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Magnetic Properties and Electronic Structures of Compounds from the Hf-Co Phase System

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Magnetic Properties and Electronic Structures of Compounds from the Hf-Co Phase System

Giorgio Concasa, Francesco Congiua, Jelena Beloˇsevi´c- ˇCavorb, and Boˇzidar Ceki´cb

aDipartimento di Fisica, Universit`a di Cagliari and CNISM, S. P. Monserrato-Sestu km 0.700, I-09042 Monserrato (Cagliari), Italy

bInstitute of Nuclear Sciences Vinca, P. O. Box 522, 11001 Belgrade, Serbia

Reprint requests to Prof. G. C.; Fax: +39070510171; E-mail: giorgio.concas@dsf.unica.it Z. Naturforsch.62a,452 – 456 (2007); received March 15, 2007

Magnetic measurements of molar susceptibilities as a function of temperature in the temperature range between 5 and 400 K were performed for the intermetallic compounds Hf2Co and HfCo2, using a SQUID magnetometer. The density of states at the Fermi level for Hf2Co was evaluated from the measured spin paramagnetic susceptibility. In addition, band structure calculations using the augmented plane waves plus local orbitals (APW+lo) method as implemented in the WIEN2k programme package for the two compounds were done. The obtained results were compared with the measured data.

Key words:Hf2Co; HfCo2; Augmented Plane Waves; Magnetic Susceptibility.

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