VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION

J. Gmehling U. Onken W. Arlt

VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION

Aliphatic Hydrocarbons c4-c6

Chemistry Data Series

Vol. I, Part 6a

Published by DECHEMA

Deutsche Gesellschaft fur Chemisches Apparatewesen

Editors: Dieter Behrens, Reiner Eckermann

,, '

Vapor-Liquid Equilibrium Data Collection

6a

Aliphatic Hydrocarbons

C4-Ce

Tables and diagrams of data for binary and multicomponent mixtures up to moderate pressures.

Constants of correlation equations for computer use.

J. Gmehling, U. Onken, W. Arlt

Lehrstuhl Technische Chemie 8 (Prof. Dr. U. Onken)

Universitat Dortmund

© 1980 DECHEMA Deutsche Gesellschaft fiir Chemisches Apparatewesen 6000 FrankfurtiMain, Federal Republic of Germany

ISBN 3-921 567-30-0

All rights reserved

No part of this work may be reproduced or used in any form or by any means - graphic, electronic, or mechanical, including photocopying, recording, or taping, or information storage and retrieval systems·- without written permission of the publishers.

Printed by Schon & Wetzel GmbH, Frankfurt/Main, F. R. Germany

·' '

6a

Aliphatic Hydrocarbons

C4-Cs

1 ,3-Butadiene Butane i-Butene 1-Butene Cyclohexane Cyclohexene Cyclopentadiene Cyclopentane 2,2-Dimethylbutane 2,3-Dimethylbutane Hexane

1-Hexene Isoprene

Systems with:

2-Methylbutane 2-Methyl-1-butene 2-Methyl-2-butene Methylcyclopentane 2-Methylpentane 3-Methylpentane 2-Methyl-1-pentene 4-Methyl-1-pentene Neopentane

trans-1 ,3-Pentadiene Pentane

1-Pentene Vinyl acetylene

VI

SUBJECTS OF VOLUME

^I

The table lists the parts of Volume

I

already publ'ished or being in preparation.

Subtitle Vol.

^I,

Part

Aqueous-Organic Systems 1 published

Supplement

1

1a in prep.

Organic Hydroxy Compounds

Alcohols 2a published

Alcohols and Phenols 2b published

Supplement 1 2c ,in prep.

Aldehydes, Ketones, Ethers 3/4 published

Esters and Carboxylic Acids

^{5 in}

prep.

Aliphati.c Hydrocarbons 6a published

6b published

Aromatic Hydrocarbons

^{7 in}

prep.

Halogen, Nitrogen, Sulfur and other Compounds

I

⁸

^{in prep.}

VII

AUTHORS' PREFACE

Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion of Part 5 has been postponed, because in correlating systems containing carboxylic acids we also intend to include vapor phase non-ideality for more than one associa­

ting component in a system; programming of this calculation procedure has not yet been finished.

From Part 5 onwards, parameters of activity coefficient equations are also given for "incomplete" x-y data (isothermal without P, resp. isobaric without T).

In these cases, equilibrium ratios y/x have been used in the objective function for parameter optimization. A further additional information in the tables from Part 5 onwards concerns incomplete isothermal x-y data; here the result of the consistency test by method 2 (area test of Redlich and Kister) is given.

We again express our thanks to the great number of colleagues who have sup­

ported our efforts by supplying VLE data from their laboratories. On this occasion we should like to repeat our plea to all workers in the field of vapor- liquid equilibrium to send us reprints of new experimental results. ^·

Special thanks are due to Dipi.-Phys. G. Schwichtenberg, head of the computer center of the University of Dortmund, and to his staff, especially to H. Forster and U. Liebegut, for their co-operation. We are also grateful to Dr. R. Ecker­

mann (DECHEMA, Frankfurt/M.) for his efforts in editing the data collection.

Finally, we wish to thank all members of our team who helped in the prepara­

tion of Part

6

of the VLE Data Collection; these are: Mrs. U. Arlt, Dipl.-lng. P.

Grenzheuser, Miss G. Hennig, W. Kirchhoff, Dipl.-lng. B. Kolbe, Mrs. S. Koort, Mrs. L. Kunzner, Dr. G. Nocon.

Dortmund, January 1980

Ulfert On ken Ji.irgen Gmehling Wolfgang Arlt

VIII

PREFACE OF EDITORS

Sub

j

ects of this series are the physical and thermodynamic property data of chemical compounds and mixtures essentially for the fluid state covering PVT data, heat capacity, enthalpy, and entropy data, phase equilibrium data, transport and interfacial tension data.

The main purpose is to prov·ide chemists and engineers with data for process design and development. For computer based calculations in process design appropriate correlation methods and accurate data must be used. These are only in some cases available in the open literature. For that reason the most urgent requirement regard!ing the publication of data is to offer classif

i

ed and critically evaluated data, thus giving an impression which of them are reliable or not. This will be the goal of the series.

DECHEMA gives the opportun:ity to authors especially from universities to publish not only their theoretical results, but also their measured or compiled data, most often a large amount, that would otherwise never have been published.

The work of Dr. Gmehling, Prof. Onken and Dipi.-Chem. Arlt on vapor-liquid equilib�ia which was supported by the Federal Ministry of Research and Tech­

nology and DECHEMA has been very fruitful; in particular, it led to an extension of the UNIFAC method, The authors have produced what is probably the largest collection of vapor-liquid equil.ibrium data that is today available with evalua­

tion programs and experimental data.

We present the evaluation of this material in several parts of the first volume of the series. We hope that this gives particularly the users an instrument that will allow them to solve their problems considerably more easily and quickly than before.

Frankfurt/Main, January 1980

Dieter Behrens Reiner Eckermann

Subjects of Volume I

CONTENTS Vol.

I,

Part 6a

IX

VI Authors' Preface . . . VII Preface of Editors ^{. . .} . . . . • . . . . . • . . . . VIII

Contents Volume I, Part 6a . . . IX Contents Volume I, Part 1 . . . XI Contents Volume I, Part 2a . . . XII Contents Volume I, Part 2b . . . XIII Contents Volume I, Parts 3+4 . . . XV

Guide to Tables ^{. . . . .} . • . • . ^. . . . . • • • . . . . XVII List of Symbols ... XXVII References ^{. . . . . . .} . . . . . . • . . . . XXIX

Data Tables

Binary Systems ... ^. Vinylacetylene ^{.... ..... ..... ..... ..... .... .... ..... ...•. ..} 1 ,3-Butadiene ^{...... ...•..... ..... ..... .... ...... .... ..... ..} 1-Butene ... ^. lsobutene

Butane ^{.......... .......... ..... ...... ......... .... ...... . .} Cyclopentadiene ... ^. Isoprene ... ^. trans-1 ,3-Pentadiene ^{..........•... ..... .... ..... ............} Cyclopentane ^{..... ..•.. ..... .... ....... .... ..... ... ...... ..} 2-Methyl-1-butene ... ^. 2-Methyl-2-butene ... ^. 1-Pentene ... ^. 2-Methylbutane ... ^. Neopentane

1 1 1 3 17 18 19 36 38 57 60 77 79 85 86 90

Pentane . . . . . . . . 100

Cyclohexene . . . 128

Cyclohexane . . . . . . . . . . . . . 139

1-Hexene . . . 340

Methylcyclopentane . . . . . . 361

2-Methyl-1-pentene . . . 376 4-Methyl-1-pentene

2,2-Dimethylbutane

378 381

X

2,3-Dimethylbutane ^. . . . 387 Hexane ^. . . . 398 2-Methylpentane ^. . . . 619 3-Methylpentane

Ternary Systems ... . ... . Cyclopentadiene

Isoprene ^{....... .. ..... ..... ... ....... .... .......... ..... . .} Cyclohexene ... ^. Cyclohexane ... ^. 1-Hexene ... . ... ^. Methylcyclopentane ... ^. Hexane

626

631 631 632 634 636 651 652 659

Appendix A: Pure Component Parameters ... . 667

Formula Index of Systems ... ^. Alphabetical Index of Systems ... ^.

673 681

1ST COf\PON£ NT

C4H 4

C4H6

C4H8

C4�8

673

Formula Index of Systems

R=RECOMMENDED VALUES

2ND COMPONENT

V INYLACETY LE N F

C6Hb BENZENE C8H1t P•XYLENE

1,3-BUTADIEN£.

CCL4 TETRACHLOROMlTHANE CH2CL2 DICHLOROM ETHANE CH3N02 NITROMETHANE CS 2 CARBON DIS ULFIDE C4H5CL 2-CHLOR0-1,3-BUTAOIENE C4H8 1-BUTENE

C4H18 BUTANE

C6H6 BENZENE

C8H8 S TYRENE

1-BUTENE

C4H1e B UT ANf.

I S OBUTENE

CSHS ISOPRENE

BUTANE

CHSN METHYLAMINE C2H5Cl E THYL CHLORIDE

C2H5D2N N·DEUTEROETHY LAI· IN E C2H7N ETHYLAMINE

C4F8 PERFLUOROCYCLOBUTANE C5H1? PENTANE

HEX ANE

3RO COMPONENT 4TH COHPONE�T

PAGE

6

8• 10 1t 11-13 14 15- 16

17

is

19-2f 22 23- 27

28 29

31- 35

= ====:===�=======�== ======c== ===�===============c================ ======== = == =========== ==================

'

CS� 6 CYCLOPENTADIENE

C5HS IS OPRENE 36

C5H11 2-�ET HYL-2-BUTENf 631

CSH 10 2-METHYL-2 -BUTlH 3 7

C51i8 ISOPRENE

CH3N(l2 NITROMETHANE 38

C2H3N A CETON ITR !lE 39-4e

C5H1t 2 -METHYL- 2-SUTENf 632-633

674

Formula Index of Systems

C%8

CSH 8

C5H1�

C5H1�

C5H1�

C5H1�

CSH12

C 2H 60S C3H7NO C5H8 C5H10 C5H1e C5H1t C 5H 12

C2H60S

CCl4 CHCl3 CS2

C2CL4 C3H8S C6H6 C6H 14 C 10H 18 C1eH18

CH3N02 C5H1t

CH3N02 C2H3N

ISOPRENE

DIM ET HVLSU lf OXIDE N,N-DIMETHYLFORMAHIDE TR-1,3-PENTAOI�NE 2-HETHY L-1 -BUTENE 2-HETHYL-2-BUTENE 3-METHY L-1-BUTENE 2-METHYLBUTANE

TR-1,3-PENTAOI�NE

OIMETHYLSUlfOXIOE

CYClOPENTANE

TETRACHLOROMETHANE CHLOROFORM CARBON DISULFIOE

TETRACHLOROETHYlENE 2-PROPANETHI O l BENZENE

2,3-DIMETHYLBUTANE CIS-DECAHYORONAPHTHALENE THA-DECAHYORONAPHTHAL ENE

2-HETHYL-1-BUTENE

NITROMETHANE 2-HETHYL-2-BUTENE

2-METHYL-2-BUTENE

NITROMETHANE ACE TON ITR ILE

41- 4 3 44 45 46- 47 48- 53 54- 55 56

57- 59

6e-61 62 63- 66

6�

67 68 69 -73

75

76

71 78

19 81- 82

C3H7NO N,N-DIMETHYLFOR�AMIDE 83

--- ---

C5H1 2 2-HETHY LBUTANE 84

1-P ENTENE

C2H 3N ACETONITR !LE 85

2-METHY LBUTANE

CS2 CARBON DISULFIOE 86-87

C2H 3N ACETONITRILE 88

C3H7NO N,N-DIMETH YLFDR�AMIOE 89

C5H1? NE OPE NTANE

C4H12SI TETRAMETHYLSILANE C5H12 PENTANE

C5H17. PENTANE

CH?.CL2 D I CHLOROMET HANE C2H3N ACETONITRILE C3H3N ACRYLONITRILE C3H8S 1-PROPANETHIOL C5H11BP PENTYL BROMIDE C6H6 BENZENE C6H12 C YC LOHEXANE

METHYL CY CLOPlNTANE C6H14 H EXAN E

C7H14 METHY LCY CL OHlXANE C7H16 J!EPTANE

C6HH CY CLOHEXEN E

C CL4 TETRA CHLOROMETHANE C2H4CL7. 1,2-D I C HLOROETHANE

C6H6 BENZENE ·

C6H12 CYCLOHEXANE

C6H12 CY CLOHEXANE

CCL4 TETR A CHLOROMETHANE

CHCLF2 CHLORODIFLUOROMETHANE CH3N02 N ITROMETHANE

CS2 CARBON DISULFIDE C2 HCL3 TRI CHLOROETHYLENE

C2HCL 5 PENTA CHLO�OETHANE C2H4BR2 1,2-DIBROMOETHANE C2H4CL 2 1,2-DI C HLOROETHANE

C 2H 5NO N _,.ET HYLFORMAI< I DE C3H3NS TH IAZOLE C4H4S THIOPHENE C4H9N PYRROLI DINE

C�H 5N PYRIDINE

675

Formula Index of Systems

9t- 94 95- 99

1U 1e1-H2

115 116-113

114-118 119

12t-121 122-123 124-125 126-127

128 129

C6H1Z CYC LOHEX ANE 634-635

C6H6 BENZENE

C6H6 BENZENl

13t-136 136 137-138

139-15t 15t

151-152 636 153-154 155 637-638

157 158-163

163 R 164-165 166 167 168-17f

17t 171-182

676

Formula Index of Systems

C6�12

C6H1?

C 5H 11 N

CM6

CY CLOHEXANE

PIPERIDINE

HEXAFLUOROBENZENE

1�3-185 185

186-191 1 91 R

=����---�=��=����:�: � ����:---���=��=

C6H5RR BROHOBENZENE 196-211

C6H5 CL CHLOROBENZEN(

C6H5N02 NITROBENZENE C6H6 BENZENE

C6H7N ANILINE

C6H11CL CHLOROCYCLOHEXANE C6H1? HETHYL C Y CLOPENTANE C6H13N CYCLOHEXYLA�INE

C6H13N HEXA�ETHYL ENEIHINE C6H 14 DIHETHY LBUTANE C 6H14 HEX AN E

C7HA TOLUENE

C7H9N HETHYLANILINE C7H14 HETHYLCY CLOHEXANE C7H 15N N-HETHY L CY CLOHEXYLAMINE

C7H16 HEPTANE

C7H16 TRIHElHYLBUTANE C8HH ETHYLBENZENE C8HH 0-XYLENE

M-XYLENE C8HH P-XYLENE C8H16 1-0CTENE C �H18 O CTA N E

C8H18 2,2,4-TRIHETHYLPENTANE

C12H?6 DODE CANE C 16H34 HEXADE CANE c ?eH42 EI COUNE

1-HEXENE

C CL4 TETRACHLOROMETHANE

C6H7N ANI LINE C6H14 HEXANE C7H8 TOLUENE

C7H16 HEPTANE

212 2f3 214-241

l4t-2 41 639

6 41-647 6 48 242-257

257 258-261 262 263

-

²⁶⁹

271-271 272 273-277

277 R

278-291 6 49-651 292-29 4 295 296-299

299 3U-316 3t6

3t7 H8-31t

3 1 1-3 12 . 313-314 315-318_

31 9

321-323 324-329 329

334-336 337-339

C6H1? 1-HEXENE

C 2CL � T ETRACHLOROETHYLENE C2HCL3 TRICHLOROETHY L E NE C2H2 CL4 1,1,2,2-TETRACHLOROET�ANE C2H3CL3 1,1,1-TRICHLOROfTHANE C2H3CL3 1,1,2-TRICHlOROETHANE C3�5 CL3 1,2,3-TRICHLOROPROPANE

C3H7BR PROPY l BROM I Of C4H11N BUTYLAMINE C4H11N D I ETH YlAM I NE C6H6 BEN lE NE C6H1 4 HHANE

C6H15N DIISDPROPYLAMINE C6H15N OIPROPYLAMINE C6H 15N HEX YL AMINE C6H15N TRIETHYLAMINE C7H8 TOLUENE

C6H12 HETHYLCYClOPENTANE

CCl4 TETRACHLOROHETHANE C3H8S 1-PROPANETHIO L

C6H6 BENZENE

C6H14 H E X AN E

C7H8 TOLUENE

C6H1? 2-METHYl-1-PENTENE

C 6 H6 BENZENE

C6H12 4-METHYL-1-PENTENE

C6H6 BENZENE

C6H11.. 2 ,2-DIMETHYLBUTANE

C CL4 T ETRACHLOROMETHANE C6H6 BENZENE

C6H14 HEXANE C16H34 HEX ADECANE

C6H11. 2 ,3-DIMETHYLBUTANE

CCL4 TEfRACHLOROHET�ANE

677

Formula Index of Systems

C6H14 HEXANE

C6H1 4 HfXANE

341

34l 343

344 345 34 6 651

347 348

349 35t 351-353

353

354 355

356 357 358-36t

361

363-368 368 R

652-658

369-374 375

376-377

37a-3ae

381 382-384 385 386

387

678

Formula Index of Systems

C6H11. 2,3-DIMETHYLBUTANE

CHCL3 CHLOROFORM

C6H6 BENZENE 391-393

C6H14 HEX AN E 394

C7H14 CYCLOHEPTANE 395

C8H 16 CYCLOOCTANE 396

C16H34 HEXADECANE 397

===============================::z::::az==:::u:::::::z::::z:::caaa:C:�::a::::a:z::::ca:cs:::::zazci::accca:aaa:::

CCL4

CD31 CD5N CHBR3 CHCL3

CH2D3N CH3D2N CH5N C2Cl4 C2D7N

C2HCL3 C2HD6N C2H2Cl4 C2H3Cl3 C2H3Cl3 C2H5D2N C2H51 C2H5N02

C2H6DN C 2H7N C2H7N C3H5CL3 C3H7N02

C3 H7N02 C3 H8S

C3H9N C3H9N

C4H11N C4H11N

HnANE

TETRA CHlOROMETHANE TRIDEUTEROIODIDE PERDEUTEROMETHYLAMINE TR IBROMOME THAN£

CHLOROFORM

TRIDEUTEROMETHYLAMINE N ,N-DEUTEROMETHYLAHINE METHYLAMINE

TETRACHLOROETHYLENE PERDEUTERODIMETHYLAMINE TRICHlOROETHYLENE HEXAD�UTERODIMETHYLAMINE 1,1,2,2-TETRACHlOROElHANE

1,1,1-TRICHLOROETHANE 1,1,2-TRICHlOROETHANE

N ,N-DEUT EROETHY lAII IN E ETHYl IODIDE

NITROETHANE

N-DEUTERODIMETHYLAHINE Dl� ETHYL AMINE ETHYLAMINE

1,2,3-TRICHlOROPROPANE 1-NITROPROPAN E 2-NITROPROPAN E 1-PROPANETHIOL PROPYlAMINE TRIMETHYLAMINE BUTYLAMINE DIETHYlAMINE

398-413 414-419 411-419 421-422

433-437 438-442 443-452 453 454-461 462-463 464-471

473 474 475-478 479-481 481-483 483 484-491 491-513 514-517 518 519 511 51 1 512-514

515-517 518 519

---�---

C6 F6 HEXAF LUOROBENZENE 521-52 1

679

Formula Index of Systems

================== ===========================================s========================================== =

C6 H14

C6H14

C6H1A

HEXANE

CM14 PERFLUOROHEXAH

C6H3 CL� 1,2, 4-T RICHLOROBENZENE C6H5CL CHLOROBENZENE

C6H5N02 NITROBENZENE C6H6 BENZENE

C6H7N ANILINE

C6H12 METHYLCYCLOPENTANE C6H14 2-MET HY LPE NTANE C6H14 3-HE THY LPENTA NE C6H15N DIISOPROPYL�HINE C6H15N DIPROPYLAM INE C6H15N HEXYLAMINE C 6H 15N TRIETHYLAMINE C7H8 TOLUENE

C7H14 METHYLCYCLOHEX ANE C7H16 HEPTANE

C8H1t P-X YLENE C8H18 OCT ANE C16H34 HEX ADECANE

2-HETHYLPE NT ANE

CCL4 TETRACHLOROMETHANE

C6H6 BENZENE

C7H8 TOLUENE C6H11 P-XYLENE

522-5l5 525

526-527 528-53f 659-661 531-533 534-'559 559

66 2-663 664-6 65 561-581

581 582 583 584

5.85 586-589

591 591-595 596-597 598-616 617-618 619-613 614-618

619

C2H5N02 NITROHHANE 621

---�---

C3H8S 1-PROPANETH I OL 6 21

C6H6 BENZENE 622-624

C16H34 HEXADECANE 625

3-METHY LPENTANE

CCL4 TETRA CHLOROMETHANE 626

C7H8 TOLUENE 627-629

C16H34 HEXADECANE 63e

681

Alphabetical Index of Systems

=============================================================================================== =· ·=======

1ST Cf•f!rO�� NT 2ND COMPON�NT 3PD COMPONE.N T

4TH CO�PONENT

PAGE

=========================================================================================== ==============

1 ,3-Pl TADJEtH

BUTA�l

1-BUTENE

CYCL�HXAN£

C4H6

BENZENE C 6 H 6

BUTANE C4H1e

1-BUTENE C4H8

CARBON DISULFIDE CSZ

14 11- 13

8- ,.

,.

---·---

�-CHLOR0-1,3-BUTADIENE C4H5CL Dl CHLOROMETHANE CH2Cl2 N ITRDMETHANE CH3N02

STTRENE C8H8

TETRACHLOROMETHANE CCL4

C4H1f

N -DEUTEROETHYLAMINE C2H502N

ETHYLAMINE C2H7N

ETHYL CHLORIDE C2H5Cl

HEXANE C6H 14

4

15-16

23- 27 28

22

31- 35

-------�---

METHYLAMINE C H5N 19- 2 1

PENTANE C5H1Z

---�---

PERFLUOROCYCLOBUTANE C4F8

C4H8

BUTANE C4H1t

C6H12

ANILINE C6H7N

BENZENE C6H6

BROMOBENZENE C6H58R CARBON OISUlfiDE CS2 CHLOROBENZENE C6H5Cl CHLOROCYCLOHEXANE C6H11Cl CHLOROOIFLUOROMETHANE CHCLF2 CYCLOHEX HAM I NE C6H13N 1,2-0IBROMOETHANE C2H4BR2

AN I LINE C6H7N

HEXANE C6H14

TOLUENE C7H8

29

17

242-257 257 214-241 241-241 R 639 64t-647 648 196-2e1 153-154 ,2t2

258-261 151-152 263-269 157

682

Alphabetical Index of Systems

:=================================================================================================a======

CYCLN·� XANl C6H12

1,2-DICHLOROETHANE C2H4CL2

DIMETHYL BUTANE C6H14

DODECANE C12H26

EICOSANE C2eH42

ETHYlBENlENE C8H11

HEPTANE C7H16

HEXADECANE C16HH

HEXAFLUOROBE NZENE C6F6

HEXAME THYLENEIMIN E C6H13N

HE X AN E C6H14

HETHYlANI LINE C7H9N HETHYLCYCLOHEXANE C7H14 N-HETHYLCYC L OHEXYLAHINE C7H15N

METHYLCYCLOPENTANE C6H12 N-METHYL FORMAHIDE C2H5NO

NITROBE NZENE C6H5N02 NITROHETHANE CH3N02

OCTANE CBH18

1-0CTENE C8H16

PENTACHLOROE THANE C 2H C l5

PERFLUOROCYCLOHEXANE C6F12 PIPE RIDINE C5 H11N

PYRIDINE C5H5N

PYRROLIDINE C 4 H9N

TETRACHLOROHETHANE CC L4

TH IAZOLE C3H3NS

THIOPHE NE C4H4S

TOLUE NE C7H8

TRICHLOROETHYlENE C2HCl3

TR I HE THYLBUTANE C7H 16 2,2,4-TRIHFTHYLPENTANE C8H18

M-XYLEN E C8H1f

0-XYlENE C8 H1e

C@H1f

BENZENE C6H6

HE PTAH C7Hf6

BENZENE C6H6

158-163 163 R Z72

H7-H9 3J8-31J

3U•H6

. 3J6 334-336 186-191 191 R

Z7J-271 273-277 277 292-294 295 296-299

299 26 2 164-465 2J3 636

32J-323 319 156 192-19 5 183•185 185 R 171-18 2

139•15e 15J

166 167 Z78-291 649-65f 155.

63 7-638 317 324-329

329 313-314 311-312 315-318

CYCL�IIEXEH

CYCLOPlNTADIFNE

CYCLflPlNTAIIE

2, 2-� tnETH Y LBUTA NE

2, 3-� 11 ETHllfUTANF

C6H1f

BENZENE C6H6

CYCLOHEXANE C6H12

1,2-DICHLOROETHAN£ C2H4CL2

TETRACHLOROMETHANl CCL4

C5H6

ISOPRENE C5H8

2-METHYL-2-BUTENE C5H1t

C5H1f

BENZENE C6H6

CARBON DISULFIDE csz

CHLOROFORM CHCL3

CI�-DECAHYDRONAPHTHALENE C1fH18

TRA-DECA HYDRONAPHTHALENE C1tH18 2,3-DIMETHYLBUTANE C6H14

2-PROPANETHIOL C3H8S TETRACHLOROETHYLENE C2Cl4 TETRACHLOROMETHANE CCL4

C6H1 4

BENHNE C6H6

HEXADECANE C1 6H34

HEXANE C6H14

TETRACHLOROMETHA�E CC L4

C6H14

BENZENE C6 H6

CHLOROFORM CHCL3

CYCLOHEPTANE C7H14 CYCLOOCTANE C8H16 HEXI\DECANE C1 6H34

HXAN E C6H14

TETRACHLOROMETHANE CCL4

C6H14

ANILINE C6H7N

683

Alphabetical Index of Systems

CYCLOHEXANE C6H1?

2-HETHYL-2-BUTENE C5H1f

13f-136 136 H7-138 129 634-6:55 128

36 631 H

6 9- 73 63- 66 66 62

75 76 74 68 67 6t- 6 1

382-384 386

385 381

391-393 388-Hf 39t 395 396 397 394 387

56t-S8f

684

Alphabetical Index of Systems

�===============================�=s=== ===================================================================

HEX A� l C6HH

B£NZENE C6H6

BUTY LA HI NE C4 H11N CHLOROBENZENE c 6H se L

CHLO ROfORM CH CL3

N-DEUTFRODI�ETHYLAHINE C2H60N N,N-OEUTEPOETHYLAMINE C2H5D2N

N,N-DEUTEROMETHYLAMINE CH3D2N DIETHYLAMINE C4H11 N DIISOPROPYLAMINE C6Hl5N OIMETHYLAM INE C2H7N DIPROPYLAMINE C6H15N ETHYL AMI NE C2H7N

£THYL I ODIDE C2H51

HEPTAN£ C7H16

HEXADE CANE C16H34

HEXADEUTERODIMETHYL-

AMINE C2HD6N

IIEXAF LUO ROBENZENE HEXYLAHINE METHYLAMINE METHYLCYCLOHEXANE

METHYLCY CLOPENTANE 2-METH YLPE NTANE 3-HETHYLPENTANE NITROBENZENE NITRO£THANE

1-NITROPROPANE 2 -N ITR OPROPAN E

O CTANE

PEROEUTERODIMETHYL­

AMINE

C6F6 C6H15N CH5N C7H14 C6H12 C6H14 C6H14 C6H5N0 2 C2H5N02

C3H7N02 C3H7N02 C8H18

C2 D7N PEROEUTERO�ETHYLAMINE CD5N PERF LUOROHEKANE C6F14

1-PROP ANETHIOL C3H8S PROPY�^{AMINE C3H9N}

1,1,2,Z-TETRA CHLOROETHANE C2HZ CL4 TETRA CHLOROETHYLENE C2CL4

TOLUENE C7H8

P- X YLENE C8H1t

BENZENE C6H6

534-559 559 R 662-663

664-665 518

659-661

423-432 432 R

475-478 438-442 519 584 491-513 585 514-517 479-481 598-616 614-618

464-471 52e-5l1 586-589 443-452 596-597 581

582 583 531-533

481-483 483 519 511 619-613

454-461 41t-419 522-525 525 511 512-514 472 45 3

685

Alphabetical Index of Systems

: :::::::::: :::;::::::::: :::::: :::::::::: :::::::::::::::::::::::::::::: :::::::::::::::::: �== ::::::.;: ::::::::::::::::::::::::::::::: :::::::::::::::::::::: Z :::::::::::::::::::: IC: :::::::::::::::::::::::: :::::::::::::=::::::::::::: ::::::::::::::::::z=:::=-z::::::;z::: ZE ::::::::::1:1:::

H�XA�E

TETRACHLOROMETHANl CCL4

TOLUENl C7H8

TRIBROHOMETHANE CHB R3 1,7,4-TRICHLOROBENZENE C6H3CL3 1,1,1-TRICHLOROETHANE C2HHL3 1,1,2-TkiCHLOROETHANE C2H3CL 3 TRICHLOROETHYLEN[ C2HCL3 1,2,3-TRICHLOROPROPAN� C3 H5C L3

TRIDEUTEROIODIDE C�31 TRIDEUTEROMETHYLA�INE CH2D3N TR lE THYLAM INE C6H15N TRII"ETHYLAMINE C3H9N

P-XYLENE C8HU

1-HEX ENE C6H12

8[NHNE C6H6

BUTYLAMINE C4H11N

DIETHYLAMINE C4H11N DIISOPROPYLAHINE C6H15N DIPROPYUMINE C6H15N

HEX ANE C6H14

HEXYLAMINE C6H15N

PROPYL BROMIDE C3H 7BR 1,1,7.,2-TETRACHLOROETHANE C2H2CL4

TETRACHLOROEThYLENE C2CL4 TETRACHLOROMETHANE CC L4

TOLUENE C7H8

1,1,1-TRICHLOROETHANE C2H3Cl3 1,1,2-TRICHLOROETHANE C2H3CL3 TR ICH LOR OETHYLENl C2HCL3

TR lE THYLAMINE C6H15N

HEXANE C6H14

591-595 42•-422 526-527 473 474

518

414-419 433-437

591 515-517 617-618

351 348

349 354 355 351-353 . 353

356

3 4 7 343

341 341

358-361 344 345 342

651 357

====================·=====================================================================================

IS�BI'TEJ;E C4H8

ISOPRENE C5H8 18

)SOPPEtfE C5 H8

ACETONITRILE C2H3N 39- 41

Z-HETHYl-2-&UTENE C5H1t 632-633

686

Alphabetical Index of Systems

===============================z=====a==================•=================x============================= =

ISOf·PF.Il[

2-tll T\! YLBUTANE

2-METtiYL-1-BUTENE

2-HETHYL-2-BUTENE

METHYLCYCLOPENTANE

:!-rtl THY LPENTANE

C5H8

---� ---

N,N-DIHETHYLFOR�AMIOF O!METHYLSULFOXIDE 2-HETHYLBUTANE 2-�ETHYL-1-BUTENE 2-HETHYL-2-BUTENE 3-METHYL-1-BUTENE

NITROHETHANE TR-1,3-PENTADIENE

ACETONITRILE CARBON OISULFIOE N,N-OIHETHYLFORHAMIOE

2-METHYL-2-BUTENE NITROMETHANE

ACETONITRILE N,N-DIMETHYLFORHA�IOE

2-METHYLBUHNE NITROHETHANE

BENZENE

HXANE 1-PROPANETHIOL

TETRACHLOROHETHANE TOLUENE

BENZEH HEXAOECANE NITROETHANE 1-PROPAHTH I Ol

TETRACHLOROMETHANE

C3H7�0 C2H60S C5H12 C5H10 C 5H 11 C5HU CH3N02 CSH8

C5H12

C2H3N CS2 C3H 7NO

C5H1t

C5H1t CH3N02

C5H1t

C2H3N C3H7NO C5H12 CH3N02

C6H12

C6 HI>

�EXANE C6H14

C3H8S CCL4 C7H8

CtH14

C6H6 C16H34 C 2H5N02 C3H8S CCL4

C6H14 44 41- 43 56 46- 47 48-53 54- 55 38 45

88 . 86-87 89

78 77

si-8 2 8 3 84 79

363-368 368 652-658 369-374 .!62 361 375

622-624 625 62t 621 619

2-RlT�Y L-1-PfNTENE

4-METHYL-1-PENTENF

NEOPf NT AN£

TR-1.3-PENTADIEN£

PENT AM

1-PENTE NE

VINYLhtETYLf.N£

C6H14

687

Alphabetical Index of Systems

HEXADECANE C1 �H34 631

- --------------------------------------------------------

TETRACHLOROMETHA�£ CCL4 626

T OLUENE C7H8 627-629

C6H12

BEN ZENE C6H6 376-377

C6H12

BENZENf C6H6

C5H12

PENTANE C5H12 95- 99

TETRAHETHYLSILANE C4H12 SI 91- 94

C5H6

D!METHYL SULFOXIDE C2H60S 57- 59

C5H12

ACETONITRILE C2H3N 1t1-1t2

ACRYLONITRILE C3H3N 1t3-114

-----------------------------------------------------

BENZENE C6H6 114-118

CYCLOHHAN£ C6H12 119

-------------------------------------------------------

DICHLOROMETHANE CH2CL2 1U

----------------------------------- -------------------

HEPTANE C7H16 126-127

HEX ANE C6H14 122-123

METHYLCYCLOHEXANE C7 H14 124-125

METHYLCYCLOPENTANE C6H12 121-121

PENTYL BROMIDE C5H118R 1t6-113

---------------------------------------------------------

1-PROPANETHIOL C3H8S 115

C5HH

ACETONITRILE C2�3N 85

C4H4

B ENZENE C6H6

P-XYLENE CRH11