3, 4) represent the stratigraphical contigui- ty to core 12522, and are mainly composed of Units D and E, unconform- ably overlain by thin covers of modern sediments (Unit G). 14C-dating on core 12519 (ERlENKEUSER et al. 1975) indicated that the major part of the section cored was deposited within a relatively short period of about 300 years giving very high sedimentation rates of 0,7 to 1,0 cm/yr and thus provides an excellent time resolution for this interval. The higher ages in the overlying laminated clays of Unit D are likely due to older reworked organic materials, a major part of which appears marine as evidenced by the lighter carbon isotopes of the total sediment

(O'

3CS) ,Resuspension of older deposits, redeposition, and bioturbation are well known processes in the marine realm to provide too high an 14C_age, For the modern Baltic, sediment surface 14C-ages of about 1000 a have been found (ERLENKEUSER 1979),

The oxygen and carbon isotope ratios measured in Unit D in both cores fell within the same range as those in 12522. Again, the stable isotope figures in the overlying Unit E differ drastically from those of Unit D, and closely group around -3%0 for oxygen and -1,0%0 for carbon, The transition occurs within 10 cm in the 14C-dated core 12519 (Fig. 3), indicating an abrupt event. 0' 3C of total organic carbon showes a similar shift, which, ividual

sarn

about 50°C 'f A. beccarii sterwith the thich allows -up). Again,

"C). Isotopic lal standard was achiev- ytical proce- tr

0

180 and ecadal Data ttecthas not a waters will s. Moreover, ic carbon as the paleois- .irnens of A.

vas used for

Paleohydrography of the Great Belt, Denmark ... 241

(6)

16~

isotop bound the re, consis reveal:

start b

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laminated lake marts clay K. W,NN et al.

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polychaete tubes Fig. 2: Isotope results and sedimentary succession in core 12522, Great Belt.

however, began earlier in the laminated ciays of Unit D. The 8' 3C·values are much higher than in Unit D but do not attain typical marine levels.

Core 12594, which was taken south of the thresholds from much deeper water (39.6 m), aiso showed similar shifts as the northern cores in the stable 242

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Fig. 3: Isotope results and sedimentary succession in core 12519, Great Belt.

Paleohydrography of the Great Belt, Denmark.. 243

_ _~• • •_ ~ . ~_ _ • _ _ • • • . _ ,_ . _ . . ~ . • • •w _ _••_

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isotope values (Fig. 5) to the heavier fractions across the Units D and E boundary. Despite of the different water depths, the similar isotope levels of the respective units in all the cores indicate a comparatively uniform and consistent bottom water mass in the region. In detail, however, core 12594 reveals the isotopic transition from the lighter level of Unit D toward Unit E to start below the DIE-boundary,

deeper stable res are

I.

(8)

8180of the modernA. beccariifrom 12 m water depth, Havstens Fjord,E.

Skagerrak, show only greatly restrained seasonal variations. Comparing the measured 8180values with the hypothetical isotopic equilibrium composition of calcite indicates that the seasonal samples of Ammonia show little re- sponse to the expected variation (Fig. 5). Regardless of the possible uncer-

Fig. 4: Isotope results and sedimentary succession in core 12523, Great Belt.

tainty figurE grow retair

F,

I

3 I

2,5 -'-

,

2

400·500 urndextral 400-500pmsinistral 500urn<'Hsinistral -

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244

(9)

Fig. 5: Isotope results and sedimentary succession in core 12594, N. Langeland Belt.

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, - - - - 1 - - - · - -

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sinistral

-~+-+-+~~.

dextral - ,-

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tainty of the vital effect - the 20 m station results (not shown) restrict this figure to 0.5 to 1%0 - Ammonia is very likely to experience its major shell growth and calcification in the late spring/early summer. This level is then retained and carried over into the following year.

Paleohydrography of the Great Belt, Denmark.. 245

- ~ - - - ~ . ~ ~ - - - ~ - - - -- - - - -- - --- --~--- - - lld, I

ItJ1111'

)sillOli tIf) ",

Jn(.:C) I

(10)

Fig. 6: 0'80 time series ofA. beccariiin Havstensfjord, eastern Skagerrak, W. Sweden.

Measured ~)l80 has been corrected by -1%0for vital offset.

Discussion The results confirmed the large shift in 1)18

0 and 1)13C of A. beccarii observed at the base of cores 12864 and 12880/12886 in the Kiel Bay (WINNet al. 1988). The oxygen and carbon isotope niveaus in Units Dand E (Fig. 2-5) are comparable and indicate that these units which depict similar bedding characteristics, are also present in the Kiel Bay.

Investigations of the Holocene sea level rise in the Western Baltic (KOLP 1979;WINN et al. 1986) showed that the sea level stagnated or even regres- sed slightly around 27 m below m.s.l, for a brief period around 9,000 to 9,400 cal. a B.P. Since the investigated cores are situated in a tectonic hinge area stable as to uplift or subsidence (GuTENBERG 1941), the present levels in the cores represent, more or less, the original depths of the sediment horizons. Therefore, after the sea-level curve (WINN et al. 1986), the water depths in the Great Belt must have been just a few meters around 9,400 a B,P, during the deposition of Unit Dat the geographical positions of cores 12519,12522and 12523.

The 1)' 80 -levels ofA. beccarii are lighter by about 3%0 than the present day Kiel Bay values (WINN et ai, 1988) and by over 4%0 compared with the results from 12 m water depth in the Havstensfjord (Fig, 6), This offset is caused not only by salinity and but also by temperature differences to the modern environments due to the shallowness of the former depositional environment.

The low faunal diversity, the absence of high marine foraminifera species, and the almost exclusive, but abundant occurrence ofA. beccarii in Unit D

(WINN 19 Kiel Bay Byth Lake), at ted elon 1975; W Baltic w, carbon ( environn thonous

UndE at salinit toleranc.

differenc total 1)18(

to a sun for

turtr«

The ~ cal. a B.

sedimen short pe to have I diversity Skaqerrs span les bioturba In cc successi The' present into con, ties in U The inflc continuit benthic I te structi

The to thOSE 12865/1 series 0

Boknis I modern

A.beccarii

S180_meas.-.6.(1%0) 10m (average)

\1 10 m

8180_exp'd (de) -e- 12m

--{>-- 20m

-a-- 30m 3~-c--c---,---,---,---,---,---,---,----,---,---,---,--c--,---,---,

2

K.WINNet al.

Havstensfjord, E. Skagerrak, Uddevalla, sw Sweden

-3 -4

8,-' cc

'"

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246

(11)

i'd(de)

~s,"!:J.(1%o) n (average)

-den.

becceni Kiel Bay

; 0 and E ict similar altic (KoIY m reqres- 9,000 to lIlic hinge 1I levels in sediment Ihe water d 9,400 a

; of cores le present d with the s offset is

.os

to the ipositiona:

a

species,

; in Unit D

_ , m _ _ ,_ _ , _ _",~_P_ale('h)ldrographyof the Great Be!~D-"nmar~:_,__, ~47 (WINN 1974) indicate that the salinity of the water column. was less than in the Kiel Bay today (with an average of 20.3 psu, RUMOHR 1979).

By the time of Unit D,the Baltic Sea was a large freshwater lake (Ancylus Lake), and the present-day Kiel and Mecklenburg Bays showed interconnec- ted elongated bodies of freshwater occupying the deep channels (KOlP 1975; WINN & AVERDIECK 1984). The only freshwater outlet of the then Western Baltic was through the Great Belt. The 8' 3C measured on the total organic carbon(ERLENKEUSERet al. 1975) also indicate the prevalence of a non-marine environment, i.e. organic detritus from lacustrine production or an alloch- thonous carbon input from terrestrial sources.

Under controlled conditions in the laboratory,A beccar!!could reproduce at salinities as low as 13%0 (BRADsHAw 1957). Adopting this lower salinity tolerance level, 13%0, for the Great Belt waters during Unit D, the salinity difference (-7%0) from today's average accounts for about -1.8%0 of the total 8' 80 -effect (-3%0). The remaining amount, -1.2%0, could be attributed to a summer temperature about 5°C higher than at present (cf. discussion for further evaluation).

The stable isotopic ratios became much heavier in Unit E at around 9100 cal. a B.P. (ERlENKEUSERet al. 1975). From the 14C-datings and the resulting sedimentation rates in core 12519, these changes took place within a very short period of less than 15 years duration. This unit was earlier interpreted to have been deposited under full marine conditions due to the higher faunal diversity with foraminiferal species found today only in the North Sea and the Skagerrak. A drastic and abrupt onset of higher salinity conditions in a time span less than 15 years can be postulated when the mixing effects through bioturbation are taken into account.

In core 12523 (not 14C-dated) this event is spread over 60 cm of the succession with indications of a regressive event during the transition (Fig. 4).

The sea level rose very rapidly during this time to about -10 m below present sea level. With the larger head of water now available, and taking into consideration that the outflowing waters were brackish, such high salini- ties in Unit E would only be possible when a thermohaline layering existed.

The inflow of higher saline waters at depth must have occurred with some continuity, advecting oxygen rich waters at a sufficient rate to allow the benthic biotopes to enhance, as is evidenced by the abundance of bioturba- te structures in this unit (WINN 1974).

The 8' 80 -levels of A beccar!! in early Unit E (ea. -3%0) are similar to those attained in the non-laminated sequence of the Kiel Bay cores 12865/12887, 12880/12886 and 12864, and also closely match a modern series of Ammon!a, collected 1974 (WEFER 1976) at 13 m water depth at Boknis Eck, western Kiel Bay (8' 80 z -2.8%0; WINN et al. 1988). Of the modern series 1993/94 from the Havstensfjord, 12 m station, the measured

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values (ca. -0.5%0, i.e. uncorrected for vital offset) are heavier by about 2.5%0 than inUnit E.

As unit E has been deposited during rapid sea level rise, water depth may have attained a level allowing to presume similar temperature regimes in the benthic realm for Unit D and the present time. Accordingly, from the 8' 80-difference (-0.2%0) in Ammonia, salinity should have been lower by about 1%0 than presently at Boknis Eck (13 psu, 10°C as effective figures for a likely shell grow1h in May, June 1974; W,NN et al. 1988). Compared to the 12m-station in the Havstensfjord (23 psu, 8°C for May, June 1993), the difference is -2.5%0 in 8' 80 or -12 psu in salinity. Accordingly, both modern references suggest salinities slightly below 15 psu for Unit E. Even if some freedom is allowed for as to the numerical values applied above for the physical parameters, the estimated salinity for the time of Unit E will not change basically.

This salinity level for Unit E is close to the lower tolerance level for Ammonia. Accordingly, the lower 8180 figures of Unit D cannot be taken to signal a still lower salinity. Instead, these values more likely are indicative of a higher temperature. The temperature equivalent of the isotope shift of about -3%0 between Unit E and D is

+

13°C, so that the calcification tempe- rature ofAmmonia is found as 23'C based on the modern T,S-pair of 10°C, 13 psu adopted for Unit E. The temperature of 23'e is not unlikely for late spring/early summer condifions in the shallow waters of the sill area in the Great Belt during the early Littorina transgression which fell into the warmth of the early Halocene.

Smaller corrections may become neccessary. One uncertainty is the regression coefficient of 8' 80 vs. salinity. The contribution of isotopically light meltwaters from Scandinavia to the Ancylus Lake would still have played some role for Unit D and part of Unit E, thus increasing the steepness of the regression. So, even with temperature and 8' 80 being the same for the modern environment and Unit E, the palaeosalinity should be higher, if the freshwater source is given a lighter oxygen isotope composition than it has today. Also the ice cap effect on 8180 of the marine water would not have decayed completely and the marine source should be given a slightly different composition than today. These points will particularly bear on model salinities if other temperature scenarios are considered.

The carbon isotope ratios also exhibit a distinct shift towards the heavier fractions across the D/E- boundary. It is noteworthy that this change also commenced and ended synchronously with those of the oxygen isotopes.

These changes occurred very rapidly in contrast to those documented in the Skagerrak core GIK 15530-4 (ERLENKEUSER 1985). In the Great Belt area they are associated with the role of the fresh waters which becomes largely reduced by the marine ingression. Part of these fresh waters originate from

248 K. WINNet aJ.

the glacie show a Cl

a light ca limnic bic slowly ex:

of month, leased by bottom IT

mohalocli The ri showed tl surroundh 1987). Th Great Bel' have beeI

The st dextral An significan variety,

as

1960). He ted the fo

8

180

,

beginning condition.

After , increase i cal. a BP Measi summer.

the early 23°C, will Comp teristics ir spectively Belt into t

(13)

the glacial rnarls in the southern marginal zone of the last glaciation and show a comparatively high content of dissolved inorganic carbon and with it a light carbon isotope composition. This isotope signature shows up in the limnic biota and its detrital remnants (cf. WEFER et al. 1978). Additionally, slowly exchanged bottorn waters could rapidly accumulate, within a couple of months, significant quantities of isotopically light, rernineralized CO2 re- leased by degradation of organic rnatter. The intrusion of salty water at the bottorn may have enhanced this carbon-isotopic signal. Probably the ther- mohalocline formed for the first time around this period.

The relative sea level curve for the Western Baltic (W,NN et ai. 1986) showed that the sea level rose very rapidly, resulting in fast erosion of the surrounding land and vegetation in the Kiel Bay area (cf. Healy & Werner 1987). The sediments also showed higher organic carbon contents. In the Great Belt, an outflow..inflow system similar to the present day is indicatec to have been established during this period.

The stable isotope measurements carried out separately on sinistral and dextral Ammonias in all the investigated cores do not show any consistent or significant differences to support a lower growth temperature for the sinistral variety, as previously postulated from the coiling ratio (LONGINELLI &TONGIORGI 1960). However, the left coiled forms were far more abundant, and domina- ted the foraminiferal assemblages of Unit E(W,NN 1974).

Conclusions

1)18

0

and 1)13C of A. beccetii in the sediment cores clearly indicate the beginning of the Littorina Transgression with the onset of brackish water conditions (13%0) at around 9,400 cal. a B.P.

After a period of about 300 years without significant changes, a drastic increase in salinity with more marine conditions (-25%0+) occurred at 9,100 cal. a B.P.

Measurernents on modern A. beccetii indicated shell growth in early summer. The summer temperatures at the bottom of the shallow waters of the early phase of the Littorina Transgression (Unit D) were estimated at 23°C, with salinity being about 13 psu.

Comparable isotope signals in sediments having similar bedding charac- teristics indicate that the laminated and non-laminated Units D and E, re- spectively, are contemporaneous and regionally correlable from the Great Belt into the Kiel Bay.

bout epth mes

I the

I' by 3 for

I the

the fern )rne

the not for n to

e

of t of

ipe-

JOC, late the mth the ight yed the the the has ave htly idel vier ilso

ies,

the hey jely 'orn

Paleohydrography of the Great Bell, Denmark... 249

(14)

BRADSHAW, H.B. (1957): Laboratory analysis on the rate of growth of the foraminifer "Streblus beecarii(LINNE) var.tepida (CUSHMAN)". - J. Paleontol., 31:1138-1147.

CHRISTIANSEN, C., CONRADSEN, K., EMELYANOW, E.,TRIMONIS, E., HEINEMEIER, J. & RUD, N. (1993):

Hydrographic changes in the southern Kattegat (Scandinavia) during the early Halocens transgr.ession. - Boreas, 22:349-356.

CONRADSEN, K.&HI:iER~NIELSEN, S.(1995): Holocene paleoceanography and paleoenvironments of the Skager.rak-Kattegat, Scandinavia. - Paleoceancqr.. 10:801-813.

OIETRICH, G. (1950): Die natQrlichen Regionen van Nord- und 08t888 aut hydrographischer Grundlage. - Kieler. Meer.esforsch., 7:35-69.

ERLENKEUSER, H" METZNER, H. & WILLKOMM, H. (1975): University of Kiel Radiocarbon measure- ments VIII. - Radiocar.bon, 17:276-300.

ERLENKEUSER, H. (1979): Environmental effects on radiocarbon in coastal marinesediments. - in:

BERGER, R. & SUESS, HE (eds.), Radiocarbon Dating, Proc. 9th Int. Radiocarbon Conf., Los Angeles and La Jolla, 1976, p.216-237. Univ. Califomia Press, Berkeley 1979.

Er"ENKEuSER, H. (1985): Stable Isotopes in benthic for.aminifers of Skagerrak cor.e GIK 15530-4:

High r.esolution recor.d of the Younger Dr.yas and the Holocene. - Nor.sk Geol. Tidsskr., 65:49-57.

GUTENBERG, B. (1941): Changes in sea level, postglaeial uplift, and the mobility of the earth's Interior. - Bull. Geol. Soc. Am" 52:721-772.

HEALY, T.&WERNER, F.(198?): Sediment budget for a semi-enclosed sea in a near hornoqene- ous lithology: example of Kleler Bucht, Westem Baltic. - Senckenb. Marit., 19:32-70.

JAr1KE,J. (1961): Beobachtungen uber Kalkaufl6sung an Schalen von Mikrofossilien in Sedimen- ten der westlichen Ostsee. - Dt. Hydrogr. Zeitschr., 14:6-11.

KOLP, O. (1965): Palaoqeoqraphische Ergebnlsse der Kartierung des Meeresgrundes der westli- chen Ostsee zwischen Fehmarn und Arkona. - Beitr. z. Meeresk., 12-14:19~59.

KOLP, O. (1975):Die submarlnen Terrassen der sudlichen Ost- und Nordsee und Ihre Beziehung zum eustatischen Meeresanstieg. - Beitr. z. Meeresk.,35/4:1-48.

Km?, O. (1979): Eustatische und isostatische Veranderunqen des suo lichen Ostseeraumes im Holozan. - Peterm. Geogr. Mitt., 123:177-187.

LONGINEll.I, A.& TONGIORGI, E.(1960):Frequenza degli individui destrogiri in deversi popolazionl di Rota/ia beecarii. - Ball. Soc. Paleontol. ltal., 1 :5-16.

NOROBERG, K. (1991): Oceanography in the Kattegat und Skager.rak over. the past 8 000 years.

- Paleooceanogr., 6:461-484.

RUMOHR, H. (1979): Hydr.ographische Dauerr.egisfrier.ungen bei Boknls Eck (20 m), Westliche Ostsee von 1975-1978. - Rep. SFB 95, Wechselwirkung Meer-Meeresboden, Univ. Kiel, 42,59 S

SAURAMO, M. (1958): Die Geschichte der. Ostsee. - Ann. Acad. Scl. Fenn., A Ill, Geol.-Geogr., Helsinki, 522 S.

SCHNiTKER, D. (1974): Eeotypie variation inAmmonia becearii. - J. Foram. Res" 4/4:216-233.

SElBOLD, E. (1971): Nebenmeere io humiden und ariden Klimaberelch. - Geol. Rundsch., 60:73-105.

250

K. WINNetal.

References

SHACKLETOt,

bentr glad, C.N.f STUIVER, M calibr

WEFEf1, G.

wesll

WEFER, G., Tram W,NN, K. (' 26:6:

WINN, K. &

of tw WINN, K., '

West WINN, K.,

West

Manuscrit Revised: {

(15)

Manuscript submitted: 08.06.1998 Revised: 07.07.1998

SHACKLETON, N.J. (1974): Attainment of isotopic equilibrium between ocean water and the benthonic foramlnitera Genus Uvigerina: isotopic changes in the ocean durinq the last glacial. - In: LASEYRIE, L. (ed.), Variation du clirnat au cours du Pleistocene, Coli. lnt.

C.N.R.S.,219:203..209.

SWIVER, M. & REIMEli, P.J. (1993): Extended 14C-data base and revised calib. 3.0 14C age calibration programm. B-Decadel Data Set. - Radiocarbon, 35:215-230.

WEFFR, G. (1976): Umwelt, Produktion und Sedimentation benthischer Foramlniferen in der westlichen Ostsee. - Oi88" Math. Naturw. Fak., Christian-Albrechts-Universitat, Kiel, 103 S.

WEFER, G., WEBER, M. & ERLENKEUSER, H. (1978): Sandablagerungen wahrend der postglazialen Transgression in der Eckernfbrder Buchf (westl. Ostsee). - Senckenb. Marit., 10:39-61.

WINN, K. (1974).Present and postglacial sedimentation in the Great Belt Channel. .. Meynlana, 26:63-101.

W,NN, K. & AVERDIECK, F. -R. (1984).Post-Boreal development of the Western Baltic: Comparison of two local sediment basins. - Meyniana, 36:35-50.

WINN, K., AVERDIECK, F.-R., ERlENI<EUSER, H.& WEfiNER, F.(1986): Holocene sea level rise in the Western Baltic and the question of isostatic subsidence. - Meynlana, 38:61-80.

WINN, K., AVERDIECK, F.-R., ERlENKEUSEfi, H.& WERNER, F.(1988): Hydrography of the Kiel Bay, Western Baltic, during the Littorina Transgression. - Meyniana, 40:61-80.

uniniter"Streblus

Ruo, N. (1993):

e early Holocene

3.leoenvironments

lydrographlscher

carbon measure-

; sediments. - In:

.arbonCont., Los 1979.

lieGIK 15530-4:

skGeol. Tidsskr.,

Iity of the earth's

near homogene- I.,19:32-70.

silien in Sedimen-

undes der westn- -:19-59.

idIhre Beziehung

Jstseeraumes im

wersi popolazioni

oast 8 000 years.

20 m), Westliche ioden, Univ. Kiel,

Ill, GeoL-Geogr.,

,4/4:216-233.

idsch., 60:73-105.

Paleohydrography of the Great Belt, Denmark...

..~----_._._..~~-~_.~_..~_.._..~.._.._-_.~_._-_._~_.._.---._---.." 251

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