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Nickel (II)-Methyl Complexes with Water-Soluble Ligands L [(salicylaldiminato-k2N,O)NiMe(L)] and Their Catalytic Properties in Disperse Aqueous Systems

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Supporting information:

Ni(II)-methyl complexes with water-soluble ligands L [(κ 2 -N,O-salicylaldiminato)NiMe(L)]

and their catalytic properties in disperse aqueous systems

Brigitte Korthals, Inigo Göttker-Schnetmann, Stefan Mecking*

300 350 400 450 500 550 600 650 0,0

0,5 1,0 1,5 2,0

absorption

wave length [nm]

0 min 20 min 40 min 60 min 80 min 100 min 120 min 140 min 160 min 180 min

Figure S1. UV-vis spectra of complex 2d in water (0.77 mg mL-1) recorded on a Varian Carey 50 at room temperature

Konstanzer Online-Publikations-System (KOPS) URL: http://www.ub.uni-konstanz.de/kops/volltexte/2008/6597/

URN: http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-65971

(2)

0 50 100 150 200 0

5 10 15

ethylene uptake [g(ethylene) h-1 ]

reaction time [min]

Figure S2. Ethylene consumption over time for polymerization in water at 20°C with 2d (lower trace: entry 8. Upper trace: entry 9).

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