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Chemical Intra-Mediterranean Variation and Insecticidal Activity of Crithmum maritimum

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Chemical Intra-Mediterranean Variation and Insecticidal Activity of Crithmum maritimum

Maria Tsoukatou

a

, Christina Tsitsimpikou

b

, Constantinos Vagias

a

and Vassilios Roussis

a,

*

a School of Pharmacy, Department of Pharmacognosy, University of Athens, Panepistimioupolis Zografou, Athens 15771, Greece.

Fax: ++30 1 7274592. E-mail: Roussis@pharm.uoa.gr

b Doping Control Laboratory of Athens, Olympic Athletic Centre of Athens “Spiros Louis”, Kifissias 37, 15123, Maroussi, Greece

* Author of correspondence and reprint requests

Z. Naturforsch.56 c,211Ð215 (2001); received October 27/December 7, 2000 Crithmum maritimum, Terpenes, Dillapiole, Ant Repellency

The chemical composition of the volatile metabolites of Crithmum maritimumharvested from several geographic localities along the Mediterranean coasts was studied by GC and GC-MSD. The major oil constituents were found to be dillapiole,γ-terpinene, sabinene, limo- nene and β-phellandrene. The Western populations were richer in dillapiole, whereas the Southern collections were characterized by increased amounts of thymol methyl ether and γ-terpinene. The Italian chemical profiles differentiated by the significant contributions of carvacrol methyl ether and isoterpinolene. The essential oils were also investigated for their insecticidal activity and their repellency againstPheidole pallidula(Nylander) ants and found to possess significant activity.

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