293
Design and Fabrication of an On-Line Consolidation Facility for
Thermoplastic Composites
CORD WERDERMANN AND KLAUS FRIEDRICH
Polymer
&Composites Group
Technische
Universität Hamburg-Harburg
MARK CIRINO AND R. BYRON PIPES
Center for Composite
MaterialsUniversity of
DelawareNewark,
DE 19716ABSTRACT: An
experimental
apparatus that utilizes continuous fiber reinforced ther-moplastics
to wind rings and short tubes has beendeveloped.
Termed an on-line consoli-dation
facility, preimpregnated
tow is consolidated while the ring isbeing
wound. Thethree most important parameters for the consolidation process are time, temperature, and pressure, and the
facility
isdesigned
to establish their optimum combination. Therefore,each component of the apparatus
provides
maximumflexibility
andvariability
in terms ofthese parameters. This article describes the basic concept of the process and then shows how the concept can be realized.
The
technique
forheating
theimpregnated
tow utilizes infrared radiation. However, ad- ditional heat sources are used toprovide optimum
temperature control at the nippoint.
Finally,
several types ofpreimpregnated
tow are used toproduce samples
that prove thefeasibility
of the process and establishacceptable
ranges on the parameters.1. INTRODUCTION
RECENTLY
MANY HIGH-PERFORMANCE advancedthermoplastics
have beendeveloped.
Their mechanical and thermalproperties
arecomparable
or evensuperior
to those of many thermosets. Inparticular, they
offer suchadvantages
asrecyclability, thermoformability, weldability,
and continuousprocessing by
avoid-ing
the timeconsuming curing stages.
Thesethermoplastics
have also been usedas matrix materials for continuous fiber-reinforced
composites.
Variouspreim- pregnated tapes
and tows arealready
available on the market and areexpected
tobe
produced
inlarge quantities
in the future.Currently only
a fewprocessing techniques
aredeveloped sufficiently
to beused in
large
scale industrialapplications.
In all these processes, the thermo-plastic
material is melted and then consolidated under pressure. Somefrequently
used methods include
friction, ultrasonic,
and resistancewelding.
These process- Journalof
THERMOPLASTIC COMPOSITEMATERIALS,
Vol. 2 -October 19890892-7057/89/04 0293-14 $4 50/0
© 1989 Technomic Publishing Co , Inc.
ing
methods can beregarded
asdiscontinuous,
because theplies
are stacked inone
step
and consolidated in thefollowing step.
Continuous processes use a hotshoe,
hot gas, infraredradiation,
or infrared laser radiation to heat thetape
ortow and consolidate it while the material is in motion.
Some studies have
investigated
infrared[1]
or laser[2]
energy to melt the ther-moplastic
matrix in a continuous process.However,
theprocessing
rates are stilllow
compared
with those obtainedduring
wetwinding,
e.g.dry
fiberspulled through
a thermoset resin bath. Because heat conduction normal to the fiber direction islow,
one of themajor problems
is how toquickly
melt the matrix of theincoming
tow withoutdegrading
the matrix on the surface. Thisproblem
canbe overcome
by subjecting
the material to alonger heating period
so that the heat-ing
power absorbedby
the surface can be reduced.The
objective
of thisstudy
is todevelop
anapparatus
for the on-line consoli- dation of continuous fiber-reinforcedthermoplastic
tows. Thefacility
will beused for the
following applications:
~
Experimental
verification of residual stress models fortape
or filament woundrings [3].
~ Evaluation of different heat sources for the on-line consolidation process.
~
Optimization
of theprocessing
parameters withrespect
to theproduct’s
per-formance.
2.
REQUIREMENTS
2.1
Properties
of Fiber-ReinforcedThermoplastics
The materials
processed
with the on-line consolidationfacility
can be any kind of fiber that ispreimpregnated
with athermoplastic
matrix material. Table 1 shows theproperties
of some standardcomposites
of this group. These materialsare
currently
available on the U.S. market[4,5,6].
2.2
Capabilities
of theRing Winding Apparatus
The winder must be able to use narrow tow, as well as wide
tape,
to windrings
Table 1.
and short tubes. The
rings
are tocomply
with the ASTM standard test method for theapparent
tensilestrength
ofring
or tubularplastics
and reinforcedplastics
[7].
This standardspecifies
the dimensions of thering
as follows:However,
it also has to bepossible
to windrings
with anadjustable
width ofup to Wr
= 1 in = 25.4 mm and a thickness of up to t, = 1 in = 25.4 mm. Thedesign
has to allow for an easy modification of some of itscomponents
to windrings
of up to two inches( =
50.8mm)
in width.The three most
important parameters during
thewinding
process aretempera-
ture, pressure, andspeed.
Allparameters
must bevariable,
since theapparatus
will be used to find theiroptimum
combination.The
temperatures
of thetape, mandrel,
andcompaction
roller must each be in-dependently
controlled. Thetemperature
of thetape
must reach thehighest
pro-cessing temperature
of the materials listed in Table 1. To evaluate different heatsources for the
melting
of thetape,
it is desirable to make themeasily
inter-changeable.
It is necessary to control thetemperature
of the mandrel and thecompaction
roller betweenTmm
= 0°C andTmax
= 150°C. Toverify
the modelon residual stresses in filament wound
rings
that has beendeveloped by
two of theauthors
[3],
itmight
become necessary to install insulationrings
on both sides ofthe
ring.
Therefore theapparatus
has toprovide enough
space to mount insulationrings
of up to one inch(=
25.4mm)
in width and thickness.The pressure is influenced
by
twocomponents:
~ The
tape’s tension,
which should beadjustable
up toFt
= 15 lbs = 67 N.~ The
compaction
pressure, which should be controllable up to a pressure ofP,
= 200pounds
per linear inch = 35.000 N m-’ .The
winding speed
has to beadjustable
up to at least v, = 100 ft min~~ = 0.508 m s-1.3. DESIGN OF THE ON-LINE CONSOLIDATION FACILITY 3.1 The Basic
Principle
The
concept
on which theapparatus’ design
is based can be viewed inFigure
1. The raw
material, i.e.,
thepreimpregnated
tow, is stored on aspool
heldby
thetensioner. From the tensioner the
tape
runsthrough
apreheater,
where it is heated to atemperature
close to theprocessing temperature
of itsthermoplastic
matrix material. After
leaving
thepreheater,
thetape
is wound on the mandrel.At the same
time,
thenip-point
heaterapplies
additional heat to thetape
and to the surface of thepreceding layer.
Thetemperature
must be sufficient to melt thethermoplastic
material so that thelayers
oftape
sticktogether.
Thecompaction
roller
applies
pressure on thenip-point
toimprove
thebonding
between theFigure 1. Schematic illustration of major components of the on-hne consolidation facility.
layers.
The mandrel as well as thecompaction
roller can be heated and cooled in order to influence thetemperature history during
thewinding
process.3.2 Fixed Mandrel vs. Fixed
Nip-Point
There are
basically
twoconcepts concerning
the kinematics of thewinding
process:
1. The first
concept [2]
uses a fixedcompaction
roller so that theposition
of thenip-point
does notchange.
This means that the mandrel has togradually
in-crease its distance from the
compaction
roller as thering gains
thickness. At the sametime,
the mandrel movesparallel
to its axis of rotation.2. The other
concept
is to rotate the mandrel around a fixed axis and move thecompaction
roller away from it as thering
builds up.Simultaneously
the pay-out eye moves
parallel
to the mandrel’s axis of rotation.The
advantage
of the first solution is that thepay-out
head and thenip-point
heater do not have to be moved.
The
disadvantages
are thecomplex design
that is necessary togive
the mandrel threedegrees
offreedom,
and thenecessity
to usestrong bearings
and motors toaccelerate the rather
heavy
mandrel.The
strong points
of the secondwinding concept
are:~ The
design
is moreeconomical,
due to theseparation
ofdegrees
offreedom, i.e.,
the mandrel rotates and thecompaction
roller and thepay-out
eye movelinearly
onseparate
axes.~ The total
weight
that has to be accelerated and deceleratedduring
thewinding
process is
relatively
small.· If additional
heating
andcooling
devices have to be mounted around the mandrel at a laterdate,
theirdesign
will be muchsimpler.
On the other
hand,
in this case it is necessary to install a moresophisticated
tow
guiding
system, to make sure that thetape
runsthrough
thepreheater properly.
Inaddition,
it is rather difficult todesign
a fixture that makes thenip- point
heater follow the movements of thenip-point.
Comparing
the pros and cons of the twosolutions,
it was decided that the secondconcept
would be much easier toincorporate
and did not have anymajor
weakness.
3.3 Horizontal vs. Vertical Axis of Rotation
Having
decided to rotate the mandrel around a fixedaxis,
the choice remained whether to rotate it around a vertical or horizontal axis. UnlikeBeyeler
et al.[2],
it was decided to choose a horizontal axis for thefollowing
reasons:~ It is much easier to remove the mandrel from the shaft to
strip
off thering.
~ There is no axial force in the mandrel drive shaft.
~ The
pay-out
head which movesparallel
to the mandrel axis does not have to be acceleratedagainst gravity.
3A Selection of the Tensioner
The tensioner has the task of
keeping
the tension in thetape
at a constant level while thetape
is unwound from thespool.
All tensioners have threecomponents
in common: a shaft to hold thespool;
alocking system
to hold thespool
on theshaft;
and a brake or clutch to control thetorque
in the shaft.Depending
on theirtorque controls,
thetensioning systems
that are available on the market can be divided into threecategories:
1. The
simplest
form of a tensioner has a control for the brake orclutch,
thatkeeps
thetorque
at a constant level.2. Mechanical tensioners have a brake that is controlled
through
a feedbackdevice and a
sensing
unit. These are located next to thespool.
Thesensing
unit can be a
rotary
dancer orfestoon, preloaded
with aspring
or apneumatic cylinder.
3.
Closed-loop
electronic tensioners have a tension sensor between tensioner andnip-point.
In additionthey
feature amicrocomputer
toadjust
thetorque
of a bi-directional servo motoraccording
to thereading
of the sensor. The servomotor works as a
brake,
but it can also rewind the tape if it has too much slack.Systems
of the firstcategory
are ratherinexpensive,
butthey
have the disadvan-tage
of notaccounting
for thedecreasing
diameter of thespool.
As aresult,
the tension in thetape
increases with time.The second kind of
system
offers asimple
buteasily adjustable closed-loop
ten-sion control. The cost is moderate and
depends
on the tension range and the ac- curacy of thesensing
unit.Systems
of the thirdcategory
areprobably
the most accuratetensioners,
because thesensing
unit can be locatedright
before thetape
reaches thenip-point
and thus
compensate
for the friction in thetape guiding system.
The disadvan-tages
of thissystem configuration
are cost and that the sensor wouldrepresent
a heat sink for thepreheated tape.
For the on-line consolidation
facility designed here,
a tensioner of the secondcategory
wasselected,
because it offered agood compromise
betweenperfor-
mance and
price.
It features arotary
festoon andprovides
two different tension ranges(1.5
lbs = 6.7 N to 5 lbs = 22.2 N and 5 lbs = 22.2 N to 15 lbs = 66.7N) depending
on thethreading path
of thetape through
its rollers. The tension is variablethrough
the use of aNitrogen pressurized cylinder.
The pressureregula-
tor and gauge can be mounted up to 10 feet = 3 m away from the tensioner in a control rack to allow easy control over the tension
during
the process.3.5 Selection of the Preheater
Basic
computations using
the laws ofthermodynamics
show that the tape hasto absorb a power of up to 3.74 KW per inch of
tape
width at the maximum wind-ing speed.
Thefollowing heating techniques
were considered for thepreheater.
Resistance
heating requires
an electric current to be sentthrough
the carbonfibers. This is
theoretically possible,
but it is verysophisticated
and does notwork for
glass
or aramid fibers.Hot rollers or
sliding
shoes could be induction or resistance heated. Sincethey
increase the tension in the
tape, they
canonly represent
agood
solution if the ten- sion sensor is located after thepreheater.
Ultrasonics can be
applied by pressing
avibrating
metal rodagainst
thetape,
but the friction between the rod and the
tape
wouldchange
the tension in thetape.
High frequency
waves can heat the materialby causing
the molecules in thethermoplastic
to oscillate.However,
this methodonly
works withthermoplastics containing polar
molecules. Inaddition,
these waves are difficult togenerate
andcan be hazardous to electronic
equipment
and humanbeings.
Laser
light
hasalready
been used to heatthermoplastic
tape[2],
but the maxi-mum
speeds
obtained areonly
about 0.05 ms-’,
becauseonly
a small area of thetape
isexposed
to the radiation.Infrared radiation is easy to
generate
and to control.However,
since it can be harmful to the eyes, a cover is necessary around theheating
elements.Hot gas has a poor
efficiency,
since notonly
thetape
but also the gas have to be heated.Furthermore,
the heat conduction coefficient between the gas and the material is low.Open
flamesprovide
ahigh density
of energy, butthey
are usu-ally
so hot thatthey
maydegrade
thepolymer.
For the reasons stated
above,
infrared radiation was selected for thepreheating.
The on-line consolidation
facility’s preheater
consists of two infrared heaters that have a totalwattage
of 10 kW at 600 V.They
are mounted sothey
face each othersimultaneously heating
both sides of thetape.
Tosupply
the heaters with the re-quired voltage,
each heater needs two buck boosters to increase the housevoltage
from 197 V to 240 V and one transformer to reach 600 V.
The
heating
power of an infraredlamp
can be controlledby reducing
the volt-age of the power
supply.
This can be done in three different ways:~ The use of a serial resistor is the least
expensive solution,
but it has the disad-vantages
of lowefficiency
andhigh
heatoutput.
~ The installation of a variable transformer has the
advantage
ofhigh efficiency
at moderate cost.
~ The use of a silicon controlled rectifier offers
high efficiency
and theoption
ofa closed
loop temperature
controller. Itsdisadvantage
lies in the strong elec- tronic noise that can be harmful to anyadjacent computer.
The cost isslightly higher
than that of a variable transformer. Here the decision was made for the silicon control rectifiers because of controladvantages.
Each infrared heater has its ownindependent
powercontroller,
so that thetop
and the bottom surface of thetape
can be heated with different power levels. The control units are mounted on theprimary
side of the transformers since their cost is lower for lowvoltages. They
may also be mounted farenough
away fromcomputers
to avoiddamage.
3.6
Tape Guiding System
The
tape guiding
system ensures that thetape’s path through
thepreheater
doesnot
change
while thespool
diameter decreases and thering
on the mandrel builds up. It also controls thetape’s
movementparallel
to the mandrel’s axis of rotation.It consists of two ceramic
rings
mounted on either side of thepreheater.
The sizeof the
rings depends
on the width of thetape.
Therings
are heldby
stainless steelpay-out
eyes that can accommodaterings
of various sizes. Whenbeing compared
with metallic
rings,
ceramicrings
have thefollowing advantages:
· The coefficient of friction between the
tape
and thering
is reduced such that the deviation of tension is minimized.· The resistance to wear is
greater.
· The thermal
conductivity
isreduced,
which means that thering
does not repre- sent asignificant
heat sink.To reduce
friction,
it would have been better to use smallrollers,
but rollers wouldhelp
todissipate
thetape’s
thermal energy. Inaddition, they require
morespace,
causing
the distance from thepreheater
to thenip-point
to becomelonger.
This would result in an unwanted
cooling
of thetape.
3.7
Nip-Point
HeaterThe
techniques
that were considered for thenip-point heating
arebasically
thesame as those for the
preheater. However,
theefficiency
of theheating system
does not have to be amajor
concern, since the amount of energy that has to beapplied by
thenip-point
heater is much smaller than that of thepreheater.
Sinceone
application
of the on-line consolidationfacility
is the evaluation of different heat sources for thenip-point heater,
it was not necessary topurchase
an expen-sive and
sophisticated piece
ofequipment.
For the reasons statedabove,
ahot-gas
gun was chosen for the initial test runs.
3.8 Mandrel
The outside diameter of the mandrel is determined
by
the size of the ASTM standard testring [7].
The mandrel has to belong enough
to windrings
that areat least two inches
(=
50.8mm)
wide. Inaddition,
it has to extend one additional inch(=
25.4mm)
on both sides of thering
in order to hold insulationrings
thatcan reduce
boundary
effects.A
major
concern is theimplementation
of aheating
andcooling system.
A closedsystem
with a heated and cooled medium such as oil would create serioussealing problems,
since the mandrel has to be removed from theapparatus
after each run tostrip
off thering.
Therefore it isadvantageous
to use an opensystem
withheating
andcooling
media that do not contaminate the work area. The mostviable solution for this
concept
was the use of hot air forheating
andliquid
nitro-gen for
cooling.
Both media are blown into the hollow mandrel. To monitor thetemperature,
asliding
surfacethermocouple
senses thetemperature
on the out- side of the mandrel. Because the mandrel canget
veryhot,
it is made of stainless steel.It is also necessary to
provide
a means to attach thebeginning
of thetape
to theFigure 2. Mandrel.
Figure 3. Structure of the setup.
mandrel. This is made
possible by
a removable section bolted to the mandrelbody.
To attach thetape,
two bolts areloosened,
thetape
inserted in theslot,
and the boltstightened again.
Adrawing
of the mandrel can be viewed inFigure
2.3.9 Pictures of the
Facility
This section shows a sketch and some
pictures
of theapparatus.
The sketch inFigure
3 visualizes how thecomponents
of thefacility
arearranged
relative toeach other in the
laboratory. Figure
4gives
an overall view of the entire appara-tus. A
close-up
of thenip-point (Figure 5)
shows some details of thefacility
around the mandrel.
302
Figure (A: preheater, mandrel).
Figure 5. Close-up of the nip-point (A: nip-point heater, B: mandrel, C: compaction roller, D:
mandrel cooling-nozzle, E: compaction-roller cooling-nozzle, F: compaction roller hot-air gun).
4. PRELIMINARY TEST RESULTS
Table 2 shows the
protocol
sheet ofpreliminary
testsperformed
on the new on-line consolidation
facility.
Theproperties
of the materials used werepresented
inTable 1. Since a fast and
qualitative rating
wasdesired,
the consolidation was evaluatedby
the sound thering
made whendropped
on a hard surface.For the first five
rings,
tow of carbon fiberspreimpregnated
with anamorphous polyamide
matrix(J2-polymer, DuPont, USA)
was used. While the firstring
wasbeing wound, heavy
smoke wasrising
from thepreheater.
Thering
showed apoor consolidation. It seemed that the
heating
power was toohigh
so that thematrix material was
vaporized.
For
safety
reasons, the motor chosen to drive the mandrel hassubstantially higher performance
curve than necessary to fulfill therequirements
listed in sec-tion 2.
Therefore,
it ispossible
to wind atspeeds
that arehigher
thaninitially
re-quired (up
to v, = 200 ft min-’ = 1.016 ms-’).
Whenwinding
the second and thirdring,
thewinding speed
wasdrastically
increased and theheating
power reduced. Inaddition,
therings
have morelayers
than theirpredecessors.
When
winding
the fifthring,
the motion controller put down thelayers
with a 50%overlap.
Inaddition,
thewinding speed
was increased. The result was aring
that has better surface
quality
and much better consolidation than the first fourrings.
Next, glass
fiberspreimpregnated
with 2GT were used. The tow is thicker than the J2 usedpreviously. Rings
six and seven were also wound with a 50 %overlap
of the
layers.
While therings wound,
very little smoke wasrising
from the pre- heater.By grinding
thering edges,
consolidation was noticed to beimproved
because of lack of voids.
Comparing
the tworings,
one can assume that ahigher
tension and a
higher compaction
force have apositive
influence on the consolida- tion.Figure
6 shows apicture
of these tworings.
For
rings eight through eleven,
Kevlarpreimpregnated
with J2 was used.Although
theheating
power was increased and thewinding speed reduced,
thei resin did not become hot
enough
to melt and consolidate. The reason for this could have been theabsorption
coefficient of thetape.
Unlike theglass/2GT tape,
the Kevlar based tow does not have carbonparticles
in the resin.The twelfth and the thirteenth
rings
were used tooptimize
thesetting
of thepreheater. Using
thepreheater
as theonly
heat source did not lead tosatisfactory
results. The tow was either burned or not hot
enough
to consolidate. A hot-nitrogen
gun was then added to heat thenip-point.
This made a considerable dif- ferenceimproving
consolidationsignificantly.
At the same time thecompaction
roller was not used. As a
result,
therings
were thicker but not as wide as the pre- vious ones.During
tests fifteen toeighteen
thenip-point
heater remained in itsposition
while thewinding speed
as well as thepreheater
power were reduced.The
eighteenth ring
was the best one made to date.Up
to thispoint,
thetemperatures
of the mandrel and thecompaction
rollerwere not controlled
during
the process.Therefore,
thetemperatures
increased whilerings
werebeing
wound.Depending
on the variousprocessing
parameters, thetemperature
of the mandrel increased about 5°C and that of thecompaction
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Figure 6. Two rings made of glass/2G T.
roller about 10°C. On the test
protocol sheet,
this is indicatedby
an asterisk pre-ceding
the value for thetemperature.
5. SUGGESTIONS FOR FUTURE WORK
In its
present
state, theapparatus
iscapable
ofwinding rings
thatcomply
withthe
requirements
listed in section 2. Future use of thefacility
will show which additions will be necessary in order toadapt
it to newapplications.
This sectiongives
a fewexamples
forpossible
modifications. Whetherthey
will be incor-porated
or notdepends
on the result of future test runs and the needs of the in- dividual user.In order to
compensate
for thevarying
thickness of theincoming tape,
it is desirable to haveclosed-loop temperature
control for thepreheater
as well as forthe
nip-point
heater. For thepreheater,
this can be achievedby measuring
thetape’s temperature
with athermocouple sliding
on thetape’s
surface. Atempera-
ture controller can use the
reading
of thethermocouple
to control the silicon con-trolled rectifiers of the
preheater
powersupply.
The silicon controlled rectifiers have a standardinput
module that can be addresseddirectly by
mosttemperature
controllers.For the
nip-point heater,
it is not easy to install atemperature
control because of thedifficulty
ofmeasuring
thetemperature
at thenip-point
itself.Investiga-
tions have been made
regarding
the use of apyrometer
for this purpose, but apyrometer
measures thetemperature
notonly
of theobject
it is aimed at, but also of theatmosphere
between the sensor and theobject. However,
itmight
bepossi-
ble to use a pyrometer that measures the radiation
only
within a limited section of the infraredspectrum.
Another
important parameter
for the consolidation is thetemperature
on the surface of thealready
woundtape.
The surface of both theincoming tape
and the lastlayer
have to be molten in order to obtain agood
consolidation. Therefore itmight
be necessary to heat thepreceding layer.
This can be doneby
the heatedmandrel,
thenip-point heater,
or an additional heat source.The consolidation also
depends
on the cool-down rate of thetape
after it haspassed
thenip-point.
Thecooling
can be influencedby
the cooledmandrel,
the cooledcompaction roller,
or an additional heat sink.In order to use the
apparatus
for the verification of a residual stress model[3],
it is necessary that the
boundary
conditions of the model be simulated as well aspossible.
Itmight
beadvantageous
to mount insulationrings
on either side of thering
to reduce the heat flux from thering
into theatmosphere.
Glass is onematerial that is very well suited for this
application
because it combines low con-ductivity, high
heatresistance,
and moderate cost.In its
present
state, the Kevlar/J2tape
cannot beprocessed
with theapparatus.
However,
this could be facilitatedby using
a resin that contains carbonparticles,
because carbon influences the
spectral absorption
coefficient of the material. Theglass/2GT tape
is anexample
of this kind of resincomposition.
ACKNOWLEDGEMENTS
One of us, C.
Werdermann, appreciates
thesupport
of hisstay
at theUniversity
of
Delaware, by
the Dean ofEngineering,
Dr. R. B.Pipes.
Theexperimental
ap-paratus
built for the Center ofComposite
Materials at theUniversity
of Delawarewas
sponsored by
theUniversity
Research InitiativeProgram
of the U.S.Army
Research Office. Additional
help
from the German Science Foundation(DFG
FR675-4-1)
forsetting
up a similarfacility
at the TechnicalUniversity
ofHamburg- Harburg
isgratefully acknowledged by
Prof. K. Friedrich.REFERENCES
1. Gruber, M. B. "Thermoplastic Tape Laydown and Consolidation," SME Technical Paper EM86-
0905 (1986).
2. Beyeler, E , W. Phillips and S. Gucen "Experimental Investigation of Laser-Assisted Thermo-
plastic Tape Consolidation," Journal of Thermoplastic Composite Materials, Vol 1 (January 1988)
3. Cirino, M. Ph.D. dissertation, University of Delaware (1989)
4. Gruber, M. B. Private communication, DuPont (1989).
5. APC-2 Data Sheet, Fiberite Corporation (1988).
6. Winkel, J. Private communication, Phillips Research Center (1989).
7. ASTM, Designation D 2290-76 "Standard Test Method for Apparent Tensile Strength of Ring or
Tubular Plastics and Reinforced Plastics by Split Disc Method," Annual Book of ASTM Stan-
dards, Section 15, Volume 15:(3) (1988).