Biogeochemical processes at Calyptogena colonies in the Japan Deep Sea Trench: evi-dence for a self-sustaining ecosystem
Janine Felden1, Tobias F. Ertefai2, Fumio Inagaki3, Antje Boetius1,4,5, Frank Wenzhöfer1
1Max Plank Institute for Marine Microbiology, Celsiusstr. 1, D-28359 Bremen, Germany
2Organic Geochemistry Group, MARUM - Center for Marine Environmental Sciences and Department of Geosciences, University of Bremen, Leobener Str., D-28359 Bremen, Germa-ny
3Geomicrobiology Group, Kochi Institute for Core Sample Research, Japan Agency for Ma-rine-Earth Science and Technology (JAMSTEC), Monobe B200, Nankoku, Kochi 783-8502, Japan
4Alfred Wegener Institute for Polar and Marine Research, 27515 Bremerhaven, Germany
5Jacobs University Bremen, 28759 Bremen, Germany
(submission to Environmental Microbiology)
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Abstract
Calyptogena species are typical members of cold seep communities associated with tectonic faults where active venting of fluids and gases takes place which are used by their endosym-biotic sulfide oxidizing bacteria as an energy source. We investigated several clam patches of Calyptogena sp. colonies at a Japan Trench mid-slope terrace at great water depth (5360 m) with the expectation of active seepage of methane and sulfide associated with high sulfate reduction (SR) rates in the sediments. To understand the main biogeochemical processes that define the locally restricted clam colonies, we applied an integrated approach of biogeochem-ical and molecular techniques. Porewater constituents and sulfate and methane turnover was measured at the center and the rim of clam colonies, while 16S rDNA and intact membrane lipid analysis gave insight into the microbial community composition. In the center of the clam field (Fig. VII-5), low SR rates were restricted to the upper (17 cm) sediment horizon and were closely coupled to the anaerobic oxidation of methane (AOM). Depth profiles of
to medi horizon The iso sorbed m cinity as a longe symbion originat local pr
Fig. VII
Fig. VII
iate AOM a n underlying otopic comp methane, bo s energy yie r fueled wi nts is rather ting from m oduction of
I-5: Photog
I-6: Geoch nesis at a
and SR (Fig g the clams position of oth depleted elding proce ith geotherm
r produced mussel remn f methane.
graph and sk
hemical and Calyptogen
g. VII-6D an s are cohere dissolved m d in 13C,pr esses (Fig. V mal fluids.
beneath th nants which
ketch of sam
d lipid-based na mussel fi
nd E). The ent with th methane an rove methan
VII-6B and The meth he clams in
h is fermen
mpling site l
d evidence f eld located
e low turnov he low disso d the prese nogenesis a d C). The C ane to nour zones with nted and via
located in th
for methano in the Japan
ver rates in olved meth ence of sign and methano Calyptogena
rish the che h high loads a methanog
he Japan De
otrophy and n Deep Sea
the upper s ane concen nificant am otrophy in c a sp. colonie emosynthet s of organic genesis lead
eep Sea Tre
d likely met Trench.
sediment ntrations.
ounts of close vi-es are no
ic endo-c endo-carbon ds to the
nch.
thanoge-Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg 0.0048120.0156.8n.d.n.d. 1231E20.104812n.m.n.m.n.d.n.d. 0.4048120.0141.9n.d.n.d. 0.704812n.m.n.m.n.d.n.d. 1.0048120.0184.2n.d.n.d. 1.454812n.m.n.m.n.d.n.d. 2.954812n.m.n.m.n.d.n.d. 4.454812n.m.n.m.n.d.n.d. 4.504812n.m.n.m.n.d.n.d. 5.5048120.0111.6n.d.n.d. 5.9548120.055.9n.d.n.d. 7.454812n.m.n.m.n.d.n.d. 8.8648120.0241.3n.d.n.d. 10.3648120.0144.0n.d.n.d. 11.864812n.m.n.m.n.d.n.d. 13.954812n.m.n.m.n.d.n.d. 15.3548120.0199.0n.d.n.d. 16.854812n.m.n.m.n.d.n.d. 18.4548120.0367.0n.d.n.d. 19.954812n.m.n.m.n.d.n.d. 21.4548120.0474.3n.d.n.d. 23.454812n.m.n.m.n.d.n.d. 24.954812n.d.483.9n.d.n.d. 26.4548120.0n.m.n.d.n.d. 27.9548120.0592.9n.d.n.d. 29.4548120.0189.3n.d.n.d. 30.9548120.0n.m.n.d.n.d. 32.9548120.0n.m.n.d.n.d. 34.4548120.0150.1n.d.n.d. 35.9548120.0n.m.n.d.n.d. 37.4548120.088.3n.d.n.d. 38.9548120.0n.m.n.d.n.d. 40.4548120.0340.4n.d.n.d. 42.4548120.0n.m.n.d.n.d. 43.9548120.0392.5n.d.n.d. 45.4548120.0n.m.n.d.n.d. 46.9548120.01.7n.d.n.d. 48.4548120.01.4n.d.n.d.
see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006
see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 133
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg 1226B21.5032970.00.5n.d.n.d. 5.9032970.04.2n.d.n.d. 8.9032970.01.7n.d.n.d. 15.4032970.01.8n.d.n.d. 18.4032970.01.2n.d.n.d. 24.9032970.01.2n.d.n.d. 27.9032970.01.4n.d.n.d. 34.4032970.01.6n.d.n.d. 37.4032970.0n.d.n.d.n.d. 43.9032970.01.7n.d.n.d. 46.9032970.04.7n.d.n.d. 53.4032970.03.7n.d.n.d. 56.4032970.00.3n.d.n.d. 62.9032970.00.4n.d.n.d. 65.9032970.05.4n.d.n.d. 73.6532970.04.3n.d.n.d. 75.4032970.07.6n.d.n.d. 81.9032970.02.6n.d.n.d. 84.9032970.04.6n.d.n.d. 91.4032970.01.2n.d.n.d. 94.4032970.04.8n.d.n.d. 100.9032970.00.2n.d.n.d. 103.9032970.02.8n.d.n.d. 110.4032970.00.6n.d.n.d. 113.4032970.01.2n.d.n.d. 119.9032970.03.3n.d.n.d. 122.9032970.04.5n.d.n.d. 129.4032970.02.4n.d.n.d. 132.4032970.07.6n.d.n.d. 138.9032970.05.9n.d.n.d. 141.9032970.02.2n.d.n.d. 148.4032970.03.8n.d.n.d. 151.4032970.01.7n.d.n.d. 157.9032970.0n.d.n.d. 160.9032970.06.4n.d.n.d. 167.4032970.07.0n.d.n.d. 170.4032970.04.4n.d.n.d. 176.9032970.0n.d.n.d. 179.9032970.04.2n.d.n.d. 186.4032970.05.4n.d.n.d. 189.4032970.02.9n.d.n.d. 196.2032970.04.5n.d.n.d. 199.2032970.0n.d.n.d. 208.4032970.04.6n.d.n.d. 211.4032970.01.9n.d.n.d. 214.9032970.03.9n.d.n.d. 217.9032970.02.3n.d.n.d.see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006see Hinrichs et al., 2006 134
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg 224.4032970.01.3n.d.n.d. 227.4032970.02.0n.d.n.d. 233.9032970.03.1n.d.n.d. 236.9032970.00.4n.d.n.d. 244.9032970.00.9n.d.n.d. 247.9032970.02.4n.d.n.d. 254.4032970.03.4n.d.n.d. 257.4032970.06.8n.d.n.d. 263.9032970.03.0n.d.n.d. 266.9032970.00.0n.d.n.d. 273.4032970.01.6n.d.n.d. 276.4032970.06.1n.d.n.d. 283.0032970.0n.d.n.d. 286.0032970.04.6n.d.n.d. 292.3032970.0n.d.n.d. 295.3032970.01.3n.d.n.d. 305.0032970.02.2n.d.n.d. 311.7032970.00.5n.d.n.d. 321.3032970.01.0n.d.n.d. 330.9032980.02.1n.d.n.d. 333.9032990.05.5n.d.n.d. 342.0033000.03.2n.d.n.d. 351.7033010.0n.d.n.d.n.d. 362.8333020.0n.d.n.d.n.d. 369.6033030.0n.d.n.d.n.d. 374.1033040.0n.d.n.d.n.d. 381.3533050.0n.d.n.d.n.d. 398.7033060.0n.d.n.d.n.d. 408.3033070.0n.d.n.d.n.d. ge _U1301C_110 mbsf110.5826565.3113.0n.d.n.d.n.d.n.d. 110.5826565.3200.0n.d.n.d.n.d.n.d. gin 171.0018284.1901.5n.d.n.d.n.d.n.d. 171.0018285.9988.8n.d.n.d.n.d.n.d. _U1326D_187 mbsf187.001828209.40.10.40.50.4 (YK06-05) 0.0561800.000081903.812.114.62.60.5 0.0561800.000061853.210.313.02.5 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006
see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006
see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006
see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 135
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg 0.0653460.097364.01.21.7n.d.n.d. 0.1553460.303540.6n.d.n.d.n.d.n.d. 0.2053460.221336.3n.d.n.d.n.d.n.d. Y0.0553460.097492.9n.d.n.d.n.d.n.d. 0.1853460.303295.81.21.60.5 0.2853460.221584.80.40.9 0.21-0.2953460.3712057.7n.d.n.d.n.d.n.d. 0.25-0.3353460.0381728.2n.d.n.d.n.d.n.d. 0.0753460.002105.7n.d.n.d.n.d.n.d. 0.1353460.009103.8n.d.n.d.n.d.n.d. 0.1753460.025290.0n.d.n.d.n.d.n.d. 0.2353460.033346.2n.d.n.d.n.d.n.d. N 0.2412606.878.9n.d.n.d.n.d.n.d. 0.7412605.637.7n.d.n.d.n.d.n.d. 1.2412601.730.6n.d.n.d.n.d.n.d. 1.7412603.349.0n.d.n.d.n.d.n.d. 2.2412604.555.6n.d.n.d.n.d.n.d. 2.7412603.535.0n.d.n.d.n.d.n.d. 136
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg 3.2412603.984.8n.d.n.d.n.d.n.d. 3.7512602.323.9n.d.n.d.n.d.n.d. 4.1512603.435.9n.d.n.d.n.d.n.d. 0.203550.0115.7n.d.n.d.1.73.8 0.303550.0195.4n.d.n.d.1.53.1 0.403550.0246.3n.d.n.d.1.73.5 0.603550.0334.6n.d.n.d.2.54.0 0.803550.0425.6n.d.1.23.15.6 1.003550.0685.60.20.10.10.0 1.203550.0607.70.81.12.64.5 1.403550.0758.9n.d.1.22.74.4 1.603550.2713.7n.d.n.d.n.d.n.d. 1.803550.10210.90.71.53.26.0 2.003551.53.71.43.68.011.9 2.203552.834.7n.d.n.d.n.d.2.4 2.403553.348.6n.d.n.d.n.d.2.8 2.603553.710.2n.d.n.d.n.d.3.7 2.803554.177.2n.d.n.d.2.15.9 3.003554.926.9n.d.n.d.n.d.n.d. 3.203554.624.5n.d.n.d.n.d.n.d. 3.403552.2108.1n.d.2.46.611.4 3.603554.842.5n.d.2.05.29.8 3.803553.955.4n.d.n.d.n.d.n.d. 4.003553.538.0n.d.2.2n.d.n.d. 4.303551.531.1n.d.n.d.n.d.3.4 4.503551.916.2n.d.n.d.n.d.n.d. 4.703551.931.51.84.34.36.6 4.903554.725.24.09.012.915.6 A _BS340G0.028830.03036.9n.d.n.d.n.d.n.d. 0.358832.8187.9n.d.n.d.n.d.n.d. 0.608838.574.9n.d.n.d.n.d.n.d. 0.7488311.8106.9n.d.n.d.n.d.n.d. 1.038835.126.1n.d.n.d.n.d.n.d. 1.348835.826.2n.d.n.d.n.d.n.d. 1.6088310.765.9n.d.n.d.n.d.n.d. 2.038839.91620.3n.d.n.d.n.d.n.d. 2.298834.0171.3n.d.n.d.n.d.n.d. 2.558832.395.6n.d.n.d.n.d.n.d. 2.878832.8120.1n.d.n.d.n.d.n.d. 3.068832.9145.3n.d.n.d.n.d.n.d. 137
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg _BS341G0.118809.8541.3n.d.n.d.n.d.n.d. 0.2588015.8663.2n.d.n.d.n.d.n.d. 0.4488011.2568.9n.d.n.d.n.d.n.d. 0.598808.6304.0n.d.n.d.n.d.n.d. 0.708809.4585.7n.d.n.d.n.d.n.d. 0.848807.5223.3n.d.n.d.n.d.n.d. 0.968804.1155.7n.d.n.d.n.d.n.d. 1.1088014.1570.3n.d.n.d.n.d.n.d. _BS344G0.0719800.03031.5n.d.n.d.n.d.n.d. 0.3619800.070n.m.n.m.n.m.n.m.n.m. 0.5219800.27048.5n.d.n.d.n.d.n.d. 0.6819800.79046.2n.d.n.d.n.d.n.d. 0.97198012.5281.8n.d.n.d.n.d.n.d. 1.1519806.039.8n.d.n.d.n.d.n.d. 1.31198031.0323.8n.d.n.d.n.d.n.d. 1.58198051.3700.6n.d.n.d.n.d.n.d. 1.97198047.834.0n.d.n.d.n.d.n.d. 2.24198015.5336.0n.d.n.d.n.d.n.d. 2.43198041.7222.7n.d.n.d.n.d.n.d. 2.64198017.0624.6n.d.n.d.n.d.n.d. 2.95198025.565.5n.d.n.d.n.d.n.d. 3.13198020.361.5n.d.n.d.n.d.n.d. 3.28198013.2260.2n.d.n.d.n.d.n.d. 3.48198028.1357.6n.d.n.d.n.d.n.d. _BS345GR0.0119446.8122.2n.d.n.d.n.d.n.d. 0.0519444.191.9n.d.n.d.n.d.n.d. 0.0719447.7152.8n.d.n.d.n.d.n.d. 0.0919445.6124.3n.d.n.d.n.d.n.d. 0.1419442.239.7n.d.n.d.n.d.n.d. 0.1819443.470.5n.d.n.d.n.d.n.d. 0.2219442.850.0n.d.n.d.n.d.n.d. 0.2619443.578.2n.d.n.d.n.d.n.d. 0.3019443.559.0n.d.n.d.n.d.n.d. _BS46G0.0120040.267.4n.d.n.d.n.d.n.d. 0.0320040.258.8n.d.n.d.n.d.n.d. 0.0520040.246.3n.d.n.d.n.d.n.d. 0.0720040.17.6n.d.n.d.n.d.n.d. 0.0920040.231.2n.d.n.d.n.d.n.d. 0.1120040.226.9n.d.n.d.n.d.n.d. 0.1320040.225.9n.d.n.d.n.d.n.d. 138
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg 0.1520040.354.2n.d.n.d.n.d.n.d. 0.1720040.461.8n.d.n.d.n.d.n.d. 0.1920041.278.3n.d.n.d.n.d.n.d. 0.2120041.597.9n.d.n.d.n.d.n.d. _BS349G0.0419700.01019.5n.d.n.d.n.d.n.d. 0.2219700.0463.2n.d.n.d.n.d.n.d. 0.4019700.1069.2n.d.n.d.n.d.n.d. 0.5019700.0987.7n.d.n.d.n.d.n.d. 0.6219708.8259.4n.d.n.d.n.d.n.d. _BS350G0.088561.681.2n.d.n.d.n.d.n.d. 0.238561.668.4n.d.n.d.n.d.n.d. 0.328562.969.3n.d.n.d.n.d.n.d. 0.368563.880.9n.d.n.d.n.d.n.d. 0.468565.2115.4n.d.n.d.n.d.n.d. 0.758565.9101.1n.d.n.d.n.d.n.d. 0.888563.657.6n.d.n.d.n.d.n.d. 1.408564.070.8n.d.n.d.n.d.n.d. 2.048565.3118.6n.d.n.d.n.d.n.d. 2.608564.737.1n.d.n.d.n.d.n.d. 2.948563.054.6n.d.n.d.n.d.n.d. 3.258561.838.7n.d.n.d.n.d.n.d. 3.508562.322.9n.d.n.d.n.d.n.d. n.d.n.d.n.d.n.d. _BS351AP0.038551.9163.0n.d.n.d.n.d.n.d. 0.188552.4102.1n.d.n.d.n.d.n.d. 0.238552.9123.6n.d.n.d.n.d.n.d. 0.288555.1165.3n.d.n.d.n.d.n.d. 0.33855100.4n.d.n.d.n.d.n.d. 0.438553.1165.3n.d.n.d.n.d.n.d. 0.48855318.3n.d.n.d.n.d.n.d. 0.538553.7165.3n.d.n.d.n.d.n.d. 0.57855261.3n.d.n.d.n.d.n.d. 0.638554.5165.3n.d.n.d.n.d.n.d. 0.838551.8165.3n.d.n.d.n.d.n.d. 0.938553.429.9n.d.n.d.n.d.n.d. 0.988553.6n.m.n.m.n.m.n.m.n.m. 1.03855159.7n.d.n.d.n.d.n.d. 1.088553.6n.m.n.m.n.m.n.m.n.m. 1.188553.7n.m.n.m.n.m.n.m.n.m. 1.238555.3207.0n.d.n.d.n.d.n.d. 1.488556.0n.m.n.m.n.m.n.m.n.m. 1.53855n.d.819.6n.d.n.d.n.d.n.d. 1.738552.3n.m.n.m.n.m.n.m.n.m. 2.108553.3n.m.n.m.n.m.n.m.n.m. _BS352G0.2785521.0135.0n.d.n.d.n.d.n.d. 139
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg 0.358554.564.8n.d.n.d.n.d.n.d. 0.4285530.1369.5n.d.n.d.n.d.n.d. 0.6085522.3454.1n.d.n.d.n.d.n.d. 0.8085519.3184.6n.d.n.d.n.d.n.d. 1.008559.5113.7n.d.n.d.n.d.n.d. 1.408552.6124.4n.d.n.d.n.d.n.d. 1.708553.973.9n.d.n.d.n.d.n.d. 1.80855n.m.119.9n.d.n.d.n.d.n.d. 1.858554.276.3n.d.n.d.n.d.n.d. _BS353G0.158559.5195.0n.d.n.d.n.d.n.d. 0.2585515.3367.8n.d.n.d.n.d.n.d. 0.3685514.7498.5n.d.n.d.n.d.n.d. 0.6085515.1452.0n.d.n.d.n.d.n.d. 0.8085517.0379.0n.d.n.d.n.d.n.d. 0.978555.5223.5n.d.n.d.n.d.n.d. 1.088554.7216.8n.d.n.d.n.d.n.d. 1.208550.0253.4n.d.n.d.n.d.n.d. 1.458555.3327.2n.d.n.d.n.d.n.d. 1.588555.6302.9n.d.n.d.n.d.n.d. 1.63855181.8n.d.n.d.n.d.n.d. 1.8085513.7n.d.n.d.n.d.n.d. 2.008559.0145.3n.d.n.d.n.d.n.d. 2.2585513.7229.7n.d.n.d.n.d.n.d. 2.508550.1206.0n.d.n.d.n.d.n.d. 2.8085511.5260.1n.d.n.d.n.d.n.d. 3.0585520.4305.3n.d.n.d.n.d.n.d. _BS356G0.0210337.3n.d.n.d.n.d.n.d.n.d. 0.1010335.51865.6n.d.n.d.n.d.n.d. 0.19103311.0n.d.n.d.n.d.n.d.n.d. 0.46103310.0n.d.n.d.n.d.n.d.n.d. 0.6410333.6298.0n.d.n.d.n.d.n.d. 0.7010334.0368.4n.d.n.d.n.d.n.d. 0.8610335.2504.8n.d.n.d.n.d.n.d. 1.0710334.6596.9n.d.n.d.n.d.n.d. _BS359AP0.1010311.511.52.30.20.20.2 0.2010311.220.84.24.40.287.3 0.3110311.026.63.83.52.262.5 0.4310313.411.310.354.0137.2290.0 0.5510312.99.711.450.8270.2295.8 0.7210312.564.86.117.6500.910.1 140
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg 0.8210312.826.43.813.5406.3296.6 0.9210313.231.211.930.5577.5367.6 _BS362G0.089600.121.5n.d.n.d.n.d.n.d. 0.159600.232.7n.d.n.d.n.d.n.d. 0.309601.189.9n.d.n.d.n.d.n.d. 0.469607.8367.0n.d.n.d.n.d.n.d. 0.629607.71280.6n.d.n.d.n.d.n.d. 0.7896023.7872.8n.d.n.d.n.d.n.d. 0.9096019.4786.3n.d.n.d.n.d.n.d. 1.0596023.8555.9n.d.n.d.n.d.n.d. 1.3196019.1236.0n.d.n.d.n.d.n.d. 1.399606.9160.5n.d.n.d.n.d.n.d. 1.549604.9145.7n.d.n.d.n.d.n.d. _BS363G0.108880.034.3n.d.n.d.n.d.n.d. 0.258880.016.7n.d.n.d.n.d.n.d. 0.458880.014.9n.d.n.d.n.d.n.d. 0.608880.021.5n.d.n.d.n.d.n.d. 0.748880.047.0n.d.n.d.n.d.n.d. 0.958880.027.0n.d.n.d.n.d.n.d. 1.088880.0n.m.n.m.n.m.n.m.n.m. 1.208880.026.8n.d.n.d.n.d.n.d. 1.438880.036.4n.d.n.d.n.d.n.d. 1.668880.1100.0n.d.n.d.n.d.n.d. 1.948880.2n.m.n.m.n.m.n.m.n.m. 2.108880.3n.m.n.m.n.m.n.m.n.m. 2.338880.57.6n.d.n.d.n.d.n.d. 2.468881.0n.m.n.m.n.m.n.m.n.m. 2.678881.714.40.10.1n.d.n.d. 2.848882.6n.m.n.m.n.m.n.m.n.m. 3.048883.535.20.20.1n.d.n.d. 3.208883.839.60.20.1n.d.n.d. 3.408884.462.50.20.1n.d.n.d. 3.608885.238.50.1n.d.n.d.n.d. 3.758886.082.30.20.10.1n.d. 3.948888.246.50.10.1n.d.n.d. 4.208889.025.6n.d.n.d.n.d.n.d. 4.4488810.228.0n.d.n.d.n.d.n.d. 4.6188814.4n.m.n.m.n.m.n.m.n.m. 4.7688811.2n.m.n.m.n.m.n.m.n.m. 4.9988812.9n.m.n.m.n.m.n.m.n.m. 5.1688814.187.7n.d.n.d.n.d.n.d. 5.3688812.757.2n.d.n.d.n.d.n.d. 141
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg (DMV)0.2020553.3140.0n.d.n.d.n.d.n.d. _310G0.5020552.8314.1n.d.n.d.n.d.n.d. 0.8020551.799.3n.d.n.d.n.d.n.d. 1.1020553.586.9n.d.n.d.n.d.n.d. 1.3520552.0425.4n.d.n.d.n.d.n.d. 1.7020553.074.4n.d.n.d.n.d.n.d. 2.1020551.8209.2n.d.n.d.n.d.n.d. 2.6020553.9101.8n.d.n.d.n.d.n.d. 3.0020553.1116.4n.d.n.d.n.d.n.d. 3.4020552.677.4n.d.n.d.n.d.n.d. 3.8020552.9177.2n.d.n.d.n.d.n.d. 4.3020552.549.6n.d.n.d.n.d.n.d. 4.4020551.676.0n.d.n.d.n.d.n.d. V0.0220550.020.3n.d.n.d.n.d.7.5 _314G0.3020550.052.2n.d.n.d.n.d.3.5 0.5020550.054.7n.d.n.d.n.d. 0.8020550.018.51.7n.d.4.75.2 1.0020550.035.6n.d.n.d.n.d.5.7 1.1520550.036.3n.d.n.d.n.d.n.d. 1.3020550.4113.12.81.43.86.8 1.6020551.9516.85.72.36.64.3 2.0020553.41041.87.17.80.06.3 2.4020554.41572.99.46.28.314.2 2.5520553.71311.67.7n.d.n.d.14.0 2.7020554.01243.85.6n.d.n.d.0.0 2.9020553.31234.05.9n.d.n.d.66.2 3.1020553.3792.04.0n.d.n.d.10.5 3.2020557.51144.1n.d.n.d.n.d.n.d. 0.0322960.00010.6n.d.n.d.n.d.n.d. _GeoB106-060.0522960.0001n.d.n.d.n.d.n.d.n.d. 0.0822960.0003n.d.n.d.n.d.n.d. 0.1022960.0002n.d.n.d.n.d.n.d. 0.1322960.00031.2n.d.n.d.n.d.n.d. 0.1522960.00031.3n.d.n.d.n.d.n.d. 0.1822960.00021.3n.d.n.d.n.d.n.d. _GeoB106-070.0522984.9n.d.n.d.n.d.n.d. 0.5522980.00012.6n.d.n.d.n.d.n.d. 1.0522980.00032.0n.d.n.d.n.d.n.d. 1.5522980.00022.7n.d.n.d.n.d.n.d. 2.0522980.00032.0n.d.n.d.n.d.n.d. 2.5522980.00032.2n.d.n.d.n.d.n.d. 3.0522980.00022.3n.d.n.d.n.d.n.d. 142
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg 3.5522980.00033.5n.d.n.d.n.d.n.d. 4.0522980.00031.9n.d.n.d.n.d.n.d. 4.5522980.00031.2n.d.n.d.n.d.n.d. 5.0522980.00081.7n.d.n.d.n.d.n.d. 5.5522980.00060.4n.d.n.d.n.d.n.d. 6.0522980.00090.7n.d.n.d.n.d.n.d. _GeoB 106-100.3529640.0011.3n.d.n.d.n.d.0.6 0.6829640.0011.1n.d.n.d.n.d.0.7 1.0129640.0001.5n.d.n.d.n.d.0.6 1.3429640.0010.9n.d.n.d.n.d.0.6 1.6729640.0020.7n.d.n.d.n.d.0.4 2.0029640.003n.d.n.d.n.d.n.d.0.4 2.3329640.003n.d.n.d.n.d.n.d.0.4 2.6629640.005n.d.n.d.n.d.n.d.0.4 2.9929640.0080.8n.d.n.d.n.d.0.4 3.3229640.0111.0n.d.n.d.n.d.0.4 3.6529640.0210.9n.d.n.d.n.d.0.4 3.9829640.0180.2n.d.n.d.n.d.0.4 4.3129640.0210.9n.d.n.d.n.d.0.4 4.9729640.0292.3n.d.n.d.n.d.0.5 4.6429640.0391.0n.d.n.d.n.d.0.4 5.3029640.0401.1n.d.n.d.n.d.0.4 5.6329640.0740.6n.d.n.d.n.d.0.4 5.9629640.1071.8n.d.n.d.n.d.0.4 6.2929640.6175.4n.d.n.d.n.d.0.4 6.6229641.0312.5n.d.n.d.n.d.0.5 6.9529640.8887.40.40.10.10.4 7.2829642.49.61.10.10.50.7 7.3529647.621.28.420.4125.934.2 _GeoB 106-240.0529230.00034.41.0n.d.n.d.n.d. 0.2529230.00039.4n.d.0.90.81.2 0.4529230.00093.0n.d.n.d.n.d.1.3 0.6529230.00134.6n.d.n.d.n.d.n.d. 0.8529230.00133.70.9n.d.n.d.n.d. 1.0529230.00152.6n.d.0.70.81.3 1.2529230.00216.8n.d.n.d.n.d.n.d. 1.4529230.00205.1n.d.n.d.n.d.n.d. _GeoB 106-250.0329211.071.80.90.91.31.3 0.0529221.5137.20.80.81.11.1 0.0829221.5110.61.72.51.31.4 0.1029221.492.11.51.44.81.4 0.1329221.175.32.55.714.14.0 0.1529221.284.7n.d.n.d.n.d.n.d. 0.1829220.954.9n.d.n.d.n.d.n.d. 143
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg o _319ROV-PC30.0220551.54.6n.d.n.d.n.d.n.d. 0.0420551.931.1n.d.n.d.n.d.n.d. 0.0620552.810.2n.d.n.d.n.d.n.d. 0.0820550.00.2n.d.n.d.n.d.n.d. 0.1020550.02.5n.d.n.d.n.d.n.d. 0.1220551.817.40.80.0n.d.n.d. 0.1420550.07.20.40.0n.d.n.d. 0.1620550.27.2n.d.n.d.n.d.n.d. 0.1820550.080.73.00.12.10.0 _310GC_125-135 cmbsf 1.352055n.m.13.90.70.30.40.8 1.352055n.m.32.12.10.60.30.3 1.352055n.m.30.62.00.60.30.2 1.352055n.m.36.52.90.90.40.3 1.352055n.m.32.42.60.90.30.2 1.352055n.m.45.53.41.41.22.0 1.352055n.m.20.91.40.60.30.2 r1.352055n.m.36.41.70.30.30.2
43 144
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg ge _U1301C_110 mbsf )110.582656n.m.n.d.n.d.n.d.n.d.n.d. 110.582656n.m.0.9n.d.n.d.n.d.n.d. 110.582656n.m.64.40.50.5n.d.n.d. 110.582656n.m.42.10.90.6n.d.n.d. 110.582656n.m.33.51.40.80.40.1 110.582656n.m.32.51.40.70.30.1 110.582656n.m.19.71.10.6n.d.n.d. 110.582656n.m.25.51.70.80.30.2 110.582656n.m.23.6n.d.n.d.n.d.n.d. r110.582656n.m.28.52.61.20.00.1 r110.582656n.m.24.33.22.94.610.6 _110 mbsf_t=30 min (2006)110.582656n.m.16.3n.d.n.d.n.d.n.d. 110.5826560.038.6n.d.n.d.n.d.n.d. quot 1** y110.5826560.1n.d.n.d.n.d.n.d.n.d. ys110.582656n.m.13.5n.d.n.d.n.d.n.d. ys110.582656n.m.21.1n.d.n.d.n.d.n.d. ys110.582656n.m.24.9n.d.n.d.n.d.n.d. ys110.582656n.m.35.5n.d.n.d.n.d.n.d. quot 2** y110.5826560.1n.d.n.d.n.d.n.d.n.d. ys110.582656n.m.20.2n.d.n.d.n.d.n.d. ys110.582656n.m.33.1n.d.n.d.n.d.n.d. ys110.582656n.m.38.6n.d.n.d.n.d.n.d. ys110.582656n.m.48.0n.d.n.d.n.d.n.d. 145
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg gin _U1326D_187 mbsf )187.001828n.m.n.d.n.d.n.d.n.d.n.d. 187.001828n.m.705.91.414.81.48.4 187.001828n.m.709.21.414.91.48.5 187.001828n.m.710.91.514.91.58.5 187.001828n.m.711.81.515.01.58.5 187.001828n.m.712.21.515.01.58.5 187.001828n.m.716.21.515.01.58.5 187.001828n.m.716.31.515.01.58.5 187.001828n.m.716.51.515.01.58.5 r187.001828n.m.716.71.515.01.58.5 (2006)187.001828n.m.258.0n.d.n.d.n.d.n.d. 187.0018280.2209.40.10.40.50.4 _U1326D_171 mbsf quot 1 y171.0018282.1n.d.n.d.n.d.n.d.n.d. ys171.001828436.5n.d.n.d.n.d.n.d. ys171.001828729.5n.d.n.d.n.d.n.d. ys171.001828842.7n.d.n.d.n.d.n.d. ys171.001828901.5n.d.n.d.n.d.n.d. quot 2 y171.0018281.8n.d.n.d.n.d.n.d.n.d. ys171.001828459.3n.d.n.d.n.d.n.d. ys171.001828798.9n.d.n.d.n.d.n.d. ys171.001828926.7n.d.n.d.n.d.n.d. ys171.001828988.8n.d.n.d.n.d.n.d. (YK06-05) _21-25 cmbsf )0.21-0.255346n.d.n.d.n.d.n.d.n.d. 0.21-0.2553461.6n.d.n.d.n.d.n.d. 0.21-0.2553463.6n.d.n.d.n.d.n.d. 0.21-0.2553461.4n.d.n.d.n.d.n.d. 0.21-0.2553467.0n.d.n.d.n.d.n.d. 0.21-0.2553464.9n.d.n.d.n.d.n.d. 0.21-0.255346n.m.n.m.n.m.n.m.n.m. 0.21-0.25534628.5n.d.n.d.n.d.n.d. 0.21-0.25534637.8n.d.n.d.n.d.n.d. 0.21-0.25534655.80.2n.d.n.d.n.d. 0.21-0.25534680.40.3n.d.n.d.n.d. r0.21-0.25534695.20.3n.d.n.d.n.d. 146
Sediment depthWater depthDissolved CH4Sorbed CH41Sorbed C2H6Sorbed C3H8Sorbedn-C4H10Sorbedn-C5H12Sorbed mbsfmmMµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg dry sedµmol/kg 0.21-0.2553460.1367.22.42.5n.d.n.d. f y0.21-0.2853460.3n.d.n.d.n.d.n.d.n.d. ys0.21-0.295346415.5n.d.n.d.n.d.n.d. ys0.21-0.295346904.5n.d.n.d.n.d.n.d. ys0.21-0.295346139.5n.d.n.d.n.d.n.d. ys0.21-0.2953462057.7n.d.n.d.n.d.n.d. f y0.25-0.3253460.0n.d.n.d.n.d.n.d.n.d. ys0.25-0.335346249.2n.d.n.d.n.d.n.d. ys0.25-0.335346965.3n.d.n.d.n.d.n.d. ys0.25-0.3353461258.9n.d.n.d.n.d.n.d. ys0.25-0.3353461728.2n.d.n.d.n.d.n.d. 147
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
Peru Basin 0.00 n.m. -61.1 0.6 n.m. n.m.
0.10 n.m. n.m. n.m. n.m.
0.40 n.m. -66.6 n.m. n.m.
0.70 n.m. n.m. n.m. n.m.
1.00 n.m. -63.8 n.m. n.m.
1.45 n.m. n.m. n.m. n.m.
2.95 n.m. n.m. n.m. n.m.
4.45 n.m. n.m. n.m. n.m.
4.50 n.m. n.m. n.m. n.m.
5.50 n.m. -59.9 n.m. n.m.
5.95 n.m. -63.5 n.m. n.m.
7.45 n.m. n.m. n.m. n.m.
8.86 n.m. -61.5 0.04 n.m. n.m.
10.36 n.m. n.m. n.m. n.m.
11.86 n.m. -65.3 3.1 n.m. n.m.
13.95 n.m. n.m. n.m. n.m.
15.35 n.m. -59.7 n.m. n.m.
16.85 n.m. n.m. n.m. n.m.
18.45 n.m. -62.4 n.m. n.m.
19.95 n.m. n.m. n.m. n.m.
21.45 n.m. -60.8 1.1 n.m. n.m.
23.45 n.m. n.m. n.m. n.m.
24.95 n.m. -59.2 n.m. n.m.
26.45 n.m. n.m. n.m. n.m.
27.95 n.m. -63.8 n.m. n.m.
29.45 n.m. n.m. n.m. n.m.
30.95 n.m. -60.4 n.m. n.m.
32.95 n.m. n.m. n.m. n.m.
34.45 n.m. -58.5 n.m. n.m.
35.95 n.m. n.m. n.m. n.m.
37.45 n.m. -56.8 n.m. n.m.
38.95 n.m. n.m. n.m. n.m.
40.45 n.m. -61.7 2.5 n.m. n.m.
42.45 n.m. n.m. n.m. n.m.
43.95 n.m. -57.0 n.m. n.m.
45.45 n.m. n.m. n.m. n.m.
46.95 n.m. n.m. n.m. n.m.
48.45 n.m. n.m. n.m. n.m.
110.58 -77.0 0.13 -64.6 w.m. n.d. n.d. n.m. n.m.
110.58 -77.3 0.76 -71.0 w.m. n.d. n.d. n.m. n.m.
PACIFIC OCEAN
Juan de Fuca Ridge IODP X 301
U1301C ODP Leg 201 Site 1231E2
see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006 see Hinrichs et al., 2006
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
IODP X 311 U1326D sample 1
171.00 -62.7 0.02 -68.2 w.m. n.d. n.d. n.m. n.m.
IODP X 311 U1326D sample 2
171.00 -66.9 1.10 -68.6 w.m. n.d. n.d. n.m. n.m.
IODP X 311
U1326D 187.00 n.m. n.m. n.m. n.m. n.m. n.m.
Japan Trench (YK06-05)
6K954R 0.05 -74.5 0.40 -77.0 0.07 -24.7 -13.9 n.m. n.m.
6K954G 0.05 -74.4 1.00 -77.5 0.01 n.d. n.d. n.m. n.m.
6K955CR 0.06 -72.3 3.00 -73.4 0.44 n.d. n.d. n.m. n.m.
0.15 -66.7 0.10 -71.5 0.84 n.d. n.d. n.m. n.m.
0.20 -71.1 1.30 -69.0 0.14 n.d. n.d. n.m. n.m.
6K957CY 0.05 -79.1 0.30 -74.7 0.44 n.d. n.d. n.m. n.m.
0.18 -84.2 1.00 -66.4 0.18 n.d. n.d. n.m. n.m.
0.28 -82.3 1.50 -70.2 0.65 n.d. n.d. n.m. n.m.
0.21-0.29 -82.9 0.8 -75.5 w.m. n.d. n.d. n.m. n.m.
0.25-0.33 -81.1 1.3 -74.3 w.m. n.d. n.d. n.m. n.m.
6K958CG 0.07 -71.9 1.80 -76.1 0.71 n.d. n.d. n.m. n.m.
0.13 -74.3 1.40 -65.2 1.05 n.d. n.d. n.m. n.m.
0.17 -78.3 0.60 -67.2 0.32 n.d. n.d. n.m. n.m.
0.23 -78.9 1.00 -71.7 0.31 n.d. n.d. n.m. n.m.
Håkon Mosby Mud Volcano (HMMV)
0.24 -61.1 0.3 -60.0 0.00 n.d. n.d. n.m. n.m.
PS ARK XXII 0.74 -59.6 0.1 -56.9 n.d. n.d. n.m. n.m.
PS70/075-1 1.24 -60.7 0.1 -60.0 0.00 n.d. n.d. n.m. n.m.
1.74 -60.7 -58.5 0.10 n.d. n.d. n.m. n.m.
2.24 -61.1 0.2 -60.6 0.20 n.d. n.d. n.m. n.m.
2.74 -59.5 0.1 -58.5 n.d. n.d. n.m. n.m.
3.24 -59.6 0.0 -59.9 0.10 n.d. n.d. n.m. n.m.
3.75 -61.2 -59.1 0.10 n.d. n.d. n.m. n.m.
4.15 -59.7 0.0 -59.1 0.30 n.d. n.d. n.m. n.m.
Cascadia Margin
ATLANTIC OCEAN
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
INDIAN OCEAN
0.20 -63.9 0.44 -46.6 0.72 n.d. n.d. n.m. n.m.
0.30 -65.2 1.34 -51.7 0.83 n.d. n.d. n.m. n.m.
0.40 -65.6 0.15 -54.6 0.52 n.d. n.d. n.m. n.m.
0.60 -65.3 0.09 -53.6 0.35 n.d. n.d. n.m. n.m.
M74/2 0.80 -66.6 0.38 -54.4 0.82 n.d. n.d. n.m. n.m.
1.00 -66.9 0.20 -52.8 0.12 n.d. n.d. n.m. n.m.
1.20 -70.2 0.21 -53.6 1.61 n.d. n.d. n.m. n.m.
1.40 -73.8 0.59 -53.9 0.58 n.d. n.d. n.m. n.m.
1.60 -81.7 0.17 -61.2 0.30 n.d. n.d. n.m. n.m.
1.80 -85.7 0.44 -81.1 0.28 n.d. n.d. n.m. n.m.
2.00 -87.9 0.14 -84.0 0.04 n.d. n.d. n.m. n.m.
2.20 -87.8 0.08 -85.6 0.09 n.d. n.d. n.m. n.m.
2.40 -87.2 0.02 -84.8 0.16 n.d. n.d. n.m. n.m.
2.60 -86.3 0.09 -85.9 0.34 n.d. n.d. n.m. n.m.
2.80 -85.0 0.06 -82.4 0.40 n.d. n.d. n.m. n.m.
3.00 -84.5 0.22 -83.3 0.07 n.d. n.d. n.m. n.m.
3.20 -83.6 0.00 -80.4 0.19 n.d. n.d. n.m. n.m.
3.40 -82.8 0.30 -82.6 0.01 n.d. n.d. n.m. n.m.
3.60 -81.7 0.01 -80.5 0.15 n.d. n.d. n.m. n.m.
3.80 -80.7 0.12 -79.3 0.28 n.d. n.d. n.m. n.m.
4.00 -78.2 0.11 -76.1 0.04 n.d. n.d. n.m. n.m.
4.30 -77.6 0.00 -73.0 1.22 n.d. n.d. n.m. n.m.
4.50 -76.5 0.01 -58.7 0.16 n.d. n.d. n.m. n.m.
4.70 -76.1 0.15 -72.9 0.22 n.d. n.d. n.m. n.m.
4.90 -75.7 0.05 -71.3 0.20 n.d. n.d. n.m. n.m.
GeoB12210-6 Makran accretionary margin, Pakistan
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
BLACK SEA
0.02 -69.4 1.60 -66.0 n.d. n.d. n.m. n.m.
0.35 -65.7 0.10 -67.6 0.0 n.d. n.d. n.m. n.m.
0.60 -63.5 1.60 -72.2 n.d. n.d. n.m. n.m.
0.74 -64.1 0.50 -69.9 n.d. n.d. n.m. n.m.
1.03 -63.6 0.60 n.d. n.d. n.m. n.m.
1.34 -61.4 0.20 n.d. n.d. n.m. n.m.
1.60 -59.4 0.30 -62.2 n.d. n.d. n.m. n.m.
2.03 -58.7 0.00 -62.0 0.4 n.d. n.d. n.m. n.m.
2.29 -51.2 0.30 -59.3 0.1 n.d. n.d. n.m. n.m.
2.55 -54.9 3.70 -59.1 0.5 n.d. n.d. n.m. n.m.
2.87 -58.8 0.30 -58.3 0.5 n.d. n.d. n.m. n.m.
3.06 n.m. -57.0 0.8 n.d. n.d. n.m. n.m.
0.11 n.m. n.m. n.d. n.d. n.m. n.m.
0.25 n.m. n.m. n.d. n.d. n.m. n.m.
0.44 n.m. n.m. n.d. n.d. n.m. n.m.
0.59 n.m. n.m. n.d. n.d. n.m. n.m.
0.70 n.m. n.m. n.d. n.d. n.m. n.m.
0.84 n.m. n.m. n.d. n.d. n.m. n.m.
0.96 n.m. n.m. n.d. n.d. n.m. n.m.
1.10 n.m. n.m. n.d. n.d. n.m. n.m.
0.07 n.d. n.d. n.d. n.d. n.m. n.m.
0.36 n.d. n.d. n.d. n.d. n.m. n.m.
0.52 n.d. n.d. n.d. n.d. n.m. n.m.
0.68 n.d. n.d. n.d. n.d. n.m. n.m.
0.97 n.d. -80.8 0.5 n.d. n.d. n.m. n.m.
1.15 n.d. n.d. n.d. n.d. n.m. n.m.
1.31 n.d. -75.4 0.1 n.d. n.d. n.m. n.m.
1.58 n.d. -70.9 0.9 n.d. n.d. n.m. n.m.
1.97 n.d. n.d. n.d. n.d. n.m. n.m.
2.24 -70.7 0.9 -70.1 0.1 n.d. n.d. n.m. n.m.
2.43 n.d. -67.7 0.2 n.d. n.d. n.m. n.m.
2.64 n.d. -67.0 0.3 n.d. n.d. n.m. n.m.
2.95 n.d. -72.5 0.6 n.d. n.d. n.m. n.m.
3.13 n.d. -76.3 1.0 n.d. n.d. n.m. n.m.
3.28 -68.3 1.5 -70.4 0.6 n.d. n.d. n.m. n.m.
3.48 n.d. -67.3 1.0 n.d. n.d. n.m. n.m.
0.01 -54.3 0.10 -59.1 0.5 n.d. n.d. n.m. n.m.
0.05 -53.3 0.10 -56.1 0.2 n.d. n.d. n.m. n.m.
0.07 -53.1 0.00 -56.8 0.8 n.d. n.d. n.m. n.m.
0.09 -52.4 0.00 -54.4 0.2 n.d. n.d. n.m. n.m.
0.14 -52.6 0.10 -62.2 0.4 n.d. n.d. n.m. n.m.
0.18 -50.8 0.70 -58.0 0.1 n.d. n.d. n.m. n.m.
0.22 -53.3 0.30 -56.6 0.5 n.d. n.d. n.m. n.m.
0.26 -53.2 0.00 -58.4 0.7 n.d. n.d. n.m. n.m.
0.30 n.m. -56.9 n.d. n.d. n.m. n.m.
TTR15_BS345G R
TTR15_BS344G TTR15_BS341G TTR15_BS340G
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
TTR15_BS46G 0.01 n.m. n.m. n.d. n.d. n.m. n.m.
0.03 n.m. n.m. n.d. n.d. n.m. n.m.
0.05 n.m. n.m. n.d. n.d. n.m. n.m.
0.07 n.m. n.m. n.d. n.d. n.m. n.m.
0.09 n.m. n.m. n.d. n.d. n.m. n.m.
0.11 n.m. n.m. n.d. n.d. n.m. n.m.
0.13 n.m. n.m. n.d. n.d. n.m. n.m.
0.15 n.m. n.m. n.d. n.d. n.m. n.m.
0.17 n.m. n.m. n.d. n.d. n.m. n.m.
0.19 n.m. n.m. n.d. n.d. n.m. n.m.
0.21 n.m. n.m. n.d. n.d. n.m. n.m.
0.04 n.m. n.m. n.d. n.d. n.m. n.m.
0.22 n.m. n.m. n.d. n.d. n.m. n.m.
0.40 n.m. n.m. n.d. n.d. n.m. n.m.
0.50 n.m. n.m. n.d. n.d. n.m. n.m.
0.62 n.m. n.m. n.d. n.d. n.m. n.m.
0.08 -50.6 0.5 -54.8 1.5 n.d. n.d. n.m. n.m.
0.23 -51.6 0.8 -54.0 0.1 n.d. n.d. n.m. n.m.
0.32 -50.9 0.9 -52.9 1.7 n.d. n.d. n.m. n.m.
0.36 -49.3 1.1 -54.1 1.0 n.d. n.d. n.m. n.m.
0.46 -49.9 0.5 -53.2 0.4 n.d. n.d. n.m. n.m.
0.75 -48.5 0.0 -54.4 0.7 n.d. n.d. n.m. n.m.
0.88 -50.2 0.1 -53.5 0.4 n.d. n.d. n.m. n.m.
1.40 -49.7 0.7 -53.1 1.2 n.d. n.d. n.m. n.m.
2.04 -50.4 0.1 -52.5 0.5 n.d. n.d. n.m. n.m.
2.60 -49.9 0.4 -49.6 0.1 n.d. n.d. n.m. n.m.
2.94 -50.0 0.5 -57.4 0.5 n.d. n.d. n.m. n.m.
3.25 -49.0 1.3 -52.9 1.3 n.d. n.d. n.m. n.m.
3.50 -44.6 0.1 -48.1 0.7 n.d. n.d. n.m. n.m.
TTR15_BS351A
P 0.03 -48.7 1.00 -55.6 0.5 n.d. n.d. n.m. n.m.
0.18 n.d. n.m. n.d. n.d. n.m. n.m.
0.23 n.d. n.m. n.d. n.d. n.m. n.m.
0.28 n.d. n.m. n.d. n.d. n.m. n.m.
0.33 n.d. -55.9 0.1 n.d. n.d. n.m. n.m.
0.43 n.d. n.m. n.d. n.d. n.m. n.m.
0.48 n.d. -52.8 0.3 n.d. n.d. n.m. n.m.
0.53 n.d. n.m. n.d. n.d. n.m. n.m.
0.57 n.d. -53.4 1.6 n.d. n.d. n.m. n.m.
0.63 n.d. n.m. n.d. n.d. n.m. n.m.
0.83 n.d. n.m. n.d. n.d. n.m. n.m.
0.93 n.d. n.d. n.d. n.d. n.m. n.m.
0.98 n.d. n.m. n.d. n.d. n.m. n.m.
1.03 n.d. n.d. n.d. n.d. n.m. n.m.
1.08 n.d. n.m. n.d. n.d. n.m. n.m.
1.18 n.d. n.m. n.d. n.d. n.m. n.m.
1.23 n.d. n.d. n.d. n.d. n.m. n.m.
1.48 n.d. n.m. n.d. n.d. n.m. n.m.
TTR15_BS349G
TTR15_BS350G
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
1.53 n.d. -50.2 1.6 n.d. n.d. n.m. n.m.
1.73 n.d. n.m. n.d. n.d. n.m. n.m.
2.10 n.d. n.m. n.d. n.d. n.m. n.m.
0.27 n.m. n.d. n.d. n.d. n.m. n.m.
0.35 n.m. n.d. n.d. n.d. n.m. n.m.
0.42 n.m. n.d. n.d. n.d. n.m. n.m.
0.60 n.m. n.d. n.d. n.d. n.m. n.m.
0.80 n.m. n.d. n.d. n.d. n.m. n.m.
1.00 n.m. -53.5 0.4 n.d. n.d. n.m. n.m.
1.40 n.m. -53.1 1.2 n.d. n.d. n.m. n.m.
1.70 n.m. -52.5 0.5 n.d. n.d. n.m. n.m.
1.80 n.m. -49.6 0.1 n.d. n.d. n.m. n.m.
1.85 n.m. -57.4 0.5 n.d. n.d. n.m. n.m.
0.15 n.m. n.m. n.d. n.d. n.m. n.m.
0.25 n.m. n.m. n.d. n.d. n.m. n.m.
0.36 n.m. n.m. n.d. n.d. n.m. n.m.
0.60 n.m. n.m. n.d. n.d. n.m. n.m.
0.80 n.m. n.m. n.d. n.d. n.m. n.m.
0.97 n.m. n.m. n.d. n.d. n.m. n.m.
1.08 n.m. n.m. n.d. n.d. n.m. n.m.
1.20 n.m. n.m. n.d. n.d. n.m. n.m.
1.45 n.m. n.m. n.d. n.d. n.m. n.m.
1.58 n.m. n.m. n.d. n.d. n.m. n.m.
1.63 n.m. n.m. n.d. n.d. n.m. n.m.
1.80 n.m. n.m. n.d. n.d. n.m. n.m.
2.00 n.m. n.m. n.d. n.d. n.m. n.m.
2.25 n.m. n.m. n.d. n.d. n.m. n.m.
2.50 n.m. n.m. n.d. n.d. n.m. n.m.
2.80 n.m. n.m. n.d. n.d. n.m. n.m.
3.05 n.m. n.m. n.d. n.d. n.m. n.m.
n.d. n.d. n.m. n.m.
0.02 n.m. n.m. n.d. n.d. n.m. n.m.
0.10 n.m. n.m. n.d. n.d. n.m. n.m.
0.19 n.m. n.m. n.d. n.d. n.m. n.m.
0.46 n.m. n.m. n.d. n.d. n.m. n.m.
0.64 n.m. n.m. n.d. n.d. n.m. n.m.
0.70 n.m. n.m. n.d. n.d. n.m. n.m.
0.86 n.m. n.m. n.d. n.d. n.m. n.m.
1.07 n.m. n.m. n.d. n.d. n.m. n.m.
TTR15_BS359A
P 0.10 n.d. -43.1 n.d. n.d. n.m. n.m.
0.20 -46.4 -45.0 n.d. n.d. n.m. n.m.
0.31 -45.2 -47.2 n.d. n.d. n.m. n.m.
0.43 -44.5 -44.5 n.d. n.d. n.m. n.m.
0.55 n.d. n.d. n.d. n.d. n.m. n.m.
0.72 n.d. -45.9 n.d. n.d. n.m. n.m.
0.82 n.d. -44.8 n.d. n.d. n.m. n.m.
0.92 -47.9 -45.7 n.d. n.d. n.m. n.m.
0.08 n.d. n.m. n.d. n.d. n.m. n.m.
0.15 -78.9 n.d. n.d. n.d. n.m. n.m.
0.30 -73.7 0.50 -78.8 1.84 n.d. n.d. n.m. n.m.
0.46 -60.3 0.90 -62.2 0.45 n.d. n.d. n.m. n.m.
0.62 -54.4 0.20 -56.3 0.47 n.d. n.d. n.m. n.m.
TTR15_BS362G TTR15_BS352G
TTR15_BS353G
TTR15_BS356G
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
0.78 -53.0 0.10 -54.3 0.55 n.d. n.d. n.m. n.m.
0.90 -54.2 0.70 -55.0 0.02 n.d. n.d. n.m. n.m.
1.05 -52.1 0.40 -56.5 0.17 n.d. n.d. n.m. n.m.
1.31 -53.3 0.80 -56.9 0.21 n.d. n.d. n.m. n.m.
1.39 -52.1 0.40 -54.6 0.83 n.d. n.d. n.m. n.m.
1.54 -52.4 0.50 -51.8 0.84 n.d. n.d. n.m. n.m.
0.10 n.m. -49.4 0.96 n.d. n.d. n.m. n.m.
0.25 n.m. -47.3 0.84 n.d. n.d. n.m. n.m.
0.45 n.m. n.m. n.d. n.d. n.m. n.m.
0.60 n.m. n.m. n.d. n.d. n.m. n.m.
0.74 n.m. -51.2 0.05 n.d. n.d. n.m. n.m.
0.95 n.m. n.m. n.d. n.d. n.m. n.m.
1.08 n.m. -52.6 0.43 n.d. n.d. n.m. n.m.
1.20 n.m. n.m. n.d. n.d. n.m. n.m.
1.43 n.m. n.m. n.d. n.d. n.m. n.m.
1.66 n.m. n.m. n.d. n.d. n.m. n.m.
1.94 -61.8 0.2 -64.6 0.9 n.d. n.d. n.m. n.m.
2.10 n.m. n.m. n.d. n.d. n.m. n.m.
2.33 -66.2 1.00 n.m. n.d. n.d. n.m. n.m.
2.46 -68.0 1.15 -71.0 1.05 n.d. n.d. n.m. n.m.
2.67 n.m. n.m. n.d. n.d. n.m. n.m.
2.84 -74.1 0.05 -75.0 1.22 n.d. n.d. n.m. n.m.
3.04 -75.5 0.30 n.m. n.d. n.d. n.m. n.m.
3.20 n.m. n.m. n.d. n.d. n.m. n.m.
3.40 n.m. n.m. n.d. n.d. n.m. n.m.
3.60 -75.9 -79.7 0.33 n.d. n.d. n.m. n.m.
3.75 n.m. n.m. n.d. n.d. n.m. n.m.
3.94 n.m. -76.6 0.13 n.d. n.d. n.m. n.m.
4.20 n.m. n.m. n.d. n.d. n.m. n.m.
4.44 -73.1 0.08 -76.2 0.16 n.d. n.d. n.m. n.m.
4.61 n.m. n.m. n.d. n.d. n.m. n.m.
4.76 n.m. n.m. n.d. n.d. n.m. n.m.
4.99 n.m. n.m. n.d. n.d. n.m. n.m.
5.16 n.m. -74.5 0.25 n.d. n.d. n.m. n.m.
5.36 -72.1 0.16 -75.1 0.33 n.d. n.d. n.m. n.m.
0.20 -59.7 0.28 -57.7 0.28 n.d. n.d. n.m. n.m.
0.50 -60.4 0.08 -57.5 0.08 n.d. n.d. n.m. n.m.
0.80 -58.4 0.21 -57.1 0.21 n.d. n.d. n.m. n.m.
M72/2_310G 1.10 -59.0 0.11 -57.5 0.11 n.d. n.d. n.m. n.m.
1.35 -58.4 0.10 -57.9 0.10 n.d. n.d. n.m. n.m.
1.70 -58.5 0.19 -57.1 0.19 n.d. n.d. n.m. n.m.
2.10 -59.4 0.11 -57.5 0.11 n.d. n.d. n.m. n.m.
2.60 -58.5 0.40 -53.1 0.40 n.d. n.d. n.m. n.m.
3.00 -58.5 0.71 -56.7 0.71 n.d. n.d. n.m. n.m.
3.40 -58.4 0.04 -55.5 0.04 n.d. n.d. n.m. n.m.
3.80 -60.0 0.04 -56.5 0.04 n.d. n.d. n.m. n.m.
4.30 -59.7 0.03 -56.1 0.03 n.d. n.d. n.m. n.m.
4.40 -59.0 0.19 -55.4 0.19 n.d. n.d. n.m. n.m.
North of DMV 0.02 n.m. n.m. n.d. n.d. n.m. n.m.
M72/2_314G 0.30 n.m. n.m. n.d. n.d. n.m. n.m.
0.50 n.m. n.m. n.d. n.d. n.m. n.m.
0.80 n.m. n.m. n.d. n.d. n.m. n.m.
1.00 n.m. n.m. n.d. n.d. n.m. n.m.
TTR15_BS363G
Dvurechenski Mud Volcano (DMV)
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
1.15 n.m. n.m. n.d. n.d. n.m. n.m.
1.30 n.m. n.m. n.d. n.d. n.m. n.m.
1.60 n.m. n.m. n.d. n.d. n.m. n.m.
2.00 n.m. n.m. n.d. n.d. n.m. n.m.
2.40 n.m. n.m. n.d. n.d. n.m. n.m.
2.55 n.m. n.m. n.d. n.d. n.m. n.m.
2.70 n.m. n.m. n.d. n.d. n.m. n.m.
2.90 n.m. n.m. n.d. n.d. n.m. n.m.
3.10 n.m. n.m. n.d. n.d. n.m. n.m.
3.20 n.m. n.m. n.d. n.d. n.m. n.m.
0.03 n.m. n.m. n.d. n.d. n.m. n.m.
0.05 n.m. n.m. n.d. n.d. n.m. n.m.
0.08 n.m. n.m. n.d. n.d. n.m. n.m.
0.10 n.m. n.m. n.d. n.d. n.m. n.m.
0.13 n.m. n.m. n.d. n.d. n.m. n.m.
0.15 n.m. n.m. n.d. n.d. n.m. n.m.
0.18 n.m. n.m. n.d. n.d. n.m. n.m.
0.05 n.m. n.m. n.d. n.d. n.m. n.m.
0.55 n.m. n.m. n.d. n.d. n.m. n.m.
1.05 n.m. n.m. n.d. n.d. n.m. n.m.
1.55 n.m. n.m. n.d. n.d. n.m. n.m.
2.05 n.m. n.m. n.d. n.d. n.m. n.m.
2.55 n.m. n.m. n.d. n.d. n.m. n.m.
3.05 n.m. n.m. n.d. n.d. n.m. n.m.
3.55 n.m. n.m. n.d. n.d. n.m. n.m.
4.05 n.m. n.m. n.d. n.d. n.m. n.m.
4.55 n.m. n.m. n.d. n.d. n.m. n.m.
5.05 n.m. n.m. n.d. n.d. n.m. n.m.
5.55 n.m. n.m. n.d. n.d. n.m. n.m.
6.05 n.m. n.m. n.d. n.d. n.m. n.m.
M67/2b_GeoB10 6-06
M67/2b_GeoB10 6-07
GULF OF MEXICO, Chapopote Knoll
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
0.35 n.m. n.m. n.m. n.m. n.m.
0.68 n.m. n.m. n.m. n.m. n.m.
1.01 n.m. n.m. n.m. n.m. n.m.
1.34 n.m. n.m. n.m. n.m. n.m.
1.67 n.m. n.m. n.m. n.m. n.m.
2.00 n.m. n.m. n.m. n.m. n.m.
2.33 n.m. n.m. n.m. n.m. n.m.
2.66 n.m. n.m. n.m. n.m. n.m.
2.99 n.m. n.m. n.m. n.m. n.m.
3.32 n.m. n.m. n.m. n.m. n.m.
3.65 n.m. n.m. n.m. n.m. n.m.
3.98 n.m. n.m. n.m. n.m. n.m.
4.31 n.m. n.m. n.m. n.m. n.m.
4.97 n.m. n.m. n.m. n.m. n.m.
4.64 n.m. n.m. n.m. n.m. n.m.
5.30 n.m. n.m. n.m. n.m. n.m.
5.63 n.m. n.m. n.m. n.m. n.m.
5.96 n.m. n.m. n.m. n.m. n.m.
6.29 n.m. n.m. n.m. n.m. n.m.
6.62 n.m. n.m. n.m. n.m. n.m.
6.95 n.m. n.m. n.m. n.m. n.m.
7.28 n.m. n.m. n.m. n.m. n.m.
7.35 n.m. n.m. n.m. n.m. n.m.
n.m. n.m.
0.05 n.m. n.m. n.m. n.m. n.m.
0.25 n.m. n.m. n.m. n.m. n.m.
0.45 n.m. n.m. n.m. n.m. n.m.
0.65 n.m. n.m. n.m. n.m. n.m.
0.85 n.m. n.m. n.m. n.m. n.m.
1.05 n.m. n.m. n.m. n.m. n.m.
1.25 n.m. n.m. n.m. n.m. n.m.
1.45 n.m. n.m. n.m. n.m. n.m.
0.03 n.m. n.m. n.m. n.m. n.m.
0.05 n.m. n.m. n.m. n.m. n.m.
0.08 n.m. n.m. n.m. n.m. n.m.
0.10 n.m. n.m. n.m. n.m. n.m.
0.13 n.m. n.m. n.m. n.m. n.m.
0.15 n.m. n.m. n.m. n.m. n.m.
0.18 n.m. n.m. n.m. n.m. n.m.
Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished M67/2b_GeoB
106-10
M67/2b_GeoB 106-24
M67/2b_GeoB 106-25
Schubotz et al., unpublished Schubotz et al., unpublished Schubotz et al., unpublished
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
0.02 n.m. n.m. n.d. n.d. n.m. n.m.
0.04 n.m. -54.4 0.45 n.d. n.d. n.m. n.m.
0.06 n.m. n.m. n.d. n.d. n.m. n.m.
M72/2 0.08 n.m. n.m. n.d. n.d. n.m. n.m.
0.10 n.m. n.m. n.d. n.d. n.m. n.m.
0.12 n.m. -54.8 0.45 n.d. n.d. n.m. n.m.
0.14 n.m. n.m. n.d. n.d. n.m. n.m.
0.16 n.m. n.m. n.d. n.d. n.m. n.m.
0.18 n.m. -55.9 0.32 n.d. n.d. n.m. n.m.
M72/2 H3PO4
t=2 1.35 n.m. -56.3 0.08 n.d. n.d. n.m. n.m.
t=5 1.35 n.m. -55.2 0.47 n.d. n.d. n.m. n.m.
t=10 1.35 n.m. -56.4 0.44 n.d. n.d. n.m. n.m.
t=15 1.35 n.m. -54.8 0.12 n.d. n.d. n.m. n.m.
t=30 1.35 n.m. -55.1 0.39 n.d. n.d. n.m. n.m.
t=60 1.35 n.m. -53.3 0.32 n.d. n.d. n.m. n.m.
t=90 1.35 n.m. -56.0 0.06 n.d. n.d. n.m. n.m.
t=24 hr 1.35 n.m. -56.7 0.42 n.d. n.d. n.m. n.m.
H3PO4 t=0 (no T, no
acid) 110.58 n.m. n.d. n.d. n.m. n.m.
t=2 110.58 n.m. n.d. n.d. n.m. n.m.
t=5 110.58 n.m. n.d. n.d. n.m. n.m.
t=10 110.58 n.m. n.d. n.d. n.m. n.m.
t=15 110.58 n.m. n.d. n.d. n.m. n.m.
t=30 110.58 n.m. -47.2 0.1 n.d. n.d. n.m. n.m.
t=60 110.58 n.m. n.d. n.d. n.m. n.m.
t=120 110.58 n.m. -55.2 0.37 n.d. n.d. n.m. n.m.
t=180 110.58 n.m. n.d. n.d. n.m. n.m.
t=24 hr 110.58 n.m. -51.9 0.45 n.d. n.d. n.m. n.m.
t=48 hr 110.58 n.m. n.d. n.d. n.m. n.m.
Other method
NaOH 110.58 -76.5 0.03 n.d. n.d. n.m. n.m.
NaOH-aliquot 1
t=1d day 110.58 -77.0 0.1 n.d. n.d. -220.9 n.m.
t=9d days 110.58 n.m. -70.1 0.62 n.d. n.d. n.d. n.d.
t=16 days 110.58 n.m. -69.5 n.d. n.d. n.d. n.d.
t=22 days 110.58 n.m. -72.7 n.d. n.d. n.d. n.d.
t=427days 110.58 n.m. -50.7 0.39 n.d. n.d. n.d. n.d.
NaOH-aliquot 2
t=1 day 110.58 -77.3 0.76 n.d. n.d. n.d. n.d.
t=9 days 110.58 n.m. -70.1 n.d. n.d. n.m. n.d.
t=16 days 110.58 n.m. -69.8 0.01 n.d. n.d. n.m. n.d.
t=22 days 110.58 n.m. -76.8 0.75 n.d. n.d. n.m. n.d.
t=427 days 110.58 n.m. -49.7 0.67 n.d. n.d. n.m. n.d.
Acid versus alkaline extracted CH43 Dvurechenskii
Mud Volcano
DMV_319ROV-PC3
DMV_310GC_125-135 cmbsf
IODP 301_U1301C_110 mbsf Juan de Fuca Ridge
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
H3PO4 t=0 (no T, no
acid) 187.00 n.m. n.m. n.m. n.m. n.m. n.m. n.m. n.m.
t=2 187.00 n.m. n.m. n.m. n.m. n.m. n.m. n.m. n.m.
t=5 187.00 n.m. n.m. n.m. n.m. n.m. n.m. n.m. n.m.
t=10 187.00 n.m. n.m. n.m. n.m. n.m. n.m. n.m. n.m.
t=15 187.00 n.m. n.m. n.m. n.m. n.m. n.m. n.m. n.m.
t=30 187.00 n.m. n.m. n.m. n.m. n.m. n.m. n.m. -196.6
t=60 187.00 n.m. n.m. n.m. n.m. n.m. n.m. n.m. n.m.
t=120 187.00 n.m. n.m. n.m. n.m. n.m. n.m. n.m. n.m.
t=180 187.00 n.m. n.m. n.m. n.m. n.m. n.m. n.m. n.m.
t=24 hr 187.00 n.m. n.m. n.m. n.m. n.m. n.m. n.m. n.m.
U1326D 171
mbsf t=30 min 187.00 -64.4 0.04 n.d. n.d. n.m. n.m.
Other method:
NaOH 187.00 -63.8 0.41 n.d. n.d. n.m. n.m.
NaOH-aliquot 1 aliquot 1
t=1d day 171.00 -62.7 0.02 n.d. n.d. -206.4
t=9d days 171.00 -66.2 0.3 n.d. n.d. -201.1
t=16 days 171.00 -69.2 0.7 n.d. n.d. -209.7
t=22 days 171.00 -71.8 n.d. n.d. -196.1
t=427days 171.00 -71.1 n.d. n.d. -203.4
NaOH-aliquot 2
t=1d day 171.00 -66.9 1.10 n.d. n.d. n.m. n.m.
t=9d days 171.00 -66.2 n.d. n.d. n.m. n.m.
t=16 days 171.00 -69.8 0.3 n.d. n.d. n.m. n.m.
t=22 days 171.00 -71.9 n.d. n.d. n.m. n.m.
t=427days 171.00 -72.4 0.1 n.d. n.d. n.m. n.m.
t=0 (no T, no
acid) 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m.
t=2 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m.
t=5 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m.
t=10 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m.
t=15 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m.
t=30* 0.21-0.25 n.m. -75.5 0.01 n.m. n.m. n.m. -175.9
t=60 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m.
t=90 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m.
t=120 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m.
t=180 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m.
t=360 0.21-0.25 -76.3 0.79 n.m. n.m. n.m. n.m.
t=24 hr 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m.
Other method:
NaOH 0.21-0.25 n.m. n.m. n.m. n.m. n.m. n.m. n.m.
t=1d day 0.21-0.29 -82.9 0.8 n.d. n.d. -145.2
IODP 311_U1326D_187 mbsf
IODP 311_U1326D_171 mbsf
Japan Trench (YK06-05) 6K957CY_21-25 cmbsf Cascadia Margin
NaOH: 21-29 cmbsf
number
mbsf ‰ ‰ ‰ ‰ ‰ ‰ ‰ (± 3 ‰) ‰ (± 3 ‰)
t=9d days 0.21-0.29 n.m. -75.7 0.2 n.d. n.d. -169.8
t=16 days 0.21-0.29 n.m. -68.9 0.5 n.d. n.d. -207.7
t=22 days 0.21-0.29 n.m. -68.0 0.4 n.d. n.d. -209.4
t=427days 0.21-0.29 n.m. -68.1 0.4 n.d. n.d. -178.2
t=1d day 0.25-0.32 -81.1 1.3 n.d. n.d. n.d.
t=9d days 0.25-0.33 n.m. -74.2 1.2 n.d. n.d. -207.7
t=16 days 0.25-0.33 n.m. -73.5 0.7 n.d. n.d. -195.0
t=22 days 0.25-0.33 n.m. -67.6 n.d. n.d. -219.4
t=427days 0.25-0.33 n.m. -66.4 0.8 n.d. n.d. -193.6
n.d.: not detected
mbsf: meter below seafloor
1 extracted with 1 N NaOH solution in 20 ml glass vials crimp sealed with silicon or butyl rubber stoppers (cooked in
2 dissolved and sorbed gases were extracted with 1 N NaOH solution and accumulated together in the headspace
3 hydrocarbon gases were extracted using hot solution of 85% phosphoric acid in partially evacuated containers w.m.: values are given as weighted mean of seperate aliquots extracted over time
n.m.: not measured
mbsl: meter below sealevel NaOH: 25-33 cmbsf
Cruise, location and station number
Depth (cmbsf) TOC (%)1 TC (%)1
Gulf of Mexico 5 1.3 4.3
M67/2b 25 1.3 4.2
GeoB106-24-1 45 1.4 4.5
65 2.6 5.8
85 0.7 5.4
105 1.2 4.5
125 1.2 5.3
145 2.2 5.7
Japan Trench 0.5 1.7 1.8
YK06-05 1.5 1.7 2.0
6K957CG 2.5 1.6 1.8
4 1.7 1.8
6 1.7 1.8
8 1.7 1.8
10 1.7 1.8
12 1.7 1.9
14 1.7 1.9
16 1.6 1.8
18 1.2 1.3
20 1.2 1.3
23 1.3 1.3
27 1.2 1.2
32 1.3 1.3
Japan Trench 0.5 2.2 2.4
YK06-05 1.5 2.4 2.4
6K955CBl. 2.5 2.1 2.4
3.5 2.2 2.7
4.5 2.0 2.3
5.5 1.9 2.1
7 1.9 2.0
9 1.8 1.9
11 1.8 1.8
13 1.7 1.7
15 1.7 1.8
17 1.7 1.8
19 1.7 1.7
21 1.8 1.9
23 1.7 1.8
Black Sea 1.5 2.7 6.3
TTR15 30 3.9 6.2
BS340G 36 3.7 7.1
74 4.6 6.7
95 3.1 8.7
142 4.6 9.5
162 0.5 2.4
191 0.5 1.7
221 0.5 2.1
251 0.6 1.9
278 0.6 2.0
288 0.6 2.2
306 0.6 2.0
Black Sea 7 1.9 6.2
TTR15 36 1.3 3.8
BS344G 52 6.7 8.9
68 1.3 4.6
97 6.3 8.6
115 0.5 1.6
131 0.5 1.2
168 0.6 1.7
197 0.7 1.3
224 0.6 1.7
243 0.5 1.1
264 0.6 1.6
295 0.6 1.5
313 0.7 2.0
328 0.5 1.6
348 0.4 1.1
Black Sea 8 1.9 4.7
TTR15 15 1.9 4.9
BS362G 30 1.8 6.4
42 1.8 4.5
46 1.6 4.1
62 2.3 5.9
78 1.7 7.2
90 2.0 4.2
105 3.4 6.5
131 2.8 5.5
139 2.8 5.1
154 4.9 8.0
Black Sea 20 1.1 1.8
M72/2 50 1.1 1.7
310GC 80 1.1 1.7
110 1.1 2.0
135 1.0 1.7
170 1.1 1.8
210 1.1 1.7
260 1.1 1.7
300 1.1 1.9
340 1.1 1.7
380 1.1 1.6
430 1.1 1.8
440 1.1 1.7
Black Sea 2 1.8 4.3
M72/2 30 1.5 3.7
80 1.5 4.8
100 2.6 4.3
115 0.9 2.5
130 3.9 5.5
160 2.8 5.4
200 1.6 3.1
240 2.0 3.7
255 1.1 1.7
270 1.1 1.7
290 1.1 2.1
310 1.2 1.8
320 1.0 1.8
Standards
Std 4.98% C 4.95
Std 7.26%C 3.56%S 7.27
Std 7.26%C 3.56%S 7.27
Std 12%C 11.99
Std 1.30%C 0.017%S 1.30
Std 0.811C 0.0062S 0.86
Std 1.30%C 0.017%S 1.28
Std 1.30%C 0.017%S 1.32
Std 2.48%C 0.069% S 2.48
Std 1.30%C 0.017%S 1.26
Std 2.48%C 0.069% S 2.48
Std 1.30%C 0.017%S 1.31
Std 1.30%C 0.017%S 1.32
Std 1.30%C 0.017%S 1.28
Std 1.30%C 0.017%S 1.34
Std 1.30%C 0.017%S 1.30
Std 1.30%C 0.017%S 1.30
Std 1.30%C 0.017%S 1.30
1Total Organic Carbon & Total Carbon, measured using a Leco C 200 CS analyzer on acidified and non-acidified samples, respectively
Cruise, location and station number
Depth (cm) Quartz Qz/Fsp (IR) Plagioclase Kfs/Plg (IR) K-feldspar Calcite Mg-rich Calcite
Aragonite
Error (rel%) ±1
Ratio of the integrated Intensity of
the Quartz 4.26 Ångstroem (Å) and the sum of integrated
intensities of K-feldspar 3.24 Å and
plagioclase 3.19 Å
±2-5
Ratio of the integrated intensities of
K-feldspar 3.24 Å and plagioclase
3.19 Å
±2-5 ±1 ±2-3 ±2-3
Black Sea
TTR15_BS340G 1.5 7.5 0.4 2.8 0.6 1.1 30.5 0.0 0.0
TTR15_BS340G 30.0 7.8 0.4 7.8 0.6 1.2 24.6 0.1 0.0
TTR15_BS340G 36.0 9.7 0.4 4.4 0.7 1.8 19.4 0.5 0.0
TTR15_BS340G 74.0 14.6 0.4 4.0 1.0 3.5 9.8 6.2 0.0
TTR15_BS340G 95.0 7.1 0.3 14.2 1.4 1.8 0.0 11.5 0.0
TTR15_BS340G 142.0 8.1 0.6 3.2 0.3 0.5 0.0 15.0 2.9
TTR15_BS340G 162.0 15.7 0.4 6.8 0.3 2.8 13.8 2.8 0.0
TTR15_BS340G 191.0 18.5 0.3 8.8 0.4 3.6 8.6 1.1 0.0
TTR15_BS340G 221.0 14.0 0.3 5.5 0.3 2.4 13.6 2.0 0.0
TTR15_BS340G 251.0 10.5 0.3 5.7 1.5 7.1 8.3 0.5 0.0
TTR15_BS340G 278.0 8.4 0.2 4.7 2.8 8.6 8.0 0.4 0.0
TTR15_BS340G 288.0 10.4 0.4 3.2 0.9 4.7 8.7 0.3 0.0
TTR15_BS340G 306.0 9.9 0.4 6.5 0.5 1.3 6.8 0.5 0.0
TTR15_BS3626G 15.0 10.5 0.2 9.0 0.2 1.9 31.5 1.3 0.0
TTR15_BS3626G 30.0 8.3 0.2 7.9 0.2 1.4 32.4 8.0 0.0
TTR15_BS3626G 46.0 10.3 0.3 11.4 0.2 2.9 21.8 4.7 0.0
TTR15_BS3626G 62.0 8.7 0.3 8.9 0.2 1.9 30.7 3.4 0.0
TTR15_BS3626G 78.0 8.9 0.2 6.0 0.2 1.8 28.7 16.0 0.0
TTR15_BS3626G 90.0 14.9 0.3 5.2 0.3 2.5 17.0 5.0 0.0
TTR15_BS3626G 105.0 13.8 0.3 12.5 0.1 1.4 8.1 13.9 0.0
TTR15_BS3626G 131.0 9.6 0.3 9.0 0.2 3.9 9.2 9.5 0.0
TTR15_BS3626G 139.0 15.1 0.3 9.4 0.1 2.2 12.1 8.5 0.0
TTR15_BS351AP 120.0 12.2 0.3 11.7 0.1 1.7 25.5 0.0 4.1
TTR15_BS351AP 150.0 12.2 0.3 9.5 0.1 1.3 29.2 0.9 0.0
Chapopote, Gulf of Mexico
M67/2b_GeoB106-10 398.0 7.5 0.5 2.6 0.6 1.5 9.2 1.7 1.7
M67/2b_GeoB106-10 728.0 6.7 0.9 2.7 1.6 0.7 8.1 0.0 0.0
M67/2b_GeoB10624-1 5.0 8.6 0.5 2.3 0.6 1.2 24.8 0.0 0.0
M67/2b_GeoB10624-1 25.0 7.3 0.4 5.4 0.5 0.9 32.4 0.0 0.0
M67/2b_GeoB10624-1 45.0 8.3 0.4 3.5 0.7 1.4 25.2 0.0 0.0
M67/2b_GeoB10624-1 65.0 7.5 0.5 5.9 0.3 0.6 19.2 0.6 4.6
M67/2b_GeoB10624-1 85.0 6.8 0.5 1.8 0.1 0.7 13.4 5.7 8.7
M67/2b_GeoB10624-1 105.0 6.0 0.6 1.3 0.3 0.4 31.5 5.7 4.4
M67/2b_GeoB10624-1 145.0 7.5 0.5 3.5 0.3 0.7 16.5 0.0 8.7
Japan Trench
YK06-05_6K954CG 5.0 9.4 0.2 24.2 0.4 0.9 21.8 0.0 0.0
YK06-05_6K955Bl. 20-22 10.1 0.2 34.1 0.3 1.5 12.1 0.3 0.0
YK06-05_6K957CG 1.0 13.1 0.3 24.2 0.3 1.2 0.0 0.4 5.3
YK06-05_6K957CG 3.0 12.2 0.2 24.0 0.2 1.3 0.0 0.3 0.0
YK06-05_6K957CG 9.0 11.8 0.3 26.7 0.2 1.2 0.0 0.3 0.0
YK06-05_6K957CG 17.0 12.7 0.3 22.5 0.1 1.4 0.3 0.0 0.0
YK06-05_6K957CG 25.0 13.1 0.2 23.1 0.2 4.7 0.2 0.0 0.0
YK06-05_6K957CG 29.0 12.9 0.2 26.7 0.4 2.2 0.0 0.2 0.0
YK06-05_6K957CY 15-20 9.7 0.2 27.7 0.2 1.0 30.7 0.4 0.0
YK06-05_6K957CY 25-30 10.7 0.2 23.5 0.1 0.7 28.7 0.4 0.0
YK06-05_6K958CY 0-10 11.6 0.3 24.0 0.2 0.6 17.0 0.1 0.0
Error (rel%)
Black Sea TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS351AP TTR15_BS351AP
Chapopote, Gulf of Mexico
M67/2b_GeoB106-10 M67/2b_GeoB106-10 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1
Japan Trench YK06-05_6K954CG YK06-05_6K955Bl.
YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CY YK06-05_6K957CY YK06-05_6K958CY
Ratio of the integrated intensities of calcite 3.035
Å and dolomite 2.889 Å
±1 ±2-3 ±2-3 ±5 ±5-10 ±5-10 ±2
12.9 0.7 0.1 0.0 31.4 3.9 0.0 3.9 0.0
10.8 0.9 0.2 0.0 25.8 2.5 0.9 1.5 0.0
8.9 0.7 0.0 0.0 20.5 5.6 1.4 4.2 0.0
2.6 4.9 0.0 0.0 21.0 7.3 2.3 5.0 0.0
10.6 2.8 0.0 0.0 14.2 7.2 2.8 4.4 0.0
7.7 0.7 0.0 0.0 18.6 9.7 5.9 3.8 0.0
3.1 5.4 0.0 0.0 22.1 6.3 0.0 6.3 0.0
2.8 4.5 0.0 0.2 14.4 2.1 1.3 0.8 0.0
3.6 3.0 0.0 0.1 18.7 8.0 2.8 5.2 0.0
3.9 1.9 0.0 0.0 10.7 10.8 3.1 7.7 0.0
4.4 1.1 0.0 0.1 9.5 8.3 4.0 4.3 0.0
4.3 0.8 0.0 0.0 9.9 8.2 5.4 2.8 0.0
2.5 1.7 0.3 0.0 9.3 4.9 2.7 2.2 0.1
22.0 0.4 0.9 0.0 34.0 2.8 0.6 2.2 0.0
27.8 0.1 0.6 0.0 41.1 5.1 1.8 3.4 0.0
5.0 0.6 0.3 0.0 27.3 3.7 0.4 3.3 0.0
21.9 0.6 0.5 0.1 35.3 4.7 0.7 4.0 0.0
40.1 0.3 0.6 0.0 45.7 3.9 2.4 1.5 0.0
11.6 1.0 0.1 0.1 23.2 7.3 3.5 3.8 0.0
8.4 0.4 1.3 0.0 23.6 4.7 0.0 4.7 0.0
11.2 0.8 0.6 0.1 20.1 4.5 2.1 2.5 0.0
19.0 0.5 0.0 0.8 21.9 7.5 5.5 2.0 0.0
16.1 0.5 0.3 0.0 30.4 6.5 1.2 5.3 0.0
26.7 0.3 0.4 0.0 30.8 4.6 0.0 4.6 0.0
28.6 0.3 0.0 0.3 13.1 4.5 0.0 4.5 0.0
27.7 0.4 0.0 0.4 8.9 4.9 0.2 4.8 0.0
19.9 0.2 0.0 0.0 25.0 9.8 3.8 6.0 0.0
34.5 0.3 0.1 0.4 33.3 1.2 0.0 1.2 0.0
30.6 0.1 0.1 0.0 25.4 7.4 3.4 3.9 0.0
49.3 0.3 0.0 0.0 24.7 0.0 0.0 0.0 0.0
10.7 0.2 0.0 0.0 28.0 6.6 0.0 6.6 0.0
18.1 0.4 0.0 0.4 42.3 8.5 3.5 5.1 0.0
11.6 0.5 0.0 0.0 25.8 7.6 0.0 7.6 0.0
0.0 0.0 0.0 21.8 1.9 0.0 1.9 0.0
2.2 0.1 0.0 0.1 12.7 3.4 3.2 0.2 0.0
1.9 0.0 0.1 1.0 6.7 3.7 1.3 2.4 0.0
2.1 0.0 0.2 4.1 4.5 8.9 3.6 5.3 0.0
1.2 0.0 0.3 5.6 6.2 7.6 1.3 6.3 0.0
0.8 0.2 0.1 0.1 0.8 6.0 2.9 3.0 0.0
0.2 0.0 0.3 0.0 0.5 5.1 1.2 3.8 0.0
0.2 0.0 0.4 1.6 2.2 3.8 1.5 2.3 0.0
2.9 0.1 0.3 0.4 32.0 6.5 3.4 3.1 0.0
0.7 0.8 0.0 0.8 30.8 7.2 2.1 5.1 0.0
0.5 0.2 0.2 0.4 17.9 8.2 1.2 7.0 0.0
Error (rel%)
Black Sea TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS351AP TTR15_BS351AP
Chapopote, Gulf of Mexico
M67/2b_GeoB106-10 M67/2b_GeoB106-10 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1
Japan Trench YK06-05_6K954CG YK06-05_6K955Bl.
YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CY YK06-05_6K957CY YK06-05_6K958CY
±2 ±5-10 ±5-10 ±5 ±5-10
Ratio of the integrated intensities
of illite/micas 10 Å and 5
Å
±5-10 ±5-10 ±5-10 ±2-5
0.0 1.0 25.4 8.3 8.3 0.4 0.0 0.0 0.0 2.2
0.0 0.2 22.8 17.6 15.9 0.4 1.7 0.0 0.0 2.7
0.0 0.0 16.5 19.7 19.7 0.4 0.0 0.0 0.0 2.4
0.0 0.0 2.4 20.8 8.5 0.4 12.2 0.0 0.0 3.3
0.0 0.0 24.5 22.5 15.7 0.4 6.9 0.0 0.0 2.4
0.0 0.4 0.0 38.6 38.6 0.4 0.0 0.0 0.0 3.9
0.0 0.2 2.0 21.0 11.7 0.4 9.3 0.0 0.0 3.7
0.0 0.0 8.6 19.2 12.6 0.4 6.6 0.0 0.0 4.4
0.0 0.0 0.0 38.7 32.1 0.4 6.6 0.0 0.0 2.7
0.0 0.0 18.7 16.3 16.3 0.4 0.0 0.0 0.0 3.3
0.0 0.0 11.6 34.6 34.6 0.4 0.0 0.0 0.0 2.5
0.0 0.0 17.5 29.9 22.8 0.4 7.1 0.0 0.0 2.5
0.0 0.2 12.5 32.5 25.6 0.4 6.1 0.8 0.0 2.4
0.0 2.4 12.7 6.7 6.7 0.4 0.0 0.0 0.0 2.6
0.0 0.2 0.4 17.0 17.0 0.4 0.0 0.0 0.0 2.3
0.3 0.0 2.1 18.9 18.9 0.4 0.0 0.0 0.0 3.2
0.0 0.0 14.2 2.9 2.9 0.4 0.0 0.0 0.0 2.7
0.0 0.0 7.8 9.3 9.3 0.4 0.0 0.0 0.0 2.0
0.0 0.0 6.8 9.9 9.9 0.4 0.0 0.0 0.0 3.5
0.0 2.7 0.8 11.9 11.9 0.4 0.0 0.0 0.0 2.0
0.4 0.0 1.4 32.1 29.8 0.4 2.3 0.0 0.0 4.3
0.0 0.0 3.0 12.3 12.3 0.4 0.0 0.0 0.0 2.8
0.0 0.0 13.3 6.2 6.2 0.4 0.0 0.0 0.0 4.2
0.0 0.6 1.7 20.1 20.1 0.4 0.0 0.0 0.0 3.7
0.0 0.0 16.4 32.1 20.6 0.8 0.0 0.0 2.7 4.1
0.0 0.0 19.7 11.9 24.4 1.1 0.0 0.0 1.7 5.3
0.0 0.0 23.4 16.4 12.7 0.2 0.0 0.0 3.7 3.7
0.0 2.5 12.5 17.0 26.8 0.3 0.0 0.0 0.0 2.9
0.0 3.5 24.9 15.9 15.9 0.1 0.0 0.0 0.0 2.1
0.0 0.0 10.6 38.3 31.2 0.3 0.0 0.0 7.1 2.8
0.0 0.1 18.1 14.6 8.4 0.2 0.0 0.0 6.2 3.3
0.0 0.1 0.0 6.7 36.1 0.4 0.0 0.0 0.0 4.0
0.0 0.3 7.9 35.6 28.6 0.3 0.0 0.0 7.1 2.3
0.0 6.1 11.9 18.9 10.5 0.5 3.6 0.0 0.0 3.8
0.0 0.0 0.0 12.3 32.1 0.3 0.0 0.0 0.0 4.2
0.0 0.0 27.2 14.5 14.5 0.5 0.0 0.0 0.0 3.3
0.0 0.0 14.9 13.7 13.7 0.5 0.0 0.0 0.0 2.0
0.0 0.0 10.9 22.4 22.4 0.2 0.0 0.0 0.0 2.8
0.0 8.5 5.2 25.5 21.5 0.3 4.1 0.0 0.0 3.2
0.0 2.0 1.0 32.8 28.4 0.2 1.6 2.8 0.0 3.6
0.0 1.0 13.9 16.0 16.0 0.4 0.0 0.0 0.0 2.4
0.0 12.3 0.6 2.9 15.1 0.5 0.0 0.0 0.0 2.7
0.0 0.2 7.3 9.3 21.6 0.5 0.0 0.0 0.0 2.0
0.0 0.0 0.0 9.9 22.7 0.5 0.0 0.0 0.0 1.2
Error (rel%)
Black Sea TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS351AP TTR15_BS351AP
Chapopote, Gulf of Mexico
M67/2b_GeoB106-10 M67/2b_GeoB106-10 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1
Japan Trench YK06-05_6K954CG YK06-05_6K955Bl.
YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CY YK06-05_6K957CY YK06-05_6K958CY
Ratio of the integrated intensities of kaolinite 3.56-3.58 Å and chlorite
3.50-3.54 Å
±2-5 ±5 ±2-5 ±2-5 ±1 ±2-5 ±2-5 ±2-5
0.3 1.5 41.5 0.2 0.0 0.0 6.6 0.0 0.0 0.4
0.1 1.7 47.3 0.2 0.0 2.1 3.2 0.0 0.0 0.0
0.4 1.4 45.5 0.2 5.5 0.0 3.8 1.2 0.0 1.6
0.3 5.0 38.8 0.4 0.6 1.8 3.9 0.0 0.0 0.0
0.2 1.0 57.6 0.1 0.0 0.0 5.1 0.0 0.0 0.0
0.3 1.6 53.8 0.2 3.8 4.5 4.3 0.0 0.0 1.1
0.2 5.4 38.3 0.4 0.7 0.0 0.2 2.0 0.5 0.0
0.3 7.2 41.5 0.5 1.9 0.0 0.8 0.0 0.1 0.0
0.2 3.5 52.9 0.3 0.2 0.6 0.0 0.0 0.0 0.0
0.2 1.7 50.8 0.2 0.0 0.0 0.1 3.5 0.1 4.0
0.0 2.8 59.8 0.1 0.0 0.0 0.9 0.0 0.0 0.0
0.1 3.0 61.0 0.2 1.1 1.7 0.7 0.0 0.4 1.2
0.2 4.5 56.8 0.2 3.2 3.5 0.3 0.0 0.2 2.7
0.4 4.3 29.1 0.4 0.2 1.6 4.1 0.0 0.0 1.7
0.4 2.7 27.6 0.3 2.1 0.0 3.9 0.0 0.0 0.0
0.5 4.3 32.2 0.5 3.0 0.0 4.9 0.0 0.0 0.0
0.3 2.5 27.1 0.3 0.4 0.2 3.0 0.0 0.1 0.0
0.4 3.0 26.0 0.4 1.5 0.7 2.1 0.0 0.0 0.0
0.3 3.3 30.8 0.7 0.4 0.0 2.1 0.0 0.0 0.0
0.4 2.6 22.1 0.6 4.7 0.0 1.0 0.0 0.0 0.0
0.4 2.8 45.2 0.2 0.8 0.0 0.3 0.0 0.0 0.0
0.4 3.2 28.8 0.7 5.2 0.0 1.0 0.0 0.2 0.0
0.5 3.6 33.9 0.4 0.9 0.0 0.0 0.7 0.5 3.3
0.4 4.3 34.3 0.4 3.7 0.0 0.0 0.0 1.2 0.0
0.4 0.9 49.2 0.2 0.2 3.5 4.8 0.0 0.0 0.0
0.6 0.8 56.9 0.1 0.0 1.1 5.8 0.0 0.3 0.0
0.6 0.9 54.1 0.2 0.0 3.8 3.2 0.0 0.5 0.0
0.6 1.1 44.5 0.2 0.0 0.0 4.9 0.0 0.3 0.0
0.6 1.3 51.5 0.2 0.0 0.0 4.8 0.0 0.0 0.0
0.6 3.0 54.7 0.1 0.0 0.0 4.5 0.0 0.0 0.0
0.6 0.8 43.3 0.2 13.9 0.0 2.0 0.0 0.0 0.0
0.3 0.9 49.6 0.1 1.8 4.0 1.8 0.3 0.0 0.0
0.4 1.1 54.6 0.1 0.0 2.6 4.2 0.0 0.6 0.0
4.6 0.0 31.7 0.3 0.0 0.2 4.8 0.0 0.2 0.0
0.3 1.1 40.9 0.3 1.7 0.0 9.0 0.0 0.0 0.0
0.6 1.0 49.7 0.3 0.0 0.0 3.0 0.0 0.0 2.0
0.5 0.9 40.4 0.3 4.6 0.0 6.9 0.0 0.6 0.3
0.6 1.9 45.6 0.3 2.1 0.0 4.6 0.0 0.4 0.0
0.6 2.0 41.9 0.3 1.3 0.0 1.5 0.0 0.7 0.0
1.0 3.2 45.7 0.3 3.3 0.0 2.1 1.1 0.1 2.0
0.4 1.5 37.6 0.3 0.4 0.0 2.4 1.8 0.6 0.0
0.3 1.5 26.4 0.4 6.4 0.0 11.0 0.0 0.1 0.0
0.4 2.4 40.5 0.4 2.4 0.0 11.2 1.4 0.0 1.4
0.0 2.9 35.0 0.3 4.3 0.0 16.7 0.0 0.0 1.9
Error (rel%)
Black Sea TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS351AP TTR15_BS351AP
Chapopote, Gulf of Mexico
M67/2b_GeoB106-10 M67/2b_GeoB106-10 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1
Japan Trench YK06-05_6K954CG YK06-05_6K955Bl.
YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CY YK06-05_6K957CY YK06-05_6K958CY
±2-5 ±2-5 ±2-5 ±2-5 ±2-5 ±2-5 ±2-5 ±5-10 ±2-5 ±2-5
0.0 0.0 0.0 0.0 0.0 0.0 7.6 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.7 0.0 3.8 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 5.7 0.0 0.0 0.0
0.0 0.1 0.0 0.0 0.0 0.0 11.1 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 1.7 0.0 0.0 0.0
0.7 0.0 0.0 0.0 0.0 0.0 7.9 0.1 0.5 0.0
0.0 0.1 0.0 0.0 0.0 0.0 7.2 2.2 0.3 0.0
1.0 0.2 0.0 0.0 0.0 0.0 3.6 0.1 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 7.2 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.3 6.9 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 4.7 0.0 0.0 0.0
0.0 0.1 0.0 0.0 0.0 0.0 5.7 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 5.1 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 7.3 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.4 0.0 6.9 0.0 0.0 0.0
0.2 0.0 0.0 0.0 0.0 0.0 12.9 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 7.3 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 19.8 0.2 0.0 0.0
0.0 0.3 0.0 0.0 0.0 0.0 17.5 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 11.0 0.0 0.0 0.0
0.4 0.0 0.0 0.0 0.0 0.0 15.1 0.2 0.3 0.0
0.5 0.0 1.2 0.0 0.0 0.0 2.0 0.0 0.0 0.0
0.0 0.1 0.8 0.0 0.0 0.0 3.2 0.4 0.0 0.0
0.0 0.0 0.0 0.0 0.0 1.7 0.4 0.0 0.0 0.0
0.0 0.2 0.0 0.0 0.0 0.0 0.3 1.8 0.0 0.0
0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.0 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 2.9 0.0 0.0 0.0
0.9 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.0 0.0 0.0 0.1 0.6 0.0 2.0 0.6 0.0 18.2
0.0 0.0 0.0 0.0 0.2 0.0 0.0 0.0 0.0 1.3
0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.0 0.1 0.0 0.0 0.0 0.0 0.0 4.9 0.0 0.3
0.4 0.0 0.0 0.0 0.0 0.0 0.4 0.1 0.0 0.4
0.2 0.0 0.0 0.0 0.3 0.0 8.3 0.0 0.0 0.1
0.0 0.0 0.1 0.0 0.0 0.0 1.9 0.1 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 12.3 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.3 0.0 0.8 0.0 0.9 0.0
0.0 0.0 0.0 0.0 0.3 0.0 3.5 1.4 0.0 1.3
0.0 0.0 1.3 0.0 0.0 0.0 0.0 0.4 0.0 0.4
Error (rel%)
Black Sea TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS340G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS3626G TTR15_BS351AP TTR15_BS351AP
Chapopote, Gulf of Mexico
M67/2b_GeoB106-10 M67/2b_GeoB106-10 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1 M67/2b_GeoB10624-1
Japan Trench YK06-05_6K954CG YK06-05_6K955Bl.
YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CG YK06-05_6K957CY YK06-05_6K957CY YK06-05_6K958CY
? ±2-5 ±2-5 ±2-5
(More than 100 is possible as all single wt. %
are mean values of up to
6 runs of the QUAX software per
sample)
0.0 0.0 0.0 0.0 100.0
0.0 0.0 0.2 0.0 100.0
0.0 0.0 0.2 0.0 100.3
0.0 0.5 0.0 0.0 100.0
0.0 0.0 0.0 0.0 100.0
0.0 0.1 0.0 0.0 100.0
0.0 0.2 1.2 0.0 100.0
0.2 0.0 0.3 0.0 100.0
0.0 0.0 0.8 0.0 100.0
0.0 0.0 0.4 0.0 100.0
0.0 0.1 0.9 0.0 100.0
0.0 0.0 1.0 0.0 100.4
0.0 0.2 0.1 0.0 100.0
0.0 0.0 0.4 0.1 100.0
0.0 0.2 0.0 0.0 100.0
0.0 0.6 0.1 0.0 100.3
0.0 0.4 0.8 0.0 100.0
0.0 0.0 0.0 0.0 100.0
0.0 0.7 0.0 0.2 100.0
0.0 0.0 0.4 0.0 100.0
0.0 0.1 0.0 0.0 100.4
0.0 0.2 0.0 0.0 100.0
0.0 0.6 0.2 0.0 100.0
0.0 0.2 1.4 0.4 100.0
0.0 0.0 0.0 0.0 100.4
0.0 0.0 0.2 0.0 100.0
0.0 1.0 0.0 0.0 100.0
0.0 0.1 0.3 0.1 100.0
0.0 0.0 1.5 0.0 100.0
0.0 0.9 0.9 0.0 100.0
0.0 0.5 0.1 0.0 100.0
0.0 0.0 0.2 0.0 100.0
0.0 0.0 0.0 0.0 100.0
0.0 0.0 0.7 0.0 100.3
0.0 0.7 0.0 0.0 100.0
0.0 0.0 0.0 0.0 100.0
0.0 0.0 0.0 0.0 100.0
0.0 0.0 0.0 0.0 100.0
0.0 0.0 0.0 0.0 99.9
0.0 0.0 0.2 0.0 100.0
0.0 0.0 0.0 0.0 100.0
0.0 0.0 0.2 0.0 100.0
0.0 0.0 0.0 0.0 100.0
0.0 0.0 0.0 0.1 100.0
TTR15_BS340G 1.5 13.6 293.5 43.7
TTR15_BS340G 32 286.1 10.9
TTR15_BS340G 36 12.4 287.3 3.9
TTR15_BS340G 74 8.7 306.8 5.9
TTR15_BS340G 95 253.0 7.4
TTR15_BS340G 142 6.3 272.4 4.3
TTR15_BS340G 162 12.4 290.6 2.4
TTR15_BS340G 191 19.8 179.8 6.0
TTR15_BS340G 221 23.4 164.4 6.8
TTR15_BS340G 251 24.6 188.0 8.8
TTR15_BS340G 278 197.3 8.5
TTR15_BS340G 288 209.2 10.6
TTR15_BS340G 306 30.0 199.2 10.6
TTR15_BS362G 8 11.8 239.6 5.4
TTR15_BS362G 15 10.9 204.1 29.4
TTR15_BS362G 30 10.6 233.3 17.4
TTR15_BS362G 46 11.2 261.2 20.1
TTR15_BS362G 62 11.5 189.8 29.4
TTR15_BS362G 78 12.1 162.6 17.4
TTR15_BS362G 90 10.4 220.0 54.1
TTR15_BS362G 105 4.0 204.3 33.8
TTR15_BS362G 131 6.2 393.1 39.2
TTR15_BS362G 139 6.1 381.9 11.0
TTR15_BS362G 154 1.9 300.4 34.0
2Ethylene glycol mono ethyl ether measured MSA
1BET (Brunauer-Emmet-Teller) mineral surface area (MSA) measured by surface adsorbed N2. Measures external mineral surfaces only, N2 does not penetrate interlayer sites in smectitic clay minerals.
VIII. AC K N O W L E D G E M E N T S
I am really thankful to Kai-Uwe Hinrichs for giving me the opportunity to conduct research in the exciting field of Organic Geochemistry. Kai and his group-members greatly introduced me into the world of this highly multidisciplinary field in which I thrived through the world of earth history, biogeochemistry, geomicrobiology and petroleum geology. I thank Wolfgang Bach who agreed on becoming the second supervisor of my PhD.
I appreciate the fruitful discussions with my colleagues Verena Heuer, Marcus Elver, Daniel Birgel, Julius Lipp, Florence Schubotz, Yushih Lin, Xavier Prieto-Mollar, and colleagues from other groups, especially Thomas Pape. Excellent scientific and technical help came from all of them concerning gas analysis and biomarker research. I thank Sean Sylva and Jeff Seewald from the Woods Hole Oceanography Institution to have introduced me into autoclave technology and isotope ratio mass spectrometry. Special thanks go to Thomas Holler from the MPI Bremen who introduced me into the field of anoxic incubations of microorganisms. Christoph Vogt excellently performed the x-ray analysis and helped me out understanding the mineralogical data set. I thank Marlene Bausch and Sabrina Renken who helped me a lot measuring hundreds of gas samples.
Thanks go to the initiators of the project, Kai-Uwe Hinrichs and Gerhard Bohrmann who raised the funds for my PhD project from the Geotechnolgien-project Metro financed by the German Ministry for Education and Science (BMBF).
I want to thank Florence Schubotz who kindly proof-read the introductory part of this thesis, and Anne Bock who helped editing the document.
Very special thanks go to my wife Ladan who is such a lovely and cheerful person that it is very easy in her company to overcome hard times and doubts.
I dedicate this PhD thesis to my mum and my dad. My dad always supported me in great manner and aroused my ambitions to educate myself and to seek my luck in intellectual stimulation. I want to thank my brother and sister and the rest of my family. My mum saw me marrying my lovely wife in August 2007 but not graduating in March 2009. She rests in Peace.
IX. PR E S E N T A T I O N S A N D O T H E R S C I E N T I F I C E X P E R I E N C E S
Oral presentations at scientific conferences
x Ertefai, T., Prieto-Mollar, X., Sylva, S., Seewald, J. and Hinrichs, K.-U.: Sorbed methane in marine sediments. Talk at the 97th International Meeting of the Geologische Vereinigung e.V. The Oceans in the Earth System, Bremen, Germany, 2007.
x Ertefai (presented as Mohr), T., Prieto-Mollar, X., Sylva, S., Seewald, J. and Hinrichs, K.-U.: Adsorption of gaseous hydrocarbons to marine sediments and clay minerals.
Talk at TTR-16 Post-Cruise Meeting. Bremen, 2007.
x Ertefai (presented as Mohr) T., Prieto-Mollar, X., Sylva, S., Seewald, J. and Hinrichs, K.-U.: Adsorption of gaseous hydrocarbons to marine sediments and clay minerals.
TTR-15 Post-Cruise Meeting. Moscow, 2006.
Poster presentations at scientific conferences
x Ertefai, T.F., Heuer, V., Prieto-Mollar, X., Sylva, S., Seewald, J. and Hinrichs, K.-U.: Quantities and isotopic signatures of sorbed methane - a biogeochemical perspective on a disregarded carbon pool. European Geosciences Union Meeting 2008, Vienna, Austria.
x Ertefai, T., Prieto-Mollar, X., Sylva, S., Seewald, J. and Hinrichs, K.-U.:
Adsorption of gaseous hydrocarbons to marine sediments and clay minerals.
International Meeting on Organic Geochemistry (IMOG). Torquay, GB, 2007.
x Ertefai (presented as Mohr), T., Prieto-Mollar, X., Sylva, S., Seewald, J. and Hinrichs, K.-U.: Adsorption of gaseous hydrocarbons to marine sediments and clay minerals. Gordon Research Conference in Organic Geochemistry. Holderness School, Plymouth, NH, USA, August 6-11, 2006.
Field experience
x 2007: M72/2: RV Meteor M72/2: Black Sea: Istanbul-Istanbul: Gas turnover at GHOSTDABS Field and Dvurechenskii Mud Volcano.
x 2007: Tidal flat investigation in the German Wadden Sea (North Sea) together with Max-Planck Institution for Marine Microbiology (Bremen, Germany)
x 2005: Training Through Research 15 (TTR 15; Floating University of IOC-UNESCO) from Istanbul to Trabzon to Istanbul on R/V PROFESSOR