ENERGY
:: SUPERMATERIAL FOR SOLAR CELLS
:: MEMBRANES AGAINST GLOBAL WARMING :: SAVING ENERGY IN GREENHOUSES
The Magazine from Forschungszentrum Jülich 02|2010
RESEARCH
in Jülich
RESEARCH in Jülich
The Magazine from Forschungszentrum Jülich
A sample of glass sealant for high-temperature fuel cells is melted with an invisible laser beam.
Cover illustration: Solidified droplets of glass used to produce a sealant for solid oxide fuel cells (SOFCs).
Towards a Sustainable Energy Supply
Prof. Dr. Achim Bachem Chairman of the Board of Directors
Prof. Dr. Harald Bolt Member of the Board of Directors
I
n order to achieve the goal of a sustainable energy supply, we must rethink our current attitude and reach out across borders. Even though the International Energy Agency (IEA) does confirm that there has been some initial positive development with respect to energy generation, it also says that global energy consumption and carbon dioxide (CO2) emis
sions continue to be on the rise.
Innovative research is the basis for sustainable change in the generation and utilization of energy.
Forschungszentrum Jülich occupies a key position in this process and has made energy research one of the three priority areas in its portfolio. Attention is focused on finding concrete applications for an en
ergy supply that is not only environmentally friendly, but also reliable and affordable. At the same time, we are analysing the mechanisms and mainsprings of global warming and are developing energy
efficient largescale equipment, such as the leading European supercomputer QPACE.
An interdisciplinary dialogue on the key issues of energy supply is needed in order to develop new solutions and approaches beyond existing structures.
In the future, our activities in this field will therefore be integrated under one roof: the Institute of Energy and Climate Research (IEK). At this new institute, researchers of the former Institute of Energy Research (IEF) and those involved in atmosphere research at the former Institute of Chemistry and Dynamics of the Geosphere (ICG1 and ICG2) – a total of 600 employees – work together with the joint goal of arriving at the optimum solution for the future.
However, no institution will be able to solve the energy problem on its own. It is therefore necessary
to establish crossborder cooperations and tread a common path in energy research. We have been maintaining a wellestablished research partnership with Oak Ridge National Laboratory, the leading research centre in the USA, for decades. A unique cooperation model we launched in 2007 is the Jülich Aachen Research Alliance (JARA) with RWTH Aachen University located in our close vicinity. In the JARA
ENERGY section, we jointly conduct research into topics such as decentralized energy supply and storage, power plant technologies and issues of nuclear waste management.
In doing so, we do not limit ourselves to one tech
nology. Our researchers are working on various solu
tions for addressing the energy problem. In this maga
zine, we would like to show how innovative materials can make conventional power plant technologies more environmentally friendly and renewable ener
gies more economically efficient, and how these ma
terials may become the linchpin in the implementa
tion of future technologies such as nuclear fusion.
We will also show how novel ideas help save energy in greenhouses, how fuel cells can be used in trucks and how researchers develop concepts for storing waste from nuclear facilities.
We hope that it makes for interesting reading!
10
SAVING ENERGY IN GREENHOUSES
Tomatoes, peppers and other plants grow better if greenhouses are covered with a new glass–foil combination which allows a particularly large amount of natural light to pass through. It also saves a lot of energy in plant cultivation.
MEMbRANES AGAINST GlObAl wARMING
Jülich scientists are developing membranes that separate the green house gas carbon dioxide from the flue gases of coal power plants and thus help protect the climate.
32
10
:: SUPERMATERIAl FOR SOlAR CEllS
Jülich solar cells with a new, highly transparent window layer demonstrate in special tests that they make very effective use of the entire spectrum of the sun’s natural radiation.
16
IN THIS ISSUE
3 Editorial
:: SNAPSHOTS FROM JülICH
6 Research at a Glance
A kaleidoscope of pictures shows highlights of Jülich research – from the dawn of a new era in computing and the development of a detector for hazardous liquids to a new method for treating tinnitus.
:: FOCUS
9 Focus on Materials
10 Supermaterial for Solar Cells
New materials make photovoltaics – a technology that is both climatefriendly and environmentally compatible – more efficient and less costly.
13 On the Way Towards an International Fusion Reactor All around the world, Jülich researchers are called upon as experts when it comes to the material and design of the inner walls of fusion devices.
16 Membranes Against Global Warming
Coal power plants are to become more climatefriendly in the future with the help of membranes for the separation of gases.
18 Heat Protection for Turbines
New ceramic thermal barrier coatings for turbines improve the efficiency of power plants.
20 Beautiful and Mysterious Pictures from Jülich research
:: HIGHlIGHTS
22 The Energy Mix of the Future
Interview with Dr. Thom Mason, Director of Oak Ridge National Laboratory, USA
24 Using Diesel More Efficiently
Fuel cell systems may soon generate the electricity required for heating and air conditioning in trucks in an environmentally friendly way.
27 Simulation for Fusion
A supercomputer located at Jülich will transfer the knowl
edge acquired in existing fusion experiments to future larger facilities.
28 Driving Without Gasoline
Knowhow from fuel cell research helps develop high
performance batteries for electric cars.
30 Research for OneMillionYear Safety
Jülich scientists are looking into possible consequences of spent fuel elements coming into contact with water.
32 Saving Energy in Greenhouses
Glass–foil combination instead of singlepane glass helps horticulturists reduce energy consumption in greenhouses.
34 News from Energy and Environmental Research
Information on the “Energy Technologies 2050” study, the most energyefficient supercomputer in the world and highaltitude flights for the climate.
DAwN OF A NEw AREA IN COMPUTING
In the next ten years the computing power of supercomputers is to increase by a factor of 1,000 to one exaflop/s, that is to say one quintillion arithmetic operations per second. In this context, Forschungszentrum Jülich and IBM have launched an “Exascale Innovation Center”. Intel and ParTec have also signed an agree
ment with Forschungszentrum Jülich for a joint “ExaCluster Lab
oratory”. Kirk Skaugen, VicePresident of the Inter Data Center Group said, “Jülich plays a leading role in pursuing research in the area of supercomputing in Europe.”
ENERGY-EFFICIENT COMPUTER CHIPS
Scientists of the Jülich Aachen Research Alliance (JARA) have realized a new switching concept for a special chip. This concept paves the way for the generation after next of highperformance computers with low energy requirements. In the memristor chips used, the resistance can be programmed and subsequent
ly remains stored. With their new switching concept, the re
searchers have solved a fundamental problem of these compo
nents: their storage space was extremely limited so far because a superimposition of information between adjacent units during operation, referred to as crosstalk, could not be avoided.
This magazine focuses on energy and environmental research at Jülich.
However, this is not the only area in which Jülich scientists have scored great successes.
Research at a Glance
LINK TIP
www.fz-juelich.de/portal/kurznachrichten
EXCEllENT YOUNG SCIENTISTS
The research of Dr. Sebastian Feste and Dr. Dörte Gocke could hardly be more different: he is concerned with the fabrication and analysis of silicon components for nanoelectronics, while she conducts research into enzymes used for example for the production of starting materials for pharmaceuticals. However, the two young scientists at Jülich do have one thing in common:
their ideas have provided decisive stimuli for their respective areas of research. For this achievement, they were awarded the 2010 Excellence Prize of Forschungszentrum Jülich endowed with € 5,000 each.
SHAMPOOS AND SHEARING FORCES
Everyday products like shampoos and plastics are a mixture of complex ingredients such as polymers and other longchain molecules. If the pressure is too high or if the mixture is stirred too violently during production then the liquids frequently separate out again. The shearing forces at the container walls are of great significance here. Scientists from Jülich and Lyon have now been able to demonstrate experimentally for the first time how an invisible slip process leads to liquids that are more stable. Their findings can help to more accurately predict the flow behaviour of complex liquids in the future.
SIMUlATED ElEMENTARY MAGNETS
Magnetic atoms behave just like tiny compass needles, apart from the fact that their magnetization can only point in two directions, either to the top or to the bottom. With the help of the supercomputer JUGENE, Jülich scientists have now simulated the behaviour of indi
vidual cobalt atoms on a platinum surface and have determined how elementary bar magnets influence each other’s orientation. Detailed knowledge of this magnetic coupling can help develop atomic data stor
age technology. The result of the simulation was confirmed in experimental measurements carried out by researchers at the University of Hamburg.
HElP wITH TINNITUS
The T30CR neurostimulator has been approved by the EU for the treatment of chronic tinnitus. The small device developed by Adaptive Neuromodulation GmbH (ANM) is based on the results of research conducted at Forschungszentrum Jülich. The neuro
stimulator combats the disturbing ringing noises in the ear – a condition estimated to affect about three million Germans – using controlled acoustic stimuli. These stimuli disrupt the undesirable synchronization of neural networks in the brain, which is responsible for the nonstop ringing in the ear.
DETECTORS FOR HAZARDOUS lIQUIDS
Jülich physicists have presented the prototype of a new detector that reliably and rapidly distinguishes for example between liq
uid explosives and harmless substances. In the future, it could be used as a monitoring device at airports, and thus render the widespread ban on liquids and gels in hand luggage – including soft drinks, numerous cosmetics and medications – unneces
sary. The researchers are in contact with industrial companies, whose job it will be to develop the prototype into a marketable product.
SNAPSHOTS FROM JÜLICH
SCHWERPUNKT
:: FOCUS ON MATERIAlS
Robust new materials are the foundation of all progress in energy technologies. Research at Jülich provides some concrete examples of this: photovoltaic modules with microcrystalline silicon carbide as a window layer are particularly efficient when it comes to converting sunlight into electric current; hope is pinned on tungsten for the continuous operation of fusion reactors in the future; ceramics help conventional gas and coalfired power plants release less climate
damaging carbon dioxide. The search for a solution to mankind’s
energy problem has a number of exciting aspects.
LEDs in different colours cast light on the black surface of a solar cell. This set-up is designed to help find out which parts of the spectrum of sunlight are utilized particularly well by solar cells.
T
he increasing number of shiny black roofs all over the country shows that photovoltaics are a growth market. The conversion of sunlight into electric current is an inexhaustible source of clean energy as well as an industry that creates jobs. In Germany alone around 57,000 people worked in the photovoltaics industry in 2008. However, production costs for solar cells are still relatively high. These shiny power gener
ators would become more costefficient if they could be successfully constructed from the thinnest possible layers. This saves costly material and reduces the amount of energy required for production.
Supermaterial for Solar Cells
Jülich researchers are developing new materials for solar cells which are expected to make this climatefriendly and environmentally compatible energy technology less costly and more efficient.
Thinfilm solar cells based on a silicon material in which the atomic components are not arranged in crystal lattices are already being produced. Using cells with a semiconductor material that is more structured could result in higher efficien
cies. Crystalline material is better suited for the sunfacing window side of the so
lar cell in particular. A team of scientists headed by Dr. Friedhelm Finger is devel
oping a material that is particularly prom
ising for this purpose. At the Jülich Insti
tute of Energy and Climate Research (IEK), solar energy researchers are pro
ducing microcrystalline silicon carbide, a material made up of many tiny crystals
FOCUS
that each consist of 50 % silicon atoms and 50 % carbon atoms.
TRANSPARENT AND STABLE
“It really is a supermaterial,” says Finger. Microcrystalline silicon carbide has many of the advantages that materials scientists involved in solar technology dream of: charge carriers are very mobile in the material, it is extremely stable and moreover, it is transparent. “Crystalline silicon carbide can therefore be used as an ideal window layer for thinfilm solar cells,” says Finger. The window layer is the side from which the sunlight hits a solar cell. At the same time, silicon car
bide also reduces light reflection. The re
sult of this “antireflection effect” and the high transparency is that light is utilized particularly well.
However, it is not easy to produce the
“supermaterial” in the desired quality.
Describing the background, Finger says that initial attempts were made as early as the 1980s. However, early experi
ments with silane and methane as source materials were unsuccessful because the researchers were unable to find the cor
rect ratio of silicon and carbon. Only if the two elements combine with each oth
er in a 1:1 ratio will transparent crystals with a high conductivity form. Tempera
tures significantly above 1,000 °C are also required for production. Conventional substrate materials such as glass plates cannot withstand such conditions. In ad
dition, hightemperature techniques con
sume a lot of energy as well as money and are therefore not suited for the low
cost mass production of solar cells.
In the meantime, however, a new method referred to as hotwire deposi
tion has been introduced at Jülich. The source material used for the technique is monomethyl silane, a gaseous compound consisting of one carbon and one silicon atom with three hydrogen atoms bound to each of them. Carbon and silicon are If an electrical conductor is connected to
the contacts of a solar cell, electrons flow from the negative pole to the posi
tive pole: an electric current is produced, just like in a battery. In order to make this possible, electrons and mobile positive charge carriers – atoms that have emit
ted an electron – must initially be pro
duced in the solar cell and then separat
ed from each other in such a way that they accumulate at the contacts. The en
ergy required for these processes comes from the particles of light captured by the solar cell.
Solar cells are based on certain mate
rials referred to as semiconductors. Semi
conductors such as silicon become elec
trically conductive when supplied with heat or light. By deliberately introducing impurities – scientists call this process
“doping” – the number of mobile charge carriers in the solar cell and therefore the cell’s current yield can be improved.
The schematic of a solar cell as cur
rently studied at Jülich is shown here:
two electrodes or contacts envelop a package made up of three different semi
conductor layers. The upper electrode is transparent so that particles of light can penetrate into the semiconductor layers.
Solar Cells – a Multi-layered Construction
The lower electrode can reflect particles of light that have overshot the target back into the semiconductor layers (re
flecting back contact). All the incident sunlight is therefore utilized in an optimal way. The solar cell is protected by a layer of glass. The semiconductor sandwich in
side the solar cell consists of an undoped ilayer in the centre that connects two differently doped layers with each other – the ndoped and pdoped layers. The
researchers introduce impurity atoms that have more electrons than the pure material into the ndoped layer (n for nega tive) and impurity atoms with fewer electrons than their neighbours into the pdoped layer (p for positive). This layer conducts positive charges. The combina
tion of the three semiconductor layers means that electrons and positive charge carriers are systematically separated from each other.
transparente Elektrode
n-dotiertes mikrokristallines Siliziumcarbid
p-dotiertes mikrokristallines Silizium reflektierender Rückkontakt i-Schicht
Glas
glass
transparent electrode n-doped
microcrystalline silicon carbide i-layer
p-doped microcrystalline silicon
reflecting back contact
light
+ -
One of the facilities used by Jülich researchers to produce the thin films for a solar cell.
therefore present in the desired ratio of 1:1 from the very beginning. If this gas is introduced into a chamber with a hot wire made of tungsten or tantalum, hydrogen is split off and the resulting silicon carbide is deposited on a substrate area at 300 °C.
In this way, highquality mi
crocrystalline films can be produced that are between 10 and 60 nanometres (millionths of a millimetre) thick. Solar cells with this type of window layer already have an efficiency of 9.6 %. “That is a fantastic value!” says Finger.
However, the researchers want to achieve even more. “The films we pro
duce with this method do have a high conductivity. However, for reasons we do not quite understand yet, the material primarily conducts free electrons, which means it is an ntype layer,” says Finger.
It is possible to produce solar cells from this material – but the light will have to come from the side of the ntype layer.
However, for the particularly effective tandem solar cells, like those developed in Jülich, ptype silicon carbide is re
quired. The Jülich researchers can manu
facture this by incorporating aluminium atoms into the material. This “doping”
produces positive charges in the silicon carbide (see box “Solar Cells – a Multi
Layered Construction” on p. 11). “For this process, we use trimethylaluminium, which is also used in the production of LEDs, for example,” says Finger. How
Inside this chamber, a hot wire glows while gaseous monomethylsilane is decomposing.
This produces films of silicon carbide that are particularly advantageous for solar cells.
-
Fraunhofer Institute for Surface Engi
neering and Thin Films in Braunschweig, Germany, which has broad experience in hot wire deposition. Using numerous methods available at Jülich, from electron microscopy to infrared and Raman spec
troscopy, the researchers analyse time and again how silicon carbide changes as a consequence of different interventions.
The aim of these studies is to make the supermaterial ready for application soon, so that the market for environmentally friendly solar energy can continue to grow in the future.
Wiebke Rögener ever, “contamination” with aluminium at
oms disrupts the crystallization process, the result being a less transparent mate
rial. Here, too, Jülich researchers have found a solution: if the pressure in the re
action chamber is increased, very trans
parent crystalline films will form once again. Finger says, “The technique works in principle, but there are a couple of things that must be optimized before it is ready for practical application.” For ex
ample, source gases that are not used up must be prevented from condensing dur
ing the manufacturing process.
In further developing the production processes, IEK is cooperating with the
FOCUS
On the way Towards an
International Fusion Reactor
Construction work is in progress in the south of France for the ITER international fusion reactor, which is planned to go into operation in 2019. Whether the project will be a success and thus fuel hopes of having a nearly inexhaustible and clean source of energy largely depends on the material used for its inner wall (“first wall”) and the way it is designed. In this field of research, Jülich scientists have special expertise which they contribute to nuclear fusion experiments all over the world and, in doing so, they extend this knowhow.
M
odern science banks on international exchange. However, there are only a few disciplines in which global cooperation is as strong as in fusion research. The scientific commu
nity, which is scattered all over the globe, has the ambitious joint goal of generating power according to the prin
ciple of the sun’s fire (see “Sun’s Fire on Earth”, p. 15) on a commercial scale from around 2050. If they succeed, the raw materials used as fuels would suffice to supply mankind with energy for a period of at least tens of thousands of years.
The Jülich plasma physicists at the In
stitute of Energy and Climate Research are among those driven by this vision.
One of them is Dr. Sebastijan Brezinsek.
He is an expert in what is called plasma–
wall interaction, i.e. the ways in which the fusion plasma, which has a tempera
ture of more than 100 million °C, and the first wall of a fusion reactor influence each other. However, he is only present at the Jülich fusion experiment TEXTOR, which is jointly operated with partners from Belgium and the Netherlands, for a few months each year. More often than not, he can be found in Culham. This UK This is what the international fusion
device ITER in Cadarache in the south of France will look like one day (above).
Top: Another virtual glimpse, this time into the vacuum vessel of the Joint European Torus (JET) in Culham, UK.
village, some 100 kilometres west of Lon
don, is the location of the Joint European Torus, or JET for short – the largest fusion device in the world and so far the most successful. Here, Brezinsek from Jülich is a “deputy task force leader”. He was ap
pointed by the EFDA (European Fusion Development Agreement), the organiza
tion which operates JET according to an agreement between the European Union and the European fusion research facili
ties.
While the plasma in the Jülich TEXTOR machine has a volume of seven cubic me
tres, JET contains a plasma of 100 cubic metres. “The amount of energy that can be obtained in a fusion device increases with the plasma volume,” says Sebastijan Brezinsek. In order for the device to gen
erate more energy than is required to produce the plasma, a minimum size is required, which even JET does not quite have. “However, JET allows us to test the overall concept envisaged for ITER and to develop it further,” says Brezinsek.
ITER – which means “the way” in Latin –
is a joint facility of Europe, the USA, Russia, China, India, Japan and South Korea. This “biggest scientific under
taking since the international space station”, as the former French President Jacques Chirac called it, is designed to deliver ten times the power it consumes for producing and stabilizing the plasma with a volume of 830 cubic metres, that is, a total output of 500 million watts, for more than eight minutes.
CONTROLLED PLASMA
Even though the hot plasma is con
tained by magnetic fields and thermally insulated, it is actually intended to touch the wall of the vacuum vessel in some places so that helium nuclei can be re
moved from the plasma. Similar to a large amount of ash in a fireplace, which will smother a fire, a byproduct referred to as “helium ash” can extinguish the plasma. Those parts of the wall that will be in contact with the plasma and must therefore be particularly resistant to heat are called the divertor.
According to its role as the direct predecessor of ITER, JET is currently be
ing retrofitted with a wall that, in terms of the materials and properties, corre
sponds to the one planned to be used in the decisive operational phase of ITER.
“While JET is being retrofitted, we will plan the experiments that will be carried out in the completely upgraded facility with its ITERlike wall from mid2011 in detail,” says Brezinsek. Ultimately, these experiments aim to clarify whether ITER can one day be operated in such a way that a wall made of the metals tungsten and beryllium can withstand the extremely high stresses over the course of many years. This is because in ITER’s divertor in particular, heat fluxes are to be expect
ed that are ten times greater than those present in an aircraft turbine or the fuel rods of a nuclear power plant. “If at all, such heat fluxes can only be found in the boosters of Ariane launch vehicles, but they only need to do their job for a maxi
mum of ten minutes until they are sepa
rated from the rocket,” says Dr. Jochen Linke, a Jülich specialist in fusion materi
als. As a consequence of instabilities in the plasma, heat pulses may even occur in ITER for fractions of a second that have substantially higher power densi
ties. In addition, the materials must also be resistant to the neutron radiation that occurs during the fusion process.
From 2011, the divertor area of the JET fusion device at the lower end of the photomontage will consist entirely of tungsten elements developed at Jülich.
FOCUS
the divertor which must withstand the highest heat fluxes consists of solid tung
sten and was codeveloped and tested at Forschungszentrum Jülich,” says Brezin
sek. He is one of the lucky few who can experience for themselves on site in Culham how this piece of Jülich proves itself in the sun’s fire.
Frank Frick MAKING WAY FOR TUNGSTEN
For a long time, fusion researchers throughout the world favoured graphite as a material for divertors, because it does not melt even at high temperatures, and because the carbon it is made of causes relatively little damage to the fu
sion fire if it finds its way into the plasma as an impurity. However, graphite is less suited for a fusion reactor in continuous operation because it would become en
riched with radioactive tritium, which constitutes an inacceptable safety prob
lem. Tungsten, in contrast, which is the element with the highest melting point (3,415 °C), has been discussed by fusion researchers for a long time, but was al
ways considered to be a poison for the plasma. The reason is that even in the hot plasma, some electrons will remain bound to the tungsten nucleus and cool the plasma by continuously absorbing en
ergy and emitting it in the form of light.
“However, in the meantime, we and other scientists have found out in many experi
ments how the plasma must be handled, how impurities can be removed and how the thermal load can be distributed more effectively, which is why tungsten has be
come the focus of research interest,”
says Brezinsek. For example, the team headed by Jochen Linke has examined the structure of tungsten produced in various way under the microscope and carried out numerous load tests, for ex
ample using specialized test devices in socalled “hot cells”. In these cells, mate
rials that are radioactive after having been bombarded with neutrons can be examined by remote handling.
Jülich knowhow has in particular contributed to the divertor that will be used in the completely upgraded JET. “That part of Nuclear fusion is expected to generate
the same amount of energy from two litres of water and 250 grams of rock as can be extracted from 1,000 litres of oil.
The water contains deuterium, also called
“heavy hydrogen”, and lithium rock, from which tritium is produced in the fusion reactor. Tritium is sometimes referred to as “superheavy hydrogen”.
Nuclear fusion quite literally fuses the deuterium and tritium nuclei, thus imitat
ing a process that also occurs in the sun.
However, not only does the centre of the sun have a temperature of around 15 mil
lion °C, it also has a pressure that is at least two billion times higher than that of the earth’s atmosphere. Since neither the pressure nor the huge volume of the sun can be imitated in a lab, a tempera
ture of 100 million °C is required in nu
clear fusion reactors to compensate for the difference. The fact that materials can withstand the hot fusion plasma at all is due to its extremely low density: the material is affected by the high energy of the impacting plasma particles but is only hit by relatively few of them.
A future fusion reactor will convert en
ergy released in the form of heat into electric current by means of turbines and generators, just as in power plants fired by coal, gas or nuclear fuel. In contrast to nuclear fission power, fusion does not produce any highlevel active waste that would have to be stored in a controver
sial final repository. Radioactive tritium is consumed in the reactor and helium, the final product of nuclear fusion, is not radioactive. In addition, no nuclear chain reaction can occur during nuclear fusion.
In the worst case, an accident in the reactor would simply cause the fusion reaction to stop.
Sun’s Fire on Earth
The beauty of tungsten: scanning electron micrographs show the metal after it has been exposed to various loads (left).
Below: Tungsten lamella for the JET divertor.
T
he earth’s atmosphere is heating up to a dangerous degree. The principal reason is greenhouse gases re
leased by man, in particular carbon diox
ide or CO2 for short, which forms during the combustion of coal, oil and natural gas. The International Energy Agency pre
dicts that the share of these fossil energy carriers in global energy consumption is even set to increase.
The solution seems simple enough: if CO2 was separated from the flue gases of power plants and then permanently stored underground, for example in ex
hausted oil fields, coal and natural gas could be used without putting a strain on the climate. There are in fact already coalfired power plants in which CO2 is scrubbed from the flue gas by means of alkaline solutions. However, the technol
ogy is very complex, requires space the size of a football pitch and reduces the efficiency of the power plant by more than ten percentage points.
THE THREE POWER PLANT CONCEPTS Scientists expect lower energy losses if the gas mixtures are separated using membranes. “In principle, there are three options,” says Dr. Wilhelm Meulenberg of the Jülich Institute of Energy and Climate Research (IEK). After combustion, it is possible, for example, to pass the flue gases through a membrane permeable for CO2 which, as it were, sifts out the greenhouse gas. It therefore performs the same job as the alkaline solution does today. Since the CO2 is only re
moved after combustion, this method is referred to as postcombustion capture.
Precombustion capture starts earlier on in the process. Coal is converted with pure oxygen, producing a gas rich in hy
drogen and carbon monoxide. The latter reacts with steam to produce carbon diox
ide, forming even more hydrogen. Mem
branes separate the CO2 from the hydro
gen so that, finally, the gas turbine can be supplied with almost pure hydrogen.
Membranes Against
Global warming
Coalfired power plants and climate protection seem to be irreconcilable opposites. Jülich scientists, however, are developing membranes designed to separate the greenhouse gas carbon dioxide from the flue gases of coal power plants. These membranes are intended to make the use of fossil fuels more climatefriendly in the future.
The third alternative is the oxyfuel technology. This involves a membrane that separates oxygen out of the air. It is then “diluted” with CO2 to avoid combus
tion temperatures rising too much. The coal is burnt with this gas mixture, the end product being highly concentrated carbon dioxide.
FOCUS
“Only the postcombustion method is already widely used today,” says Meulen
berg. This method of CO2 capture pro
vides the opportunity of retrofitting exist
ing power plants. Meulenberg says, “The other two methods offer greater CO2 savings potentials and efficiency losses can be kept at a lower level. However, these methods raise even more issues.”
The Helmholtz Alliance MEMBRAIN, coordinated by Prof. Detlev Stöver of For
schungszentrum Jülich, aims at address
ing these issues as quickly as possible.
MEMBRAIN also includes other research institutions, universities in Germany and abroad as well as industrial companies.
The development of climatefriendly coal power plants also plays an important role within the Jülich Aachen Research Alliance JARA.
In addition to the technical properties of the membranes, their entire life cycle must be analysed. This involves ques
tions concerning the disposal of compo
nents and the costs incurred including the transport and storage of carbon diox
ide. Systems Analysis and Technology Evaluation (STE) at Jülich also explores possible reactions of the public to these power plants with incorporated mem
branes.
The first step is, however, the produc
tion of suitable materials. Polymers – highly specialized plastics, so to speak – can be used for CO2 separation at temperatures of up to 200 °C. The sepa
ration of hydrogen or oxygen, however,
requires temperatures of 400 to 900 °C.
Ceramic membranes such as those pri
marily developed at the Jülich Institute of Energy and Climate Research can be used for these purposes.
HIGHPERFORMANCE CERAMICS An interesting membrane material the Jülich researchers are working on is called BSCF. It belongs to a group of minerals named perovskites after the Russian mineralogist Lev Alekseevich Perovski (1792–1856). BSCF is particu
larly suited for the separation of oxygen from air. The MEMBRAIN Alliance, for ex
ample, showcased a demonstrator with a BSCF membrane area of 0.2 m² at the Hanover Trade Fair. It has so far been able to produce around 300 kilograms of pure oxygen in 1 600 operating hours at a temperature of 800 to 850 °C and an oxygen flow of 2.5 litres per minute.
The equipment for testing such new materials is not available off the shelf.
“We build test stands in which the mem
branes can be fixed and then be tested under controlled conditions,” says engi
neer Dr. Michael Butzek of the Jülich Cen
tral Technology Division (ZAT). How does a membrane behave at several hundred degrees Celsius? How does the gas flow change at different pressures? How quickly does the material age? “We must continuously adapt the apparatus to the changing tasks,” says Butzek.
Material development, practical appli
cability, constraints with respect to gov
ernment policy and the energy economy – there are numerous factors that have an impact on whether techniques for car
bon dioxide separation succeed or fail.
“Nobody can say today which route will eventually be taken,” says Meulenberg.
“We are working on finding the best pos
sible basis for taking a decision.”
Wiebke Rögener
A scientist at Forschungszentrum Jülich measures how permeable a ceramic membrane is to oxygen (left).
Far left: The apparatus she uses in close-up.
This type of membrane sepa- rates oxygen out of the air at several hundred degrees Celsius. The specimen on the right is still unfinished.
The porous substrates gives the membrane mechanical stability.
T
he higher the temperature at which a power plant turbine is operated, the more electricity it generates from each cubic metre of natural gas.Thin thermal barrier coatings made of ceramics protect the metal turbine blades from the damaging effects of the hot fuel gas. “Partially yttriastabilized zirconia, or simply YSZ, as we call it, is currently the material of choice for this kind of applica
tion. This ceramics is very tough and withstands stresses exceptionally well,”
says Prof. Robert Vaßen of the Jülich In
stitute of Energy and Climate Research.
For him, there is currently no material in sight which could completely replace
YSZ, even though this material has its disadvantages, too. For example, the porous interior structure of the ceramics undergoes a phase transition at tempera
tures above 1,200 °C which reduces their porosity – experts call this process
“sintering”. As a consequence, the mate
rial loses its elasticity and starts to chip off.
The team headed by Vaßen is working on improving the successful YSZ thermal barrier coatings even further and on making them more resistant to heat.
The researchers’ strategy is to increase the share of fine pores in the layer, because air pores reflect heat radiation and increase insulation. The more pores, the better the thermal barrier. Porosity can be increased during the manufactur
ing process, in which ceramic powder is injected into the 3,000 °C flame of a plasma burner, where it is melted and accelerated. A computercontrolled robot arm moves the plasma burner along the surface of the blade and thus applies the ceramic thermal barrier coating.
Heat Protection for Turbines
Ceramics are used wherever it gets really hot inside a power plant turbine. Still, even the best of these materials cannot withstand temperatures above 1,200 °C for a very long time. Jülich researchers intend to change this in order to help turbines in power plants release less greenhouse gas and utilize the fuel more efficiently.
Prof. Robert Vaßen (bottom) with the powders he and his team use to produce thermal barrier coatings for turbines.
Next page left: A mixture of ceramic powder and water or ethanol is injected into the torch of the plasma burner and accelerated.
The result (centre) is a thin protective ceramic layer on the workpiece.
Right: The heat resistance of new ceramics is tested on a test stand.
The scientists are experimenting with the powder’s particle size in order to pro
duce a more porous ceramic material.
The finer the powder, the finer the pores – that is the theory. In practice, however, the powder must not be too finely ground. Otherwise, it may cake and will not flow evenly into the plasma flame.
Vaßen and his colleagues have found a way out of the dilemma: they mix very finely ground ceramic powder, which is not freeflowing on its own, with water or ethanol. This suspension is fed to a plas
ma burner through a newly developed at
omizing valve. This results in many tiny pores in a very stable ceramic layer. “The thermal barrier coatings fabricated in this manner have an excellent dispersive ca
pacity. Up to 95 % of the thermal radia
tion is reflected back,” says Vaßen.
In order to make YSZ ceramics even more resistant to mechanical loads, the scientists have transferred the produc
tion process into a vacuum. Under such conditions, there is no counterpressure for the hot gases of the plasma burner, which causes them to expand to an ex
treme extent. “If the particles are intro
duced into the expanded plasma, they do not only melt, they vaporize. In this way, we obtain a rodlike structure that con
forms to extreme mechanical require
ments,” says Vaßen.
MAKE OR BREAK
However, this is not enough for the re
searchers. Their goal is to achieve oper
FOCUS
ating temperatures for the gas turbines of 1,450 °C. The development of com
pletely new thermal barrier coatings from entirely novel ceramics is therefore one of the key research areas at the Institute of Energy and Climate Research. Once these ceramics have been produced, they will be applied to the YSZ like pro
tective armour. Prof. Tilman Beck tests whether the double layers developed by Vaßen and his colleagues deliver what they promise. At the Microstructure and Properties of Materials laboratories, which are also part of the Institute of En
ergy and Climate Research, he has two test stands at his disposal that are unique in the world. “What makes these furnaces so special is that we can simu
late rapid and extreme temperature fluc
tuations, which are also relevant in prac
tical applications, by activating each of the heatproducing halogen lamps indi
vidually,” says Beck about the advantages of the system. A hydraulic system grips the samples from the top and the bottom and exposes them to cyclic compressive and tensile loads. Ceramics in power plant turbines are exposed to centrifugal loads that correspond to several thou
sands of kilograms per square centi
metre. After all, the blades of a power plant turbine rotate at 3,000 revolutions per minute.
The researchers work like detectives in order to exactly understand how cracks and ruptures form. Using acoustic emission analysis, they can already hear
during the experiment whether a crack is propagating. An infrared camera is used afterwards. Following a flashlight im
pulse, it is used to observe how heat transmission subsides in the samples.
Parts of layers that have separated from their metal base material can be detect
ed with this method even if the diameter is no more than half a millimetre. “We can therefore exactly locate the position of the defect,” says Beck. This is exactly where he and his colleagues will then try and find the physical and chemical causes of the defect with an electron mi
croscope.
One the one hand, this precise fault analysis initially benefits the team head
ed by Vaßen in further improving the pro
duction processes for the ceramics. On the other hand, the results are also ap
plied in model calculations that can be used to obtain robust estimates on the stability of new coating systems relatively quickly. Such estimates are also of inter
est for industry. New thermal barrier systems that pass all the tests ultimately benefit energy companies and their customers as well as the climate. If a 240 MW gas turbine power plant can generate 2 % more electricity from the same amount of natural gas, it will produce this electricity more cheaply and release 24,000 less tonnes of carbon dioxide each year.
Brigitte StahlBusse
2
beautiful and Mysterious
If you hear the word “energy technology”, you will probably think of wind turbines, highvoltage pylons and power plant chimneys. These pictures from Jülich energy re
search show that technology also has other facets aesthetic and mysterious ones.
1
Solidified droplets of glass used to produce a sealant for solid oxide fuel cells (SOFCs).2
A look through a solar cell to the end of an optical wave guide.It is part of a new measuring system for determining how sensi
tive a solar cell is to the various spectral regions of sunlight.
3
A drop of glass taken out of the induction furnace at Jülich’s Central Technology Division, which has a temperature of 1,500 °C.1
3
4
Samples of materials for solid oxide fuel cells joined by means of a laser beam. They are tested for characteristics such as tightness and strength.
5
The wall of an electron beam welding chamber at the Jülich Central Technology Division. When in operation, it is used to permanently join extremely heatresistant materials for energy technology.6
A sample is melted with an invisible electron beam.FOCUS
5
8 6
7
Part of an experimental setup for determining the uniformity of light of a solar simulator. It produces light with a spectrum that is as close as possible to that of natural sunlight, which is important for testing solar cells.
8
A glimpse through a sight glass into a device for manufacturing solar cell layers. Inside, gaseous molecules are broken up withthe help of a plasma (purple). The resulting substances precipitate on a substrate.
9
This scanning electron micrograph shows the pool of molten highgrade steel that forms if the material is heated to its melting point within milliseconds. This would happen if the steel came into contact with the plasma in a fusion device.
4
7
9
Interview with Thom Mason
The Energy Mix of the Future
Energy is the basis for the high standard of living in the industrialized countries.
Dwindling fossil resources, global warming and environmental disasters such as the oil spill in the Gulf of Mexico show that we cannot continue as before. Dr. Thom Mason, the Director of Oak Ridge National Laboratory in the USA, comments on the shortterm and longterm options for quenching the world’s thirst for energy.
Question: what is work in the area of energy research focused on at Oak Ridge?
Mason: One focus of our work is on sci
ence and technology that make a clean energy future possible. We cover funda
mental research on the one hand as well as applicationoriented topics such as re
newables, grid and power plant technolo
gies and end use of energy on the other hand. The key to making substantial progress, however, is connecting basic science and applications, because even if we could accelerate the implementation of novel energy technologies, this would not suffice to reach the targets in terms of carbon dioxide emissions and energy Dr. Thom Mason
security in the near future. What is re
quired are some very fundamental break
throughs – and that is why we need the scientific community to engage.
Question: what are the effects in this respect of a cooperation between two institutions such as Oak Ridge National laboratory and Forschungszentrum Jülich?
Mason: The problems are very very diffi
cult and no one is going to solve them by themselves. It ultimately comes down to the scientists exchanging information, finding common interests and turning them into breakthroughs – for example, costeffective carbon dioxide separation
HIGHLIGHTS
or that, together, we can bring solar en
ergy to a point where it is very easy to integrate it in every single building.
Question: You just alluded to an impor- tant joint project: ceramic filters that will make zero-carbon conventional gas or coal power plants possible. Does that not leave us with the problem of where and how to store carbon dioxide?
Mason: Yes. Even if we figure out a cost
effective way of separating carbon diox
ide, for example using membranes, we must still find an answer to the question of suitable reservoirs. We really have to gain a better understanding of the bio
geochemistry. There is no point in storing the CO2 underground if it escapes after ten or twenty years. Considerable work remains to be done to find the right geological formation. We need to solve this question in parallel with the task of CO2 separation.
Question: what do you think of calls for investing all funding in renewable ener- gy sources only?
Mason: I don’t think much of them – only an energy mix will take us a step forward.
Take the example of Denmark, which already generates 20 % of its electrical power from wind energy. However, if the wind force decreases by just a metre per second, the loss of energy is equivalent to the capacity of an entire coalfired power plant. Now that may be manage
able if it is just 20 %, but the whole thing becomes very challenging beyond that level. I believe that smart grids will mean improvements, but that does not change the fact that we need to ensure base load capacity. In my opinion, we have two op
tions for this – at least until fusion power is available: conventional coal power plants and nuclear power. The oil spill in the Gulf of Mexico has reminded people that obviously all energy sources have risks. Whether you dam a river, drill for oil
offshore or cover large areas of land with wind turbines – every kind of energy sup
ply has an impact on the environment.
You always have to trade off these conse
quences against the benefits, which in
clude the contribution to our industrial competitiveness or to preserving our standard of living.
Question: In addition to solar and wind energy, many people also pin their hopes on the use of fuel cells. Do you share these hopes?
Mason: Cars will almost certainly be electrified in future. It is not yet clear though, in my opinion, whether those cars will be driven by batteries or fuel cells. Both technologies still have to over
come some hurdles – particularly in terms of costs and energy efficiency.
Since the question of which technology will win the race is still entirely open, you have to explore both of them equally.
Question: Fusion research is a prime example of large-scale international co- operation. Nevertheless, the general public is under the impression that progress is slow. Do we need fusion at all?
Mason: Fusion is the only potential ener
gy form that will not pose problems in terms of fuel supply – it is something we need to work on as an option for future generations. One way or the other, we are going to exhaust carbon resources.
Even with fission, we are dependent on the uranium resources available, even if the fissile material is recycled. Fusion will not solve our current problems, but we need it if we want our planet to remain inhabitable even for 10 billion people. I believe the investments will eventually pay off.
Brigitte StahlBusse
Oak Ridge National Laboratory (ORNL) with its more than 4,600 employees and Forschungszentrum Jülich have been cooperating for many years. The partners agreed upon an exchange of scientists as early as 1969. Close ties have existed between the two institutions ever since, for example in energy and materials research. These ties, which have grown in the course of decades, were cemented with binding contracts in 2008 and 2010.
Oak Ridge National laboratory (ORNl)
Protons from a high-energy accelerator hit a heavy-metal target in the SNS neutron source – an important research facility within the Oak Ridge National Laboratory.
A
mong US truck drivers, it quite common to leave the engine running during a break, above all to ensure that the heating or air condition
ing system is supplied with power. How
ever, when a vehicle is idled, the engine generates little usable energy per litre of diesel and produces a lot of fumes that harm the climate. “The market is hungry for a dieselpowered auxiliary power unit for trucks that has an energy yield of more than just five or ten per cent,” says
Jülich scientist Dr. Robert Steinberger
Wilckens. Solid oxide fuel cells (SOFCs) are just one of several types of fuel cells studied at the Jülich Institute of Energy and Climate Research, and are particu
larly suited as auxiliary power units.
Compared to most lowtemperature fuel cells, which run exclusively on pure hydrogen, SOFCs have the advantage that they can also use methane and carbon monoxide as a fuel or else as a
“fuel gas”. An upstream reformer unit can convert the diesel fuel that drives the truck into these three fuel gases.
SOON READY FOR THE MARKET SteinbergerWilckens, who coordi
nates Jülich’s activities with respect to SOFCs, estimates that this type of fuel cell will be ready for the market within less than four years. “By then, we must be able to make sure that the cells sur
vive the numerous switching processes between the on and the off state during their lifetime without any damage.” The high operating temperature of more than 700 °C is difficult to handle. It is neces
sary to make the ceramic material of the electrolyte permeable to oxygen ions (see figure on p. 25). The high tempera
ture itself is not the actual problem – SOFCs are already very reliable in con
tinuous operation – but the change in temperature when the cell is switched on or off. Changes in temperature cause the metal and the ceramic materials in the cell to contract or expand to a different extent.
The sealing material, which ensures that air and fuel gases do not mix, is under particular stress. “The problem would be solved quickly if we could use a metal gasket,” says Mihaly Pap, an engineer at the Jülich Central Technology Division.
Using Diesel more Efficiently
Jülich researchers have improved dieselpowered fuel cell systems to such an extent
that their application in trucks is now within reach. Auxiliary power units in trucks
could produce the power required by heating and air conditioning systems in a more
efficient and environmentally friendly manner than combustion engines.
HIGHLIGHTS
- -
-
- air
unused aircompo- nents anode electrolyte cathode
electric consumer
fuel
H2
O2 O2-
H2O
unused fuel water
This is how a fuel cell works, in this case the SOFC version powered by hydrogen or hydrocarbons: air is introduced at the positive pole, the cathode. The oxygen molecules (O2) in the air take up elec
trons from the cathode material. They move through the electrolyte as negative
ly charged ions to the anode, i.e. the negative pole, where they react with the hydrogen (H2) to form water (H2O). The surplus electrons are released in this process and utilized as electric current.
Efficient Converters of Chemical Energy
This melts the broken glass sealant material. When the material cools down and solidifies, the defective spot is com
pletely sealed again. The amazing thing is that the method is successful even though the laser has to permeate the metal material of the SOFC. Pap’s depart
ment has recently filed a patent for this technique, which PhD students helped to develop.
ENORMOUS PROGRESS
The “survival” of the sealing material would be easier if the operating tempera
ture of SOFCs was not quite as high. Dr.
Frank Tietz and his colleagues are there
fore working on improving the permeabil
ity of the electrolyte layer to oxygen ions at lower temperatures. “We have recently found out how to build cells that have about the same performance at 550 °C as cells 15 years ago at 950 °C,” says Tietz. The researchers achieved this enormous progress by reducing the elec
trolyte layer’s thickness to one to two thousandths of a millimetre. “We are the only ones in the world who can produce layers this thin for electrolytes with a size of ten by ten square centimetres,” says Tietz. The scientists scored a success by Production of the thin electrolyte layer
of a fuel cell by means of dip coating. A substrate is first immersed in a liquid, called the “sol”, and then removed at a constant rate.
“However, our sealing material must fulfil requirements that metal cannot – for ex
ample, it must be electrically insulating.”
In many years of work, Pap’s working group has succeeded in developing glass seals that can at least withstand the cooldown of SOFCs to a standby tem
perature of approximately 350 °C. This would be quite acceptable for a truck that is driven every day. If the SOFCs are switched off in the evening, the tempera
ture could be maintained at this level until the next morning. “Scientists all over the world are still having a tough time finding the ideal gasket that is not damaged by repeated complete cool
down,” says Pap.
This problem makes being able to repair a defective seal all the more important. So far, an expensive stack of several fuel cells connected in series has had to be discarded even if the gasket was only untight in one single place. How to reach untight places inside the stack without breaking the stack apart? The solution: “Similar to doctors, who focus radiation on a tumour in radiotherapy, without damaging the irradiated healthy tissue, we focus a laser beam on the defective spot,” says Pap.
Computer simulation of the flow velocities in the reformer that produces the hydrogen required by the HT-PEFC fuel cell from diesel. The velocity decreases from red (100 metres per second) to yellow and green and finally blue.
optimizing the socalled solgel technique for their purposes, which is also used, for example, for the antireflection coating of ophtalmic lenses. However, if SOFCs are intended to be operated at 650 °C in the future, the thin electrolyte layer would double the performance of the SOFCs at this temperature. The advantage of such a high operating temperature is that the cells can use methane without the up
stream reformer.
In order to achieve further improve
ments, the researchers are studying how the materials are affected during the operation of the fuel cells on the micro
scopic level. For this purpose, they are using the numerous tools for analysis available in their stateoftheart lab put into operation in November 2008. This does not only facilitate the progress of SOFCs. The researchers are also working on an alternative, the hightemperature polymer electrolyte fuel cell or HTPEFC for short. “The decisive advantage is that HTPEFCs only need to heat up for three minutes. In contrast, it takes SOFCs 20 to 30 minutes before they are ready to operate,” says Dr. Bernd Emonts, who coordinates research activities in the field of lowtemperature fuel cells at IEK.
The “HT” in the name of the HTPEFC can be attributed to the fact that it is a
“hotter” version of the older PEFC that operates at 90 °C. The operating tem
perature of HTPEFCs, in contrast, is about 160 to 180 °C. “Their advantage is
that the hydrogen they consume does not need to be highly purified, which takes us back to diesel or jet fuel,” says Emonts. The more modest requirements with respect to purity enables the hydro
gen to be produced from diesel in an upstream reformer.
REFORMER IMPROVED WITH HELP OF JUGENE
The key factor for the efficiency of such a reformer is that the diesel is mixed well with air and water. To this end, a group of researchers headed by Prof.
Ralf Peters has calculated the flows of gases and liquids injected in the mixing chamber of a reformer for a 5 kW HTPEFC with the Jülich supercomputer JUGENE. In addition, they simulated the
flows with coloured liquids in a glass model of the reformer. In this way, they were able to optimize the shape of the mixing chamber so that initially, 99.9999 % of the diesel could be utilized – and even after 1,000 operating hours, it is still as much as 99.7 %. Due to this success, Peters’ team had so much confidence in the supercomputer’s calculations that they had it design the mixing chamber of a larger reformer for a 50 kW fuel cell on its own, without comparison with real reformer models. Although the large reformer has not yet undergone initial tests, the researchers have no doubt that their “colleague”, the supercomputer, has once again done a firstclass job.
Axel Tillemans
This fuel cell stack (left) with dimensions of 25 x 35 x 50 cm consists of three modules with ten individual HT-PEFC fuel cells each (bottom, in the foreground).
HIGHLIGHTS
Simulation for Fusion
The Jülich Supercomputing Centre operates the first supercomputer exclusively for European fusion research known as HPCFF. Its computing power of about 100 teraflop/s – 100 trillion arithmetic opera
tions per second – is required to transfer the knowl
edge gained in today’s fusion experiments to future larger facilities.
W
hoever designs a fusion device (see “Sun’s Fire on Earth” on p. 15) must address a special problem. A look at the construction of new sports equipment, aircraft or bridges shows that these objects of very different sizes are all tested in wind tunnels, for example for air drag or stability. These wind tunnels therefore have very differ
ent sizes as well, although inside them, the wind often flows around models that have been built true to scale instead of real test objects. The engineers can then scale up the test results. “Unlike wind tunnel experiments, this is not possible for the important interface between the plasma and the first wall of a fusion device,” says Prof. Detlev Reiter of the Jülich Institute of Energy and Climate Research. He continues, “What we know about the physical processes at the edge of the plasma today can only be extra
polated to future larger fusion devices or even a fusion power plant with the aid of computer simulations.”
In fact, there are very many and very different physical processes close to the first wall of a fusion device that play a role and interact in extremely complicat
ed relationships. The calculations there
fore require a great deal of time and ef
fort. “Only with the current generation of supercomputers and in particular with the HPCFF is it possible to include all three dimensions of a fusion device in the simulation,” says Reiter, who heads the Computer Simulation for Fusion team at Jülich. Before this only the cross sec
tion of the device was used for the simu
lation, assuming that it was representa
tive of the entire reactor – which can be compared to the assumption that a slice of bologna sausage will always look the same irrespective of where you cut it.
However, the simulations on the HPCFF
including the third dimension have re
vealed that in areas for which experimen
tal data is difficult to obtain, the behav
iour of the plasma edge is not as symmetrical as previously expected.
Since this may also have conse
quences for the contact between plasma and wall in the international experimental reactor ITER, which will be put into opera
tion in 2019, the Jülich team was put in charge of the relevant calculations – thus beating the field in an international com
petition.
Frank Frick
2D simulation (left) and 3D simulation (above) of the plasma temperatures close to the first wall of a fusion device (top). Temperatures decrease from red to green to light blue.