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Flavonoids and Terpenoids from the Resinous Exudates of Madia Species (Asteraceae, Helenieae)

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Flavonoids and Terpenoids from the Resinous Exudates of Madia Species (Asteraceae, Helenieae)

Eckhard Wollenweber

a*

, Marion Dörr

a

, Marco Dörsam

a

,

Abu El-Hamed Hassan

b,d

, Ahmed A. Ahmed

c

, M. F. Hegazy

c

, and Klaus-Peter Zeller

d

a Institut für Botanik der Technischen Universität, Schnittspahnstrasse 3, D-64287 Darmstadt, Germany. Fax: 00 49-61 51/16 46 30. E-mail: Wollenweber@bio.tu-darmstadt.de

b Department of Chemistry, Aswan-Faculty of Science, South Valley University, Aswan, Egypt

c Department of Chemistry, Faculty of Science, El-Minia University, El-Minia 61519, Egypt

d Institut für Organische Chemie, Universität Tübingen, D-72076 Tübingen, Germany

* Author for correspondence and reprint requests

Z. Naturforsch.58 c, 153Ð160 (2003); received October 10/November 14, 2002

The resinous material accumulated on aerial parts of Madiaspecies is shown to consist mainly of diterpenes, containing a series of flavonoid aglycones. A6- and/or 8-O-substitution is characteristic for many of these flavonoids. Three known rare diterpenes were found and the structure elucidation of a diterpene with a new carbon skeleton, named madiaol, is re- ported.

Key words: Madia, Flavonoid Aglycones, Diterpenes

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