Cocrystallisation of Trimethylchloro- stannane with a Distannoxane Norbert W. Mitzel, Christian Lustig, and Sandra Scharfe
Anorganisch-chemisches Institut, Technische Universität München, Lichtenbergstr. 4, DÐ85747 Garching Reprint request to Dr. N. W. Mitzel.
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Z. Naturforsch.56 b,440Ð442 (2001);
received March 2, 2001
Tin, Stannoxanes, Supramolecular Aggregate Partial hydrolysis of a mixture of Me2SnCl2and Me3SnCl affords an aggregate of the composition [Sn2Cl(O)(OSnMe3)(Me)4]2, which cocrystallises with two equivalents of Me3SnCl to form endless bands of {[Sn2Cl(O)(OSnMe3)(Me)4]2·
2 Me3SnCl}⬁linked through Sn · · · Cl intermolecu- lar contacts.