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Phase Transition Properties of a Ferroelectric Superlattice with Surface Modification

Hong-Li Guoa, Xiao-Yu Kuanga,b, Xiong Yanga, and Rui-Peng Chaia

aInstitute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China

bInternational Centre for Materials Physics, Academia Sinica, Shenyang 110016, China Reprint requests to X.-Y. K.; E-mail: scu kxy@163.com

Z. Naturforsch.63a,351 – 358 (2008); received November 1, 2007

The phase diagrams of a ferroelectric superlattice with finite alternating layers are investigated by using the transverse Ising model within the mean-field approximation. The effects of surface modi- fication are introduced through a surface exchange interaction constant and a surface transverse field parameter. The results indicate that the features of the phase diagrams can be greatlymodified by changing the transverse Ising model parameters. In addition, the crossover features of the inside transverse field parameters from the ferroelectric dominant phase diagram to the paraelectric domi- nant phase diagram are determined for a finite alternating superlattice.

Key words:Ferroelectrics; Phase Transitions.

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