• Keine Ergebnisse gefunden

Synthesis, Thermal and X-Ray Investigations of the High-Temperature Phase of Copper(I) Cyanide

N/A
N/A
Info
Herunterladen
Protected

Academic year: 2022

Aktie "Synthesis, Thermal and X-Ray Investigations of the High-Temperature Phase of Copper(I) Cyanide"

Copied!
1
0
0

Wird geladen.... (Jetzt Volltext ansehen)

Jetzt herunterladen ( 1 Seite )

Volltext

(1)

Synthesis, Thermal and X-Ray Investigations of the High-Temperature Phase of Copper(I) Cyanide

Olaf Reckewega, Cora Linda, Arndt Simonb, and Francis J. DiSalvoa

aBaker Laboratory, Department of Chemistry and Chemical Biology Cornell University, Ithaca, NY 14853-1301, USA

bMax-Planck-Institut f¨ur Festk¨orperforschung, D-70569 Stuttgart Reprint requests to Dr. O. Reckeweg. E-mail: olaf.reykjavik@gmx.de Z. Naturforsch. 58b, 155 – 158 (2003); received October 15, 2002

CuCN was investigated by chemical analysis, IR spectroscopy and powder X-ray diffraction. A high-temperature phase of CuCN was identified and structurally characterized by Rietveld refine- ment. HT-CuCN is isotypic to AgCN (R¯3m (No. 166), Z=3, a=597.109(8), c=484.33(5)pm, Cu (3a), C/N (6c), z=0.3915(10)at 77 K) with head-tail disorder of the cyanide anions.

Key words: Copper, Cyanide, Structure Elucidation, Thermal Properties, Optical Spectroscopy

Referenzen

Jetzt herunterladen ( PDF - 1 Seite - 6.25 KB )

ÄHNLICHE DOKUMENTE

Max–Planck–Institut f ¨ur Festk¨orperforschung

Electronic properties of heterostructures, quantum wells, superlattices, and molecular systems, in particular the influence of quantum phenomena on the transport and optical

Pr CBr:AFerromagnetwithPr CLayersHansj¨urgenMattausch,ReinhardK.KremerundArndtSimon Pr CBr:EinFerromagnetmitPr C-Schichten

Max-Planck-Institut f¨ur Festk¨orperforschung, Heisenbergstraße 1, D-70569 Stuttgart, Germany Reprint requests

Synthesis and Crystal Structure of K6

Max-Planck-Institut f¨ur Festk¨orperforschung, Heisenbergstraße 1, D-70569 Stuttgart, Germany Reprint requests to Prof.. The structure has been solved by using single crystal

Synthesis, Thermal and X-Ray Investigations of the High-Temperature Phase of Copper(I) Cyanide

While it seems reasonable to assume that CuCN would adopt a structure similar to AgCN and AuCN on the basis of the NMR data, none of the diffraction patterns reported in the

Rietveld Refinement of the Crystal Structure of α-Be3

a Baker Laboratory, Department of Chemistry and Chemical Biology Cornell University, Ithaca, NY 14853-1301, USA. b Max-Planck-Institut f¨ur Festk¨orperforschung,

OlafReckewegandFrancisJ.DiSalvo Ba [NbN ] O[CN ]–Synthesis,CrystalStructureandRamanSpectrum

Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA.. Reprint requests

X-ray Investigations of Liquid Bismuth-Copper Alloys

The results are compared to previous neutron diffraction results by Zaiss and Steeb, to square-well potential model calculations by Gopala Rao and Satpathy and to a simple

Institut f¨ ur Festk¨ orperforschung Forschungszentrum J¨ ulich GmbH

Hence, phase separation from the meta-stable state is initiated by fluctuations of suf- ficiently large amplitude, contrary to phase separation from the unstable state, where